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  • CdSe nanocrystals  (1)
  • SANS  (1)
  • Springer  (2)
  • 1995-1999  (2)
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  • Springer  (2)
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  • 1995-1999  (2)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 13 (1998), S. 629-633 
    ISSN: 1573-4846
    Schlagwort(e): quantum dots ; II–VI crystal growth ; silica gel ; SANS
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Size and size distribution of the semiconductor nanocrystals embedded in a dielectric matrix play a dominant role in line broadening and the exciton quantum confinement level. The results show new aspects of the CdS and CdSe crystal growth as quantum dots using small angle neutron scattering techniques (SANS). Thus, the crystal growth influences the aggregation process of the silica network. The intensity difference of the scattering between the silica matrix and the composite accounts for the crystal size and their volume fraction. Under similar conditions CdS nanocrystals grow faster and bigger than CdSe ones.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1573-4846
    Schlagwort(e): CdSe nanocrystals ; silica xerogels ; sonogels ; SAXS
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Small-angle X-ray scattering (SAXS) experiments were carried out to characterize the structure of the composite formed by CdSe nanocrystals embedded in a popous silica matrix (silica xerogels containing Cd with formamide addition and ultrasound treatment). SAXS results from samples before Se diffusion indicate the presence of heterogeneities with a bimodal size distribution which was associated to the existence of mesopores (pores of several hundred Å) immersed in a nanoporous matrix (characteristic pore radii of 20–30 Å). The diffusion of Se induces the nucleation and growth of CdSe nanocrystals. The average size of the nanocrystals increases with Cd content. Higher Se doses promote the formation of larger nanocrystals (radius of gyration of ∼30 to 50 Å). Anomalous scattering results confirm the existence of Se aggregation associated with CdSe nanocrystal formation and suggest that only partial segregation of Cd and Se occurs.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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