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  • Polymer and Materials Science  (1,063)
  • INSTRUMENTATION AND PHOTOGRAPHY
  • Wiley-Blackwell  (1,063)
  • 1980-1984  (1,063)
  • 1
    Electronic Resource
    Electronic Resource
    Synthesis of fibre-forming copolymers of acrylonitrile with acrylates in systems based on lithium alkoxides (1984)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 35 (1984), S. 65-67 
    Details
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Copolymerisation von Acrylnitril und Acrylaten wurde in Dimethylformamid bei hohem Acrylnitril/Acrylat-Verhältnis im Temperaturbereich von -50 bis +10°C durch Lithiumalkoxide initiiert. Die Bedingungen zur direkten Präparation von Spinnlösungen der Copolymere wurden erarbeitet. Das Lösungsspinnen dieser Copolymere durch Orientierungsfällung ergab Fasern mit hohen Festigkeitswerten.
    Notes: The copolymerization of acrylonitrile with acrylates has been initiated by lithium alkoxides in dimethylformamide at a high acrylonitrile/acrylate ratio over the temperature range from -50 to 10°C. The conditions for a direct preparation of spinning solutions of the copolymers were determined. The solution-spinning of these copolymers by orientational precipitation yielded fibres exhibiting high strength properties.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/actp.1984.010350115
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  • 2
    Electronic Resource
    Electronic Resource
    Kinetics of epoxy resin synthesis on the basis of GPC measurements (1981)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 2783-2786 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1981.070260827
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  • 3
    Electronic Resource
    Electronic Resource
    Storage hardening and “abnormal” groups in guayule rubberThis article was presented at the 27th IUPAC Congress, Helsinki, Finland, August 1979. (1981)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 1511-1517 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hardening process of natural (Hevea brasiliensis) rubber, that takes place when this rubber is stored in dry conditions over long periods of time, has been correlated with the presence of reactive “abnormal” groups directly grafted on the polymeric chain and in the serum of the latex. In the present work, natural Hevea (HR) and Guayule (Parthenium argentatum) rubber (GR) were stored under accelerated conditions and the changes in Mooney viscosity and molecular weight measured. The results showed that while HR undergoes hardening, GR keeps its Mooney viscosity constant, as does a constant viscosity (CV) Hevea rubber. These results are explained by the absence of functional “abnormal” groups that sustain the hardening reactions.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1981.070260508
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  • 4
    Electronic Resource
    Electronic Resource
    Effect of fibronectin on the adhesion of an established cell line to a surface reactive biomaterial (1982)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 16 (1982), S. 195-207 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: We have demonstrated that an established hamster cell line (NIL 8 M-2) will adhere to the bioceramic bioglass. The rate at which the NIL 8 M-2 cells assume a spread morphology on bioglass is density dependent and the morphology displayed by NIL 8 M-2 cells attached to bioglass is much more elongated than that displayed by NIL 8 M-2 cells attached to nonreactive glass. Precoating the bioglass with the plasma form of human fibronectin significantly reduces the density dependent nature of cell spreading. Coating the bioglass with fibronectin also reduces the time required for cell spreading and changes the morphology of the attached cells from an elongated to an extremely flattened shape. Our work raises the possibility that bone-implant adhesion might be improved by introducing molecules relevant to cell-substrate attachment into the biomaterial prior to implantation.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jbm.820160303
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  • 5
    Electronic Resource
    Electronic Resource
    Low energy electron loss studies of cuInSe2 surfaces (1982)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 4 (1982), S. 227-229 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The low energy loss spectra (LELS) of clean and oxygen contaminated (111) p-type CuInSe 2 single crystals are reported. Losses due to interband transitions and plasmon excitations are observed. By varying the primary electron energy (100-500 eV) both surface and bulk features of the conduction bands are probed. As oxygen is adsorbed on the surface of the CuInSe 2 (at room temperature), the In and Se atoms seem to associate with themselves and with oxygen, whereas the Cu atoms do not seem to play a direct role in the oxidation process. LELS Spectra are presented as a function of primary beam energy and oxygen absorption.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740040602
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  • 6
    Electronic Resource
    Electronic Resource
    Surface structure and NiO dispersion for NiO/γ-Al2O3 catalysts (1982)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 4 (1982), S. 234-239 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Chemisorption of CO at temperatures below 100°C has been used to evaluate the dispersion of NiO in a series of NiO/γ-Al2O3 catalysts. CO adsorption measurements were supplemented by i.r. spectroscopy to establish the CO/NiO stoichiometry. From monolayer coverage data derived from Freundlich's equation, the percentage of NiO dispersion and the average NiO crystallite size were calculated. The crystallite size of supported NiO was found to be practically constant for NiO loadings from 1 to 8 wt%, experimenting an abrupt increase for higher NiO contents. These results were consistent with additional information on the surface structure of the catalysts obtained by IR spectroscopy, X-ray diffraction, magnetic susceptibility, and reduction with H2.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740040604
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  • 7
    Electronic Resource
    Electronic Resource
    Untersuchungen zur Belastbarkeit von Polybutylenterephthalat (1981)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 32 (1981), S. 465-466 
    Details
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The deformation stability of polybutylene terephthalate in dependence on stress and temperature was determined. The lifetime of the polymer is described as a function of these parameters. The results are compared with the values obtained with other polymers.
