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  • Springer  (123)
  • Wiley  (51)
  • American Institute of Physics  (47)
  • American Institute of Physics (AIP)  (47)
  • 1990-1994  (268)
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  • 1
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Polyaniline and polyalkylaniline perchlorates were prepared by oxidative coupling polymerization of anilines by the use of copper(II) perchlorate in acetonitrile as an oxidant. The corresponding polymer bases obtained by treating the perchlorates with alkaline solution were soluble in dimethylsulfoxide and partly soluble in tetrahydrofuran. The molecular weights of the THF-soluble components were 2000–6000. The charge transport of the perchlorates is influenced by the chain length and the steric effect of alkyl substituents.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The frequency dependence of the ac susceptibility in polycrystalline samples of YBaCuO has been studied at the ac field range 0.06–1.2 Oe. The curve of the real part of the susceptibility χ' exhibits two drops, the first one close to Tc and the other well below Tc which could correspond to screening behavior of the grains and grain boundaries, respectively. The imaginary part of the susceptibility shows only a peak below Tc which is related to hysteresis losses at the grain boundaries. The peak corresponding to intragrains hysteresis losses is very small and appears masked by the losses of the intergrains. In the range of 1–20 kHz, the onset temperature of χ' showed no frequency dependence. However, the width of the transition decreases lightly and there is a small shift in the peak of χ‘ to higher temperature as the frequency increases. This behavior could be explained in terms of the thermally activated Anderson flux creep. The shift depends on the amplitude of the measuring field. The activation energy for flux creep ranges from 6.4 eV at 0.02 Oe to 3.23 eV at 1.2 Oe in the zero-field-cooled measurements and from 3.41 eV at 0.02 Oe to 1.41 eV at 1.2 Oe in the field-cooled measurements.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 2749-2752 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Molecular beam epitaxy of Er-doped CaF2 layers on (100)oriented CaF2 substrates was performed using CaF2 and ErF3 evaporation cells. The effect of growth temperature and Er concentration on the distribution of the different emission centers observed in these epitaxial Er-doped layers was investigated. Photoluminescence analyses were performed in the 830–860 nm wavelength range in which the 4S3/2→4I13/2 transitions of the Er3+ ions take place. The evolution of the relative emission intensity between single and aggregate Er3+ centers as a function of growth temperature shows that the emission from isolated Er3+ ions is favored in a growth temperature range of 500–520 °C. Emission lines from complex Er3+ centers are found to rise relative to those of isolated sites as Er concentration increases. Finally, no quenching of the integrated luminescence intensity occurs in the concentration range investigated, 0.05–6 mol % (0.1–16 wt%).
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 7797-7804 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Local vibrational modes (LVM) of Si in substitutional sites have been observed by resonant Raman spectroscopy in highly doped (≥8×1018 cm−3) InxGa1−xAs layers, either relaxed or under strain, on [100] GaAs substrates. The peak frequency ωLVM of the Si on Ga site (SiGa) LVM in unstrained samples shifts to lower values with increasing In content. For x≤0.10 this shift is clearly higher than expected from a linear interpolation between the measured values in the binaries. The comparison between the SiGa peak frequency measured in both a full strained layer and a relaxed layer with similar composition provides a rough determination of the deformation potentials for the SiGaLVM in these layers: q/ω2LVM=−2.7±1 and p/ω2LVM=−2.5±1. As the In content becomes higher the width of the SiGa peak increases much more than that of the GaAs-like longitudinal optical-phonon peak, revealing the splitting due to the loss of local symmetry introduced by the In. New calibration factors for the Si-defect concentrations have been deduced, which allow estimation of the solubility limit for the Si incorporation in substitutional positions, which ranges from 2.3×1019 to 2.6×1019 cm−3 for the layers at the growth conditions used. The analysis of the integrated intensity of the LVM Raman peaks indicates that the degree of electrical compensation is clearly reduced for increasing In up to x≤0.05, due to both an increase of the solubility limit for Si in these layers and a saturation or slight reduction of the SiAs-related defect concentrations. This conclusion is also supported by Hall and plasmon measurements. © 1994 American Institute of Physics.
