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  • 1
    Publikationsdatum: 2015-05-16
    Beschreibung: In porous media, the nonwetting phase is trapped on water saturation due to capillary forces acting in a heterogeneous porous structure. Within the capillary fringe, the gas phase is trapped and released along with the fluctuation of the water table, creating a highly active zone for biological transformations and mass transport. We conducted column experiments to observe and quantify the magnitude and structure of the trapped gas phase at the pore scale using computed microtomography. Different grain size distributions of glass beads were used to study the effect of the pore structure on trapping at various capillary numbers. Viscous forces were found to have negligible impact on phase trapping compared with capillary and buoyancy forces. Residual gas saturations ranged from 0.5 to 10%, while residual saturation increased with decreasing grain size. The gas phase was trapped by snap-off in single pores but also in pore clusters, while this single-pore trapping was dominant for grains larger than 1 mm in diameter. Gas surface area was found to increase linearly with increasing gas volume and with decreasing grain size.
    Digitale ISSN: 1539-1663
    Thema: Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2015-06-17
    Beschreibung: We investigated the inflammatory response, acute phase response and genotoxic effect of diesel exhaust particles (DEPs, NIST1650b) following a single intratracheal instillation. C57BL/6J BomTac mice received 18, 54 or 162 µg/mouse and were killed 1, 3 and 28 days post-exposure. Vehicle controls and the benchmark particle carbon black (CB, Printex 90; 162 µg/mouse) were tested alongside for comparison. The cellular composition and protein concentration were determined in bronchoalveolar lavage (BAL) fluid as markers for an inflammatory response. Pulmonary and systemic genotoxicity was analysed by the alkaline comet assay as DNA strand breaks in BAL cells, lung and liver tissue. The pulmonary acute phase response was analysed by Saa3 mRNA levels by real-time quantitative polymerase chain reaction. Instillation of DEP induced a strong neutrophil influx 1 and 3 days, but not 28 days post-exposure. Saa3 mRNA levels were increased at all time point for the highest dose and 28 days post-exposure for the middle dose. DEP increased levels of DNA strand breaks in lung tissue for all doses 1 day post-exposure and after 28 days for mid- and high-dose groups. Pulmonary exposure to DEP induced transient inflammation but long-lasting pulmonary acute phase response as well as genotoxicity in lung tissue 28 days post-exposure. The observed long-term pulmonary genotoxicity by DEP was less than the previously observed genotoxicity for CB using identical experimental set-up.
    Print ISSN: 0267-8357
    Digitale ISSN: 1464-3804
    Thema: Biologie , Medizin
    Publiziert von Oxford University Press
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2015-06-18
    Beschreibung: Author(s): A. Kartavtsev, G. Raffelt, and H. Vogel Neutrinos propagating in media (matter and electromagnetic fields) undergo flavor and helicity oscillations, where helicity transitions are instigated both by electromagnetic fields and matter currents. In addition, it has been shown that correlations between neutrinos and antineutrinos of opposite ... [Phys. Rev. D 91, 125020] Published Tue Jun 16, 2015
    Schlagwort(e): Field Theory, Formal Particle Theory
    Print ISSN: 0556-2821
    Digitale ISSN: 1089-4918
    Thema: Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2019
    Beschreibung: Abstract Mineral dust is a key player in the Earth system that affects the weather and climate through absorbing and scattering the radiation. Such effects strongly depend on the optical properties of the particles that are in turn affected by the particle shape. For simplicity, dust particles are usually assumed to be spherical. But this assumption can lead to large errors in modeling and remote sensing applications. This study investigates the impact of dust particle shape on its direct radiative effect in a next‐generation atmospheric modeling system ICON‐ART (ICOsahedral Nonhydrostatic with Aerosols and Reactive Trace gases) to verify if accounting for non‐sphericity enhances the model‐observation agreement. Two sets of numerical experiments are conducted by changing the optical shape of the particles: one assuming spherical particles and the other one assuming a mixture of 35 randomly oriented tri‐axial ellipsoids. The simulations are compared to MISR, AERONET and CALIPSO observations (with focus on North Africa). The results show that consideration of particle non‐sphericity increases the dust AOD at 550 nm by up to 28% and leads to slight enhancement of the agreement between modeled and measured AOD. However, the model performance varies significantly when focusing on specific regions in North Africa. These differences stem from the uncertainties associated with particle size distribution and emission mechanisms in the model configuration. Regarding the attenuated backscatter, the simulated profile assuming non‐sphericity differs by a factor of 2 to 5 from the experiment assuming spherical dust, and is in a better agreement with the CALIPSO observations.
    Print ISSN: 2169-897X
    Digitale ISSN: 2169-8996
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley im Namen von American Geophysical Union (AGU).
