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The Raman spectrum of ammonium meta-periodate (1980)

Shurvell, H. F. ; Brown, R. J. C. ; Korppi-Tommola, J.

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 9 (1980), S. 28-32

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Raman spectra of NH4IO4 and ND4IO4 have been recorded at several temperatures between 83 K and 371 K. As the temperature is increased, several bands due to both internal and external modes of the periodate ion are shifted to lower wavenumbers. There is a crossing of the Ag and Eg librational modes of the IO4-ion near 200 K. The bands due to the ammonium ion vibrations are broadened as the temperature is increased and the librational lattice mode is no longer observable above about 200 K. The present results are correlated with observations from NQR, NMR and X-ray diffraction studies.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250090108

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