ISSN:
1573-904X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Determinations of log P values of copper complexes in oil/water were performed in a new, totally closed apparatus connected with a filter-probe extractor. The results indicate that the system may be generally suitable for the determination of log P values of oxidizable and nonoxidizable metal complexes. In the case of the copper (I) complexes spectrophotometric analysis was not feasible, since 1-octanol was extracted by these complexes into the aqueous phase, resulting in a change in the extinction coefficient. To establish accurately the concentration in each phase, copper was determined by atomic absorption spectrometry.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1016392123137
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