Publikationsdatum:
2019-01-31
Beschreibung:
Herein we report a novel palladium-catalyzed reaction that results in phenanthrene derivatives using aryl iodides, ortho-bromobenzoyl chlorides and norbornadiene in one pot. This dramatic transformation undergoes ortho-C–H activation, decarbonylation and subsequent a retro-Diels–Alder process. Pleasantly, this protocol has a wider substrate range, shorter reaction times and higher yields of products than previously reported methods.
Print ISSN:
2195-951X
Digitale ISSN:
1860-5397
Thema:
Chemie und Pharmazie
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