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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 19 (1968), S. 837-844 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Thermogravimetric method for investigating the solid/gas and melt/gas equilibria in sulphate systems of corrosion-chemical importanceThe authors describe a micro-thermogravimetric method which permits the determination of the phase zones of sulphate systems as a function of temperature and of the SO3-partial pressure. At the Me2SO4—SO3 (Me = Na, K) system, the existence limits of the bi-variant melt and the mono-variant equilibria Me2SO4(solid)-melt and Me2SO4(solid)-Me2S2O7(solid) are determined. Water vapour is dissolved in the melt phases investigated because the existence limits of the latter are modified by the vapour.
    Notes: Es wird eine mikro-thermogravimetrische Methode beschrieben, welche gestattet, die Phasenfelder von Sulfatsystemen als Funktion der Temperatur und des SO3-Partialdrucks zu ermitteln. Am System Me2SO4—SO3 (Me = Na, K) werden die Existenzgrenzen der bivarianten Schmelze und die monovarianten Gleichgewichte Me 2SO4 (fest)-Schmelze und Me2SO4 (fest)-Me2S2O7 (fest) bestimmt. Wasserdampf löst sich in den untersuchten Schmelzphasen, denn ihre Existenzgrenzen werden durch ihn verändert.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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