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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 339 (1997), S. 637-641 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The treatment of several branched methylchlorooligosilanes (Si4, Si5) with diethylamine leads to a partial or complete substitution of the chloro substituents for diethylamino groups under formation of the first known (diethylamino)-methylchlorooligosilanes containing more than two Si atoms. The condensation of (Et2N)2MeSi—SiMeCl(NEt2) (1d) with Li in THF yields the linear tetrasilane (Et2N)2MeSi—SiMe(NEt2)—SiMe(NEt2)—SiMe(Et2N)2(2a).The NMR investigations provided information of the general shift ranges of several Si units in (diethylamino)-methylchlorooligosilane systems as well as the number of stereoisomers of the prepared products.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2021-08-12
    Description: In this work, silicone/carbon nanotube (CNT) composites were produced using a spread coating process, followed by morphological investigations and determination of their electrical properties and heating behaviour through the application of electric potential. Composites containing varying amounts of CNT (1–7%) were investigated for their thermal behaviour with the use of an IR camera. Subsequently, thermal behaviour and electrical properties were measured when the samples were stretched (up to 20%). With the 7% CNT composites, which had a conductivity of 106 S/m, it was possible to achieve a temperature of 155 °C at a relatively low voltage of 23 V. For high CNT contents, when the potential was controlled in such a way as to maintain the temperature well below 100 °C, the temperature remained almost constant at all levels of strain investigated. At higher potentials yielding temperatures around 100 °C and above, stretching had a drastic effect on temperature. These results are critical for designing composites for dynamic applications requiring a material whose properties remain stable under strain.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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