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  • 2020-2023  (8)
  • 1960-1964  (195)
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  • 1
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Farrell, U. C., Samawi, R., Anjanappa, S., Klykov, R., Adeboye, O. O., Agic, H., Ahm, A.-S. C., Boag, T. H., Bowyer, F., Brocks, J. J., Brunoir, T. N., Canfield, D. E., Chen, X., Cheng, M., Clarkson, M. O., Cole, D. B., Cordie, D. R., Crockford, P. W., Cui, H., Dahl, T. W., Mouro, L. D., Dewing, K., Dornbos, S. Q., Drabon, N., Dumoulin, J. A., Emmings, J. F., Endriga, C. R., Fraser, T. A., Gaines, R. R., Gaschnig, R. M., Gibson, T. M., Gilleaudeau, G. J., Gill, B. C., Goldberg, K., Guilbaud, R., Halverson, G. P., Hammarlund, E. U., Hantsoo, K. G., Henderson, M. A., Hodgskiss, M. S. W., Horner, Tristan J., Husson, J. M., Johnson, B., Kabanov, P., Brenhin K. C., Kimmig, J., Kipp, M. A., Knoll, A. H., Kreitsmann, T., Kunzmann, M., Kurzweil, F., LeRoy, M. A., Li, C., Lipp, A. G., Loydell, D. K., Lu, X., Macdonald, F. A., Magnall, J. M., Mänd, K., Mehra, A., Melchin, M. J., Miller, A. J., Mills, N. T., Mwinde, C. N., O'Connell, B., Och, L. M., Ossa Ossa, F., Pagès, A., Paiste, K., Partin, C. A., Peters, S. E., Petrov, P., Playter, T. L., Plaza-Torres, S., Porter, Susannah M., Poulton, S. W., Pruss, S. B., Richoz, S., Ritzer, S. R., Rooney, A. D., Sahoo, S. K., Schoepfer, S. D., Sclafani, J. A., Shen, Y., Shorttle, O., Slotznick, S. P., Smith, E. F., Spinks, S., Stockey, R. G., Strauss, J. V., Stüeken, E. E., Tecklenburg, S., Thomson, D., Tosca, N. J., Uhlein, G. J., Vizcaíno, M. N., Wang, H., White, T., Wilby, P. R., Woltz, C. R., Wood, R. A., Xiang, L., Yurchenko, I. A., Zhang, T., Planavsky, N. J., Lau, K. V., Johnston, D. T., Sperling, E. A., The Sedimentary Geochemistry and Paleoenvironments Project. Geobiology. 00, (2021): 1– 12,https://doi.org/10.1111/gbi.12462.
    Description: Geobiology explores how Earth's system has changed over the course of geologic history and how living organisms on this planet are impacted by or are indeed causing these changes. For decades, geologists, paleontologists, and geochemists have generated data to investigate these topics. Foundational efforts in sedimentary geochemistry utilized spreadsheets for data storage and analysis, suitable for several thousand samples, but not practical or scalable for larger, more complex datasets. As results have accumulated, researchers have increasingly gravitated toward larger compilations and statistical tools. New data frameworks have become necessary to handle larger sample sets and encourage more sophisticated or even standardized statistical analyses. In this paper, we describe the Sedimentary Geochemistry and Paleoenvironments Project (SGP; Figure 1), which is an open, community-oriented, database-driven research consortium. The goals of SGP are to (1) create a relational database tailored to the needs of the deep-time (millions to billions of years) sedimentary geochemical research community, including assembling and curating published and associated unpublished data; (2) create a website where data can be retrieved in a flexible way; and (3) build a collaborative consortium where researchers are incentivized to contribute data by giving them priority access and the opportunity to work on exciting questions in group papers. Finally, and more idealistically, the goal was to establish a culture of modern data management and data analysis in sedimentary geochemistry. Relative to many other fields, the main emphasis in our field has been on instrument measurement of sedimentary geochemical data rather than data analysis (compared with fields like ecology, for instance, where the post-experiment ANOVA (analysis of variance) is customary). Thus, the longer-term goal was to build a collaborative environment where geobiologists and geologists can work and learn together to assess changes in geochemical signatures through Earth history.
    Description: We thank the donors of The American Chemical Society Petroleum Research Fund for partial support of SGP website development (61017-ND2). EAS is funded by National Science Foundation grant (NSF) EAR-1922966. BGS authors (JE, PW) publish with permission of the Executive Director of the British Geological Survey, UKRI.