    Notes: Die Deformationsstabilität von Polybutylenterephthalat wurde in Abhängigkeit von der Spannung und der Temperatur bestimmt. Die Lebensdauer des Polymers kann als eine Funktion dieser Parameter angegeben werden. Die Ergebnisse werden mit den an anderen Polymeren erhaltenen Werten verglichen.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/actp.1981.010320806
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  • 8
    Electronic Resource
    Electronic Resource
    Thermodynamics and equilibrium sedimentation analysis of the close approach of DNA molecules and a molecular ordering transition (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 1305-1328 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Measurement of the equilibrium distribution of persistence length fragments of DNA in high concentration in the ultracentrifuge shows that the reduced osmotic pressure rises much faster than linearly. From analysis of the data in terms of the Zimm cluster integral we infer that the net interactions between helices are purely repulsive at all distances. A theoretical equation of state derived from scaled particle theory with one adjustable parameter is in excellent agreement with the experimental data so long as the salt concentration is not excessively low. The parameter represents the hard-core radius in a simplified approximation to the potential function for the electrostatic repulsion between helices. Its value depends on the salt concentration, and it shrinks at high salt to a radius in close agreement with direct structural estimates. At a particular value of the osmotic pressure that is only slightly salt dependent, the solution undergoes a reversible transition to a denser, turbid, optically anisotropic phase. The relation between DNA volume fraction, including the electrostatic radius, at the transition point and the effective asymmetry of the molecules as a function of salt is in approximate correspondence with various theoretical treatments. However, the experimental function extrapolates to the correct limit for spherical particles. The work needed to bring DNA to a high concentration is estimated. The results suggest that the phase transition is first order.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1981.360200615
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  • 9
    Electronic Resource
    Electronic Resource
    Experimental characterization of poly(hydroxyalkyl-L-glutamine) conformations in aqueous calcium chloride and sodium perchlorate solutions (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1923-1941 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(hydroxyalkyl-L-glutamine) (alkyl = ethyl, propyl, butyl) solutions have been studied by CD as functions of temperature and activity of calcium chloride and sodium perchlorate. Helical content is altered by changes in salt activity and temperature. The helicity of poly(hydroxybutyl-L-glutamine) and poly(hydroxypropyl-L-glutamine) falls to zero in a monotonic fashion with increasing calcium chloride activity. A nonzero helicity reappears at activities in excess of 5-50 mol kg-1. Poly(hydroxypropyl-L-glutamine) is much more sensitive to calcium chloride than is poly(hydroxybutyl-L-glutamine), and both polypeptides are more sensitive to calcium chloride than are typical proteins. Markedly different behavior is observed with sodium perchlorate. This salt acts as a helix stabilizer at low activities but becomes a destabilizer at activities higher than 0.3-1.0 mol kg-1. In this respect the effect of sodium perchlorate on nonionic poly(hydroxyalkyl-L-glutamines) resembles that seen with cationic poly(L-lysine) and poly(L-arginine). Helix stabilization at low sodium perchlorate activity is moderate for poly(hydroxybutyl-L-glutamine) and large for poly(hydroxypropyl-L-glutamine) and poly(hydroxyethyl-L-glutamine).
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1980.360191102
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  • 10
    Electronic Resource
    Electronic Resource
    Calculated microwave absorption of double-helical B-conformation poly(dG)·poly(dC) (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 853-864 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We have estimated the absorption of microwave radiation by the four acoustic modes of poly(dG)·poly(dC) in B conformation. The eigenvectors used in this calculation are those obtained from a refined normal coordinate analysis by fitting the velocity of the longitudinal acoustic mode to that observed by Brillouin scattering. The acoustic modes couple to the radiation field when translational invariance is broken such as for finite segments of helix and as may be the case in vivo. Calculations for various helix lengths show that the estimated absorption is greater than that of water by at least two to three orders of magnitude in some cases.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1981.360200415
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