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  • 1
    Publication Date: 2017-04-04
    Description: The volcanic hazard potential of Mount Etna volcano is currently nourished by long-lasting, powerful eruptions of basaltic magmas coupled with increased seismicity and ground deformation, and the world's largest discharge of volcanic gases. The current evolutionary cycle of Mount Etna activity is consistent with subduction-related chemical modifications of the mantle source. Arrival of a new mantle-derived magma batch beneath the volcano has been hypothesized, but is still elusive among the erupted products. Here we demonstrate petrological and geochemical affinities between the magmas supplying modern eruptions and high-Mg, fall-stratified (FS) basalts ejected violently 4 k.y. ago. The FS primitive magmas (13 wt% MgO) are characteristically volatile enriched (at least 3.8 wt% H2O and 3300 ppm CO2), and bear a trace element signature of a garnet-bearing, metasomatized source (high Gd/Yb, K/La, U/Nb, Pb/Ce, Ca/Al). They started crystallizing olivine (Fo91), clinopyroxene (Mg# 92.5), and Cr spinel deep in the plumbing system (〉5 kbar), contributing to the cumulate piles at depth and to differentiated alkaline basalt and trachybasalt magmas in the shallow conduit. Continuous influx of mantle-derived, volatile-rich magmas, such as those that supplied the FS fallout, provides a good explanation for major compositional and eruptive features of Mount Etna.
    Description: Published
    Description: 255-258
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; volcano ; picrite ; melt inclusions ; volatiles ; degassing ; mantle ; meta-somatism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: The volcanic hazard potential of Mount Etna volcano is presently nourished by long-lasting, powerful eruptions of basaltic magmas coupled with increased seismicity and ground deformation, and the world’s largest discharge of volcanic gases. The current evolutionary cycle of Mount Etna activity is consistent with subduction-related chemical modifications of the mantle source. Arrival of a new mantle-derived magma batch beneath the volcano has been hypothesized, but is still elusive among the erupted products. Here we demonstrate petrological and geochemical affinities between the magmas supplying modern eruptions and high-Mg, fall-stratified (“FS”) basalts ejected violently ~4 Kyr ago. The “FS” primitive magmas (~13 wt% MgO) are characteristically volatile-enriched (at least 3.8 wt% H2O and 3300 ppm CO2), and bear trace element signature of a garnet-bearing, metasomatised source (high Gd/Yb, K/La, U/Nb, Pb/Ce, Ca/Al). They started crystallizing olivine (Fo91), clinopyroxene (Mg# 92.5) and Cr33 spinel deep in the plumbing system (〉 5 kb), contributing to the cumulate piles at depth and to differentiated alkaline basalt and trachybasalt magmas in the shallow conduit. Continuous influx of mantle-derived, volatile-rich magmas, such as those that supplied the “FS” fallout, provides a good explanation for major compositional and eruptive features of Mount Etna.
    Description: Published
    Description: open
    Keywords: Etna, volcano ; picrite ; melt inclusions ; volatiles ; degassing ; mantle, ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 26 (1984), S. 121-130 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In order to be useful for ionic crystals cluster calculations must be modified so as to simulate the crystal potential in a reasonable way. Two aspects of such calculations - the normalization of the orbitals and the construction of the coulomb potential - are analyzed in some detail. Illustrative calculations are carried out for MgO and the results are compared with experimental data and with other theoretical results.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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