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  • Articles  (7)
  • Wiley-Blackwell  (7)
  • 1980-1984  (7)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 4 (1983), S. 556-562 
    ISSN: 0192-8651
    Keywords: Computational Chemistry and Molecular Modeling ; Biochemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Notes: A method is presented for counting the number of resonance structures for large benzenoid polynuclear hydrocarbons. Structure counts for even systems are made and compared with those of the odd systems resulting from the removal of one of the π centers from various points in the even structure. A computer program for performing the calculations is also given.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 3 (1981), S. 215-218 
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An approach to simplifying die design for rigid PVC is proposed. Previous work, in this area, has been considered too complicated to be of use to the average die designer. It is hoped that the provided information, simplified equations and tabular format can make it easier to achieve good dies for this important processing technique.
    Additional Material: 2 Ill.
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  • 3
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Fast Atom Bombardment mass spectra of a number of xanthane dyes are reported. These dyes are insufficiently volatile to give spectra by conventional electron impact ionization. Fragmentation pathways have been determined by metastable linked scan techniques and accurate masses obtained by peak matching. The xanthane dyes may be readily identified from their FAB spectra by the presence of characteristic ions.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 17 (1983), S. 395-410 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The flexural strength, microstructure and relative Ca and Si concentration at the surface of two commercial orthopedic aluminas were studied before and after aging up to 52 weeks in simulated body fluids or in subcutaneous implantation in rodents. There was no significant reduction in flexural strength after aging, but there was evidence of Ca and Si dissolution from the external grain boundary surfaces, particularly for specimens aged in demineralized water. No change occurred in the Ca and Si concentrations within the specimen's bulk during either in vivo or in vitro aging.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 11 (1981), S. 363-368 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The temperature dependence of the Raman spectrum of potassium perrhenate is reported. Some new detailed results on the temperature dependence of the low frequency Raman bands of ammonium perrhenate are also presented. The frequency versus temperature plots for both internal and external modes of the ReO4- ion in KReO4 appear to be linear over the temperature range from 20 to 300 K. This is in contrast to the non-linear behaviour of the external modes of the ReO4- ion in NH4ReO4. A crossing of the frequencies of the Ag and Eg librational modes of the ReO4- ion in NH4ReO4 occurs near 200 K, the temperature at which anomolies have been observed in the temperature dependence of several physical properties of this salt. The apparent discontinuities near 200 K in the slopes of the wavenumber versus temperature curves reported earlier1 are now shown to be shoulders on smooth curves. Extrapolation of the frequency versus temperature plots of the Eg and Bg translational modes of the ReO4- ion in KReO4 indicates that a crossing of the curves would occur at about 500 K, while for NH4ReO4 the crossing of the frequencies of these modes is observed near 200 K. The significance of these observations with respect to the structure and a possible higher order phase transition in the NH4ReO4 crystal is discussed.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 13 (1982), S. 53-55 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The pressure dependences at room temperature of the translational lattice modes and of the ν2 and ν4 internal bending modes of the ReO4- ion in solid NH4ReO4 are reported. There is no evidence of any phase transition up to a pressure of 15 kilobar. The pressure coefficients of the translational modes are 2.0 cm-1 GPa-1 and 3.0 cm-1 GPa-1 for the Bg and Eg modes respectively. The pressure coefficients of the bending modes are 1.0 cm-1 GPa-1 and 5.4 cm-1 GPa-1 for the Bg and Ag components of ν2, and 4.1 cm-1 for the overlapped Bg and Eg components of ν4.The symmetry assignments of the low frequency lines in the spectrum were checked by means of polarized Raman spectra of a single crystal. The previous assignments are correct.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 9 (1980), S. 28-32 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Raman spectra of NH4IO4 and ND4IO4 have been recorded at several temperatures between 83 K and 371 K. As the temperature is increased, several bands due to both internal and external modes of the periodate ion are shifted to lower wavenumbers. There is a crossing of the Ag and Eg librational modes of the IO4-ion near 200 K. The bands due to the ammonium ion vibrations are broadened as the temperature is increased and the librational lattice mode is no longer observable above about 200 K. The present results are correlated with observations from NQR, NMR and X-ray diffraction studies.
    Additional Material: 6 Ill.
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