ISSN:
0170-2041
Keywords:
Haloperoxidase
;
Enzymes
;
Bromination
;
Pentabromopseudilin
;
Pseudilins
;
Bromopyrroles
;
Pyrroles, bromo
;
Streptomyces aureofaciens
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Marine Bacteria, VII. - Enzymatic Bromination of Pseudilins and Related Heteroarylphenols with a Chloroperoxidase from Streptomyces aureofaciens Tü 24During the bromination of various substituted synthetic phenyl pyrroles with a chloroperoxidase from Streptomyces aureofaciens Tü 24, mixtures of bromopyrroles are obtained which are not easily accessible by chemical methods. According to the structure of the pyrroles and the kinetics of their transformation, the reaction centre of the enzyme is situated in a slitlike cavity of about 4 × 7 × 8 Ä.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199419940112
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