ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
In the title compound, [Sn(C6H5)2(C12H19N2)]Br·H2O, the SnIV atom lies on a twofold axis and is coordinated by a C and two N atoms from the 2,6-bis[(dimethylamino)methyl]phenyl ligand in a tridentate fashion and by two phenyl groups. The resulting geometry is intermediate between square pyramidal and trigonal bipyramidal, with three C atoms in equatorial and the two N atoms in axial positions. The main deformation from ideal trigonal-bipyramidal geometry is seen for the N—Sn—N angle [152.18 (7)°]. The Br− anion and the water solvate molecule are on an inversion centre and twofold axis, respectively. They form an infinite chain of Br...H—O—H...Br hydrogen bonds [Br...O 3.529 (2) Å] without contributing to the primary coordination sphere of the Sn atom.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101000026
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