    Keywords: Consortium ; Database ; Earth history ; Geochemistry ; Website
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-10-18
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tamborski, J., Cai, P., Eagle, M., Henderson, P., & Charette, M. Revisiting 228Th as a tool for determining sedimentation and mass accumulation rates. Chemical Geology, 607, (2022): 121006, https://doi.org/10.1016/j.chemgeo.2022.121006.
    Description: The use of 228Th has seen limited application for determining sedimentation and mass accumulation rates in coastal and marine environments. Recent analytical advances have enabled rapid, precise measurements of particle-bound 228Th using a radium delayed coincidence counting system (RaDeCC). Herein we review the 228Th cycle in the marine environment and revisit the historical use of 228Th as a tracer for determining sediment vertical accretion and mass accumulation rates in light of new measurement techniques. Case studies comparing accumulation rates from 228Th and 210Pb are presented for a micro-tidal salt marsh and a marginal sea environment. 228Th and 210Pb have been previously measured in mangrove, deltaic, continental shelf and ocean basin environments, and a literature synthesis reveals that 228Th (measured via alpha or gamma spectrometry) derived accumulation rates are generally equal to or greater than estimates derived from 210Pb, reflecting different integration periods. Use of 228Th is well-suited for shallow (〈15 cm) cores over decadal timescales. Application is limited to relatively homogenous sediment profiles with minor variations in grain size and minimal bioturbation. When appropriate conditions are met, complimentary use of 228Th and 210Pb can demonstrate that the upper layers of a core are undisturbed and can improve spatial coverage in mapping accumulation rates due to the higher sample throughput for sediment 228Th.
    Description: This research was undertaken thanks in part to funding from the Canada First Research Excellence Fund, through the Ocean Frontier Institute. This project was supported by U.S. Geological Survey Coastal and Marine Hazards and Resources Program. Any use of trade, firm or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. PC acknowledges the support of the Natural Science Foundation of China (NSFC) through Grants No. 92058205.
    Keywords: Sedimentation ; Mass accumulation ; Thorium isotopes ; Lead-210 ; Wetlands ; Sea level rise
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tamborski, J. J., Eagle, M., Kurylyk, B. L., Kroeger, K. D., Wang, Z. A., Henderson, P., & Charette: 1774-1792, https://doi.org/10.1002/lno.11721.
    Description: Respiration in intertidal salt marshes generates dissolved inorganic carbon (DIC) that is exported to the coastal ocean by tidal exchange with the marsh platform. Understanding the link between physical drivers of water exchange and chemical flux is a key to constraining coastal wetland contributions to regional carbon budgets. The spatial and temporal (seasonal, annual) variability of marsh pore water exchange and DIC export was assessed from a microtidal salt marsh (Sage Lot Pond, Massachusetts). Spatial variability was constrained from 224Ra : 228Th disequilibria across two hydrologic units within the marsh sediments. Disequilibrium between the more soluble 224Ra and its sediment-bound parent 228Th reveals significant pore water exchange in the upper 5 cm of the marsh surface (0–36 L m−2 d−1) that is most intense in low marsh elevation zones, driven by tidal overtopping. Surficial sediment DIC transport ranges from 0.0 to 0.7 g C m−2 d−1. The sub-surface sediment horizon intersected by mean low tide was disproportionately impacted by tidal pumping (20–80 L m−2 d−1) and supplied a seasonal DIC flux of 1.7–5.4 g C m−2 d−1. Export exceeded 10 g C m−2 d−1 for another marsh unit, demonstrating that fluxes can vary substantially across salt marshes under similar conditions within the same estuary. Seasonal and annual variability in marsh pore water exchange, constrained from tidal time-series of radium isotopes, was driven in part by variability in mean sea level. Rising sea levels will further inundate high marsh elevation zones, which may lead to greater DIC export.
    Description: This research was undertaken thanks in part to funding from the Canada First Research Excellence Fund, through the Ocean Frontier Institute. Additional funding was provided by the U.S. Geological Survey (USGS) Coastal & Marine Geology Program and the USGS Land Change Science Program's LandCarbon program.
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015920, doi:10.1029/2019JC015920.
