ISSN:
1435-1536
Keywords:
Polymer adsorption
;
tri(ethyleneglycol) polyacrylate
;
plasmapheresis
;
membrane
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract We study the adsorption of polyacrylate of tri(ethyleneglycol) in water on a plasmapheresis membrane, whose main constituent is a copolymer of acrylonitrile and methylmethacrylate. The amount of adsorbed polymer has a strong dependence on pH. Adsorbance is high at low pH and very low at high pH, while in the intermediate range the interfacial concentration Γ is not a monotonic function of the solution concentrationC. Viscosimetry andUV adsorbance measurements in solution suggest the existence of plurimolecular structures, aggregates, or micelles. We propose a kinetic model, where these latter objects act as detergents at highC and, therefore, contribute to decreasing the interfacial concentration Γ when increasingC.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00654657
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