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2017-07-14
    Beschreibung: Interest in energy storage technologies is still increasing in times of the excess of electricity that is generated by wind farms or solar plants. Solar electricity can be transformed to solar-hydrogen via water electrolysis. A crucial part of the energy storage technologies plays the efficient conversion of H 2 and CO 2 from renewable resources. Here, the process conditions for continuously catalytic hydrogenation of CO 2 to CH 3 OH under supercritical conditions over lab-synthesized Cu/ZnO/Al 2 O 3  catalysts were investigated. The impact of temperature (230 – 330 °C), residence time (0.5 - 2.2 s) at moderate pressure (150 bar) but even above the supercritical parameters of CO 2 showed a selective CO 2 hydrogenation. Higher H 2 concentrations, respectively higher H 2 :CO 2 -ratios (H 2 :CO 2  = 6), lead to an increased selectivity of CH 3 OH. A possible in situ phase separation of reaction products within the reactor due to the higher densities of the reaction mixture by the highered pressure could affect the kinectics and simplfy the down-stream processing. The combination of thermodynamic studies (phase separation phenomena) as well as the catalytic performance tests for the CO2 hydrogenation under supercritical conditions are discussed. Based on these data a process concept is presented.
    Print ISSN: 0930-7516
    Digitale ISSN: 1521-4125
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Publiziert von Wiley
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2020-02-24
    Beschreibung: The bulk magnetic mineral record from Lake Ohrid, spanning the past 637 kyr, reflects large-scale shifts in hydrological conditions, and, superimposed, a strong signal of environmental conditions on glacial–interglacial and millennial timescales. A shift in the formation of early diagenetic ferrimagnetic iron sulfides to siderites is observed around 320 ka. This change is probably associated with variable availability of sulfide in the pore water. We propose that sulfate concentrations were significantly higher before 320 ka, due to either a higher sulfate flux or lower dilution of lake sulfate due to a smaller water volume. Diagenetic iron minerals appear more abundant during glacials, which are generally characterized by higher Fe = Ca ratios in the sediments. While in the lower part of the core the ferrimagnetic sulfide signal overprints the primary detrital magnetic signal, the upper part of the core is dominated by variable proportions of high- to low-coercivity iron oxides. Glacial sediments are characterized by high concentration of high-coercivity magnetic minerals (hematite, goethite), which relate to enhanced erosion of soils that had formed during preceding interglacials. Superimposed on the glacial–interglacial behavior are millennial-scale oscillations in the magnetic mineral composition that parallel variations in summer insolation. Like the processes on glacial–interglacial timescales, low summer insolation and a retreat in vegetation resulted in enhanced erosion of soil material. Our study highlights that rock-magnetic studies, in concert with geochemical and sedimentological investigations, provide a multi-level contribution to environmental reconstructions, since the magnetic properties can mirror both environmental conditions on land and intra-lake processes.
    Beschreibung: Published
    Beschreibung: 2093–2109
    Beschreibung: 1A. Geomagnetismo e Paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): Environmental magnetism Pleistocene Lake Ohrid ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Fresenius' Zeitschrift für analytische Chemie 83 (1931), S. 221-222 
    ISSN: 1618-2650
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    European journal of wildlife research 5 (1956), S. 143-146 
    ISSN: 1439-0574
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Parasitology research 6 (1933), S. 308-322 
    ISSN: 1432-1955
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Zusammenfassung Unter dem Einfluß hoher Gaben von Calcinosefaktor (= Bestrahlungsderivat des Ergosterins) konnten bei Infektionen mit Muskeltrichinellen,Cysticercus pisiformis undC. fasciolaris, Eimeria Stiedae experimentelle Kalkablagerungen im Wirtsgewebe in der Nähe der Parasiten erzielt werden, während solche bei Infektionen mitSchistosoma-Eiern,Schizotrypanum und Sarcosporidien ausblieben. Bei Muskeltrichinellen setzte eine experimentelle Verkalkung der Kapsel schon 2–3 Monate nach der Infektion ein, zu einer Zeit, nach derSpontanverkalkungen noch nicht auftraten. Die Verkalkungen betrafen im Falle vonCysticercus pisiformis nekrotisches Lebergewebe, und sind wahrscheinlich als unspezifische Reaktionen zu betrachten, denn entsprechende Verkalkungsbilder ließen sich durch Einführung von Fäden in die Leber und anschließende überdosierung erzielen. In den übrigen positiven Fallen dürfte mit einem spezifischen Einfluß vonseiten der Parasiten zu rechnen sein. Einlagerungen im Innern der Parasiten, die mit Wahrscheinlichkeit als Kalk anzusprechen waren, fanden wir nur bei denSchistosoma-Eiern.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Parasitology research 5 (1933), S. 425-431 
    ISSN: 1432-1955
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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