    Description: A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river‐influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high‐resolution pan‐Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25–50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle‐reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s−1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
    Description: Funding for Arctic GEOTRACES was provided by the U.S. National Science Foundation, Swedish Research Council Formas, French Agence Nationale de la Recherche and LabexMER, Netherlands Organization for Scientific Research, and Independent Research Fund Denmark. Data from GEOTRACES cruises GN01 (HLY1502) and GN04 (PS94) have been archived at the Biological and Chemical Oceanography Data Management Office (Biological and Chemical Oceanography Data Management Office (BCO‐DMO); https://www.bco-dmo.org/deployment/638807) and PANGAEA (https://www.pangaea.de/?q=PS94&f.campaign%5B%5D=PS94) websites, respectively. The inorganic carbon data are available at the NOAA Ocean Carbon Data System (OCADS; doi:10.3334/CDIAC/OTG.CLIVAR_ARC01_33HQ20150809).
    Description: 2020-10-08
    Keywords: Arctic Ocean ; Transpolar Drift ; trace elements ; carbon ; nutrients ; GEOTRACES]
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Mears, C., Thomas, H., Henderson, P. B., Charette, M. A., MacIntyre, H., Dehairs, F., Monnin, C., & Mucci, A. Using Ra-226 and Ra-228 isotopes to distinguish water mass distribution in the Canadian Arctic Archipelago. Biogeosciences, 17(20), (2020): 4937-4959, doi:10.5194/bg-17-4937-2020.
    Description: As a shelf-dominated basin, the Arctic Ocean and its biogeochemistry are heavily influenced by continental and riverine sources. Radium isotopes (226Ra, 228Ra, 224Ra, and 223Ra), are transferred from the sediments to seawater, making them ideal tracers of sediment–water exchange processes and ocean mixing. As the two long-lived isotopes of the radium quartet, 226Ra and 228Ra (226Ra with a t1∕2 of 1600 years and 228Ra with a t1∕2 of 5.8 years) can provide insight into the water mass compositions, distribution patterns, as well as mixing processes and their associated timescales throughout the Canadian Arctic Archipelago (CAA). The wide range of 226Ra and 228Ra activities, as well as of the 228Ra∕226Ra, measured in water samples collected during the 2015 GEOTRACES cruise, complemented by additional chemical tracers – dissolved inorganic carbon (DIC), total alkalinity (AT), barium (Ba), and the stable oxygen isotope composition of water (δ18O) – highlight the dominant biogeochemical, hydrographic, and bathymetric features of the CAA. Bathymetric features, such as the continental shelf and shallow coastal sills, are critical in modulating circulation patterns within the CAA, including the bulk flow of Pacific waters and the inhibited eastward flow of denser Atlantic waters through the CAA. Using a principal component analysis, we unravel the dominant mechanisms and apparent water mass end-members that shape the tracer distributions. We identify two distinct water masses located above and below the upper halocline layer throughout the CAA and distinctly differentiate surface waters in the eastern and western CAA. Furthermore, we highlight water exchange across 80∘ W, inferring a draw of Atlantic water (originating from Baffin Bay) into the CAA. This underscores the presence of an Atlantic water “U-turn” located at Barrow Strait, where the same water mass is seen along the northernmost edge at 80∘ W as well as along the southeasternmost confines of Lancaster Sound. Overall, this study provides a stepping stone for future research initiatives within the Canadian Arctic Archipelago, revealing how quantifying disparities in the distributions of radioactive tracers can provide valuable information on water mass distributions, flow patterns, and mixing within vulnerable areas such as the CAA.
    Description: This research has been supported by Canadian GEOTRACES via NSERC-CCAR, the U.S. GEOTRACES via NSF Chemical Oceanography (grant no. OCE-1458305), and the DAAD, MOPGA-GRI (grant no.57429828).
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Costa, K. M., Hayes, C. T., Anderson, R. F., Pavia, F. J., Bausch, A., Deng, F., Dutay, J., Geibert, W., Heinze, C., Henderson, G., Hillaire-Marcel, C., Hoffmann, S., Jaccard, S. L., Jacobel, A. W., Kienast, S. S., Kipp, L., Lerner, P., Lippold, J., Lund, D., Marcantonio, F., McGee, D., McManus, J. F., Mekik, F., Middleton, J. L., Missiaen, L., Not, C., Pichat, S., Robinson, L. F., Rowland, G. H., Roy-Barman, M., Alessandro, Torfstein, A., Winckler, G., & Zhou, Y. 230 Th normalization: new insights on an essential tool for quantifying sedimentary fluxes in the modern and quaternary ocean. Paleoceanography and Paleoclimatology, 35(2), (2020): e2019PA003820, doi:10.1029/2019PA003820.
