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Divalent manganese in two different tetragonal sites of Cs2NaLaCl6 (1994)

Quintanar, C. ; Gleason, R. J. ; Boldú, J. L. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 100 (1994), S. 6979-6980

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Electron paramagnetic resonance studies performed at room temperature in Mn2+ doped Cs2NaLaCl6 single crystals (elpasolite type) showed that the Mn2+ ion occupies two different tetragonal symmetry sites in a cubic crystalline lattice. Both sites possess principal Z-axes along 〈100〉 crystallographic directions with large splittings (≈1.0 cm−1 and ≈0.8 cm−1) of the spectra. Several facts are taken into account in order to establish tentative models for the structural configuration of the two sites.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.467016

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