ISSN:
1572-8927
Keywords:
Equilibrium constants
;
CuCl
;
CuBr
;
complexes
;
Pitzer equations
;
spectral data
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The stoichiometric equilibrium constants, K 3 * , for the formation of CuX 3 2− from CuX 2 − +X− where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45°C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, β0, β1 and Cφ, for the interaction of Na+ with CuX 2 − and CuX 3 2− are briefly discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00648142
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