    Description: 230Th normalization is a valuable paleoceanographic tool for reconstructing high‐resolution sediment fluxes during the late Pleistocene (last ~500,000 years). As its application has expanded to ever more diverse marine environments, the nuances of 230Th systematics, with regard to particle type, particle size, lateral advective/diffusive redistribution, and other processes, have emerged. We synthesized over 1000 sedimentary records of 230Th from across the global ocean at two time slices, the late Holocene (0–5,000 years ago, or 0–5 ka) and the Last Glacial Maximum (18.5–23.5 ka), and investigated the spatial structure of 230Th‐normalized mass fluxes. On a global scale, sedimentary mass fluxes were significantly higher during the Last Glacial Maximum (1.79–2.17 g/cm2kyr, 95% confidence) relative to the Holocene (1.48–1.68 g/cm2kyr, 95% confidence). We then examined the potential confounding influences of boundary scavenging, nepheloid layers, hydrothermal scavenging, size‐dependent sediment fractionation, and carbonate dissolution on the efficacy of 230Th as a constant flux proxy. Anomalous 230Th behavior is sometimes observed proximal to hydrothermal ridges and in continental margins where high particle fluxes and steep continental slopes can lead to the combined effects of boundary scavenging and nepheloid interference. Notwithstanding these limitations, we found that 230Th normalization is a robust tool for determining sediment mass accumulation rates in the majority of pelagic marine settings (〉1,000 m water depth).
    Description: We thank Zanna Chase and one anonymous reviewer for valuable feedback. K. M. C. was supported by a Postdoctoral Scholarship at WHOI. L. M. acknowledges funding from the Australian Research Council grant DP180100048. The contribution of C. T. H., J. F. M., and R. F. A. were supported in part by the U.S. National Science Foundation (US‐NSF). G. H. R. was supported by the Natural Environment Research Council (grant NE/L002434/1). S. L. J. acknowledges support from the Swiss National Science Foundation (grants PP002P2_144811 and PP00P2_172915). This study was supported by the Past Global Changes (PAGES) project, which in turn received support from the Swiss Academy of Sciences and the US‐NSF. This work grew out of a 2018 workshop in Aix‐Marseille, France, funded by PAGES, GEOTRACES, SCOR, US‐NSF, Aix‐Marseille Université, and John Cantle Scientific. All data are publicly available as supporting information to this document and on the National Center for Environmental Information (NCEI) at https://www.ncdc.noaa.gov/paleo/study/28791.
    Keywords: Thorium ; Sediment flux ; Holocene ; LGM ; GEOTRACES
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Seyler, L., Kujawinski, E. B., Azua-Bustos, A., Lee, M. D., Marlow, J., Perl, S. M., & Cleaves, H. J. Metabolomics as an emerging tool in the search for astrobiologically relevant biomarkers. Astrobiology, (2020), doi:10.1089/ast.2019.2135.
    Description: It is now routinely possible to sequence and recover microbial genomes from environmental samples. To the degree it is feasible to assign transcriptional and translational functions to these genomes, it should be possible, in principle, to largely understand the complete molecular inputs and outputs of a microbial community. However, gene-based tools alone are presently insufficient to describe the full suite of chemical reactions and small molecules that compose a living cell. Metabolomic tools have developed quickly and now enable rapid detection and identification of small molecules within biological and environmental samples. The convergence of these technologies will soon facilitate the detection of novel enzymatic activities, novel organisms, and potentially extraterrestrial life-forms on solar system bodies. This review explores the methodological problems and scientific opportunities facing researchers who hope to apply metabolomic methods in astrobiology-related fields, and how present challenges might be overcome.
    Description: This study was partially supported by the ELSI Origins Network (EON), which is supported by a grant from the John Templeton Foundation. The opinions expressed in this publication are those of the authors and do not necessarily reflect the views of the John Templeton Foundation. This work was partially supported by a JSPS KAKENHI Grant-in-Aid for Scientific Research on Innovative Areas “Hadean Bioscience,” grant number JP26106003, and also partially supported by Project “icyMARS,” funded by the European Research Council, ERC Starting Grant No. 307496. A.A-B thanks the contribution from the Project “MarsFirstWater,” funded by the European Research Council, ERC Consolidator Grant No. 818602 and the HFSP Project UVEnergy RGY0066/2018.
    Keywords: Biomarkers ; Biosignatures ; Metabolism ; Molecular fossils ; Biogeochemistry
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 83 (1961), S. 4671-4672 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 85 (1963), S. 2462-2466 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 32 (1960), S. 796-799 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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