ALBERT

Description: Hydrogen (δ2H) and oxygen (δ18O) isotopes of water extracted from speleothem fluid inclusions are important proxies used for paleoclimate reconstruction. In our study we use a cavity ring-down laser spectroscopy system for analysis and modified the approach of Affolter et al. (2014) for sample extraction. The method is based on crushing of small sub-gram speleothem samples in a heated and continuously water-vapour purged extraction line. The following points were identified: Injection of reference water shows a precision (1σ) of 0.4–0.5 ‰ for δ18O values and 1.1–1.9 ‰ for δ2H values for water amounts of 0.1–0.5 μl, which improves with increasing water amount to 0.1–0.3 ‰ and 0.2–0.7 ‰, respectively, above 1 μl. The accuracy of measurements of water injections and water-filled glass capillaries crushed in the system is better than 0.08 ‰ for δ18O and 0.3 ‰ for δ2H values. The reproducibility (1σ) based on replicate analysis of speleothem fluid inclusion samples with water amounts 〉0.2 μl is 0.5 ‰ for δ18O and 1.2 ‰ for δ2H values, respectively. Isotopic differences between the water vapour background of the extraction system and the fluid inclusions have no significant impact on the measured fluid inclusion isotope values if they are within 10 ‰ for δ18O and 50 ‰ for δ2H values of the background. Tests of potential adsorption effects with inclusion free spar calcite confirm that the isotope values are unaffected by adsorption for water contents of about 1 μl (fluid inclusion) water per g of carbonate or above. Fluid inclusion analysis on three different modern to late Holocene speleothems from caves in northwest Germany resulted in δ18O and δ2H values that follow the relationship as defined by the meteoric water line and that correspond to the local drip water. Yet, due to potential isotope exchange reactions for oxygen atoms, hydrogen isotope measurements are preferentially to be used for temperature reconstructions. We demonstrate this in a case study with a Romanian stalagmite, for which we reconstruct the 20th century warming with an amplitude of approximately 1 °C, with a precision for each data point of better than ±0.5 °C.

Description: Previous glacial intervals were punctuated by abrupt climate transitions between cold (stadial) and warm (interstadial) conditions. Many mechanisms leading to stadial-interstadial variability have been hypothesized with ice volume being a commonly involved element. Here, we test to which extent insolation modulated stadial-interstadial oscillations occurred during the penultimate glacial. We present a replicated and precisely dated speleothem record covering the period between 200 and 130 ka before present from caves located in the European Alps known to be sensitive to millennial-scale variability. We show that the widely proposed relationship between sea level change and stadial-interstadial variability was additionally modulated by solar insolation during this time interval. We find that interstadials occurred preferentially near maxima of Northern Hemisphere summer insolation, even when sea level remained close to its minimum during peak glacial periods. We confirm these observations with model simulations that accurately reproduce the frequency and duration of interstadials for given sea-level and insolation forcing. Our results imply that summer insolation played an important role in modulating the occurrence of stadial-interstadial oscillations and highlight the relevance of insolation in triggering abrupt climate changes.

Description: Mountain glaciers are sensitive recorders of natural and human-induced climate change. Therefore, it is imperative to obtain a comprehensive understanding of the interplay between climate and glacier response on both short and long timescales. Here we present an analysis of oxygen and carbon isotope data from speleothems formed mainly below a glacier-covered catchment in the Alps 300,000 to 200,000 years ago. Isotope-enabled climate model simulations reveal that δ18O of precipitation in the Alps was higher by approximately 1 ‰ during interstadials compared to stadials. This agrees with interstadial-stadial amplitudes of our new speleothem-based estimate after correcting for cave-internal effects. We propose that the variability of these cave-internal effects offers a unique tool for reconstructing long-term dynamics of warm-based Alpine palaeoglaciers. Our data thereby suggests a close link between North Atlantic interstadial-stadial variability and the meltwater dynamics of Alpine glaciers during Marine Isotope Stage 8 and 7d.