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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 3200-3207 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work presents a study of the distribution of Yb3+ ions in LiNbO3 and LiNbO3:MgO using cooperative luminescence as a probe. The cooperative rate is measured as a function of Yb3+ concentration in the samples. After comparing the experimental results with simple possibilities for rare earth distribution, a model for the distribution of Yb3+ ions is proposed, in which a fraction of the dopant ions forms pairs with an Yb3+ ion placed at Li+ site and the other one at Nb5+ site, while the rest of the ions are randomly placed at Li+ sites. Moreover, the codoping with MgO enhances the cooperative emission and this is discussed in terms of a more efficient redistribution of Yb3+ ions to Nb5+ sites. © 2001 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 499-503 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The incorporation of Nd3+ in CaF2 layers grown on Si and GaAs substrates by molecular beam epitaxy is studied by photoluminescence spectroscopy. The results are in qualitative agreement with those obtained on CaF2:Nd homoepitaxial layers. A lower emission intensity (∼70%) at λ=1.0475 μm is attributed to residual stress and crystalline defects. Concentration quenching of photoluminescence appears at concentrations higher than 3.6 wt % Nd. The use of (Ca,Sr)F2 for lattice matching to GaAs leads to a significant inhomogeneous broadening of Nd3+ emissions due to disorder in the cationic sublattice.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 270-273 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: CaF2:Er layers have been grown by molecular-beam epitaxy on (100)-oriented CaF2 substrates; the Er concentration ranges from 1% to 50% (mole fraction). The 1.54 μm emission observed under excitation around 800 nm was studied by photoluminescence. Up to 35% Er concentration the integrated emission increases monotonously, quenching appearing for higher doping levels. Photoluminescence results are discussed within the framework of previous studies of Er3+ emission in the near-infrared range (830–860 nm) in order to gain insight into the Er centers involved in the 1.54 μm emission.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 2749-2752 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Molecular beam epitaxy of Er-doped CaF2 layers on (100)oriented CaF2 substrates was performed using CaF2 and ErF3 evaporation cells. The effect of growth temperature and Er concentration on the distribution of the different emission centers observed in these epitaxial Er-doped layers was investigated. Photoluminescence analyses were performed in the 830–860 nm wavelength range in which the 4S3/2→4I13/2 transitions of the Er3+ ions take place. The evolution of the relative emission intensity between single and aggregate Er3+ centers as a function of growth temperature shows that the emission from isolated Er3+ ions is favored in a growth temperature range of 500–520 °C. Emission lines from complex Er3+ centers are found to rise relative to those of isolated sites as Er concentration increases. Finally, no quenching of the integrated luminescence intensity occurs in the concentration range investigated, 0.05–6 mol % (0.1–16 wt%).
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 5876-5880 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The fluorescence (excitation and emission) spectra of Nd3+ ions in gadolinium gallium garnet (GGG):Nd and GGG:Nd,Cr have been investigated in the spectral region of laser interest, 4F3/2→4I11/2 transitions. Four sites, denoted as α, β, γ, and δ are present in GGG:Nd, while two additional sites, ε and ζ, appear in GGG:Nd,Cr crystals. Site selective excitation (by using a Ti-sapphire laser) has permitted to obtain the energy level values for each Nd3+ site. This information is necessary for making lasers with these materials. Thus, it has been determined that the γ site is the responsible for laser action in the GGG:Nd minilasers.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 4485-4489 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Nd3+-doped CaF2 monocrystalline films have been grown by molecular-beam epitaxy using CaF2 and NdF3 evaporation on CaF2 (100) substrates. Auger electron spectrometry and high-energy electron diffraction have been used as in situ techniques to characterize the grown layers. No degradation of crystallinity was observed even for the highest levels of doping considered. The effect of Nd3+ concentration is studied by means of the photoluminescence signal of Nd3+ ions. The results can be compared favorably with those of bulk CaF2:Nd crystals. For a given Nd3+ concentration a lower quantity of Nd3+ aggregate centers is observed. Nd3+ ions can, therefore, be efficiently incorporated in isolated Nd3+-F− centers up to concentrations of 3.7 wt % Nd3+ without emission quenching of the associated line at 1.0457 μm. The results are related to the thermodynamic conditions imposed by the molecular-beam epitaxy technique.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 736-740 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The photoluminescence (excitation, emission, and fluorescence decay time) spectra of spinel (Ti:MgAl2O4) excited by pulsed Nd:YAG and dye lasers have been systematically investigated. Excitation into the T2g→Eg crystal-field transition of Ti3+ produces a broad infrared emission band at 805 nm which could, in principle, be used for tunable laser applications. Two different Ti3+ centers with lifetimes of 4.2 and 41 μs contribute to this emission. At the same time this IR band can also be observed under high-intensity excitation in the ultraviolet region (266 nm) via a two-photon process.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 4056-4062 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The laser performance of the nonlinear Yb3+:MgO:LiNbO3 crystal is assessed under Ti:sapphire laser pumping. Spectral properties related to infrared laser action such as the emission and absorption cross sections have been evaluated. Different crystallographic configurations have been used. Laser oscillation in the near infrared region has been observed along the crystallographic c axis and along the type I phase matching direction for infrared to green generation. High slope efficiency in the infrared region (62%) and the possibility of low laser thresholds (14.7 mW) are demonstrated. By using a birefringent filter, broadband tuning from 1030 to 1070 nm is obtained in this system. In addition, 58 mW of green power by self-frequency doubling of infrared laser emission is achieved, revealing the potential of LiNbO3:MgO as a self-frequency-doubling material. © 2000 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 74 (1999), S. 3113-3115 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Stable continuous-wave laser action in the near-infrared and in the green spectral region has been obtained in a self-frequency doubling solid-state laser, the Yb3+:MgO:LiNbO3 nonlinear crystal. By pumping with a Ti:sapphire laser and using a nearly concentric cavity, laser action at 1.06 μm was achieved with an absorbed power threshold of 101 mW and efficiency around 47%. As much as 60 mW of self-frequency-doubled radiation at 530 nm was also obtained with absorbed pump powers of 800 mW in critical cavity alignment. Efficient laser action was also obtained in the near-infrared region under pumping with diode laser. © 1999 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 76 (2000), S. 1374-1376 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Continuous-wave laser action from an Yb3+ doped periodically poled LiNbO3:MgO bulk crystal at 1.06 μm is reported. In addition, efficient and stable self-frequency-doubled laser action at 531 nm was obtained by quasiphase matching. Up to 10.5 mW of green output power is obtained from a total laser output power of 58 mW. The experiments were carried out by end pumping with a Ti:sapphire laser, as a surrogate source for a diode laser, at 980 nm. Laser operation was stable at room temperature. The results are compared with those corresponding to single-domain Yb-doped crystals. © 2000 American Institute of Physics.
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