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The use of room- and low-temperature photoluminescence (PL) spectroscopy for the assessment of n-type pseudomorphic AlGaAs/InGaAs/GaAs high-electron-mobility transistor structures is reported. We describe a method to determine the InAs mole fraction x, the channel layer thickness L, and the confined two-dimensional electron gas density (ns), based on the comparison between the PL transitions and the recombination energies derived from self-consistent calculations of the subband structure. A detailed analysis of the optical transitions and their dependence on the Fermi level position and temperature is performed. It is shown that, in real devices, the high sensitivity of the recombination energies and intensities on small changes of the parameters x, L, and ns allows us to detect deviations from their nominal structural parameters within the uncertainty of the molecular beam epitaxy growth technique. The present assessment procedure has been applied to a significant number of samples, and it has been backed by independent measurements of these parameters by more sophisticated techniques such as Shubnikov–de Haas and PL excitation in standard and gated samples, and by physical techniques like transmission electron microscopy and Auger spectroscopy.
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: By embedding piezoelectric InGaAs/GaAs multiple quantum wells (MQWs) in specifically designed p-i-n structures, we demonstrate that the nonlinear optical response can be used to identify the dominant screening mechanisms and simultaneously to determine the strain distribution. Furthermore, we show that a knowledge of the screening mechanisms and spatial band structure, in turn, can be used to control the nonlinear optical response. For this demonstration, we fabricate two p-i(MQW)-n samples on [111]-oriented GaAs substrates. The samples are designed such that, if the dominant screening is associated with photogenerated carriers that remain in the wells, a blue shift of the exciton would be expected in each. By contrast, if the screening is associated with carriers that have escaped the wells and moved to screen the entire MQW, one will shift to the blue and the other to the red if the lattice is mechanically clamped, but both will shift to the red if the lattice is mechanically free. The observation of a blue shift and a red shift indicates that, while in-well screening may be present, the dominant screening is out-of-well and that these particular structures are mechanically clamped to the lattice constant of the GaAs. Most importantly, these results illustrate the added flexibility that the piezoelectric field gives in tailoring the nonlinear optical response. © 1994 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 270-273 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: CaF2:Er layers have been grown by molecular-beam epitaxy on (100)-oriented CaF2 substrates; the Er concentration ranges from 1% to 50% (mole fraction). The 1.54 μm emission observed under excitation around 800 nm was studied by photoluminescence. Up to 35% Er concentration the integrated emission increases monotonously, quenching appearing for higher doping levels. Photoluminescence results are discussed within the framework of previous studies of Er3+ emission in the near-infrared range (830–860 nm) in order to gain insight into the Er centers involved in the 1.54 μm emission.
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 5136-5139 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In this short note we describe a novel method, based upon the Kirkwood equation, for doing free energy simulations in asymmetric molecular systems typical of those encountered with supercritical fluid mixtures involving large organic species solvated in a lighter supercritical gas. The rationale behind this modified Kirkwood approach has been to develop simulation procedures that are both accurate and stable, by minimizing the perturbation to the system that is implicit to all perturbation-based simulation methods. A good example of an algorithm in this latter class of methods is the free energy perturbation method (FEP) which has been used in this work for comparative purposes with our proposed technique which we refer to as the modified Kirkwood coupling method (MKC). The MKC approach described here effectively makes the perturbation process in the simulation process vanishingly small and appears to result in a stable, accurate algorithm for free energy calculations in chemical mixtures. Numerical results supporting these conclusions are provided in two Lennard-Jones model systems at supercritical conditions.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 6979-6980 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Electron paramagnetic resonance studies performed at room temperature in Mn2+ doped Cs2NaLaCl6 single crystals (elpasolite type) showed that the Mn2+ ion occupies two different tetragonal symmetry sites in a cubic crystalline lattice. Both sites possess principal Z-axes along 〈100〉 crystallographic directions with large splittings (≈1.0 cm−1 and ≈0.8 cm−1) of the spectra. Several facts are taken into account in order to establish tentative models for the structural configuration of the two sites.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 65 (1994), S. 2153-2154 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The design of two small, compact and portable cells for EXAFS measurements of liquids is presented. One of the cells has been optimized for transmission measurements and the other for fluorescence. The sample chamber of both cells has been designed metal free to avoid corrosion by acids or bases. Materials and construction of the cell are such that their cost is quite low. The cells have been tested by recording EXAFS spectra of ionic aqueous solutions.
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