Publication Date:
2007-10-10
Description:
In the molecule of the title compound, [TiBr2(C13H14)], the TiIV centre is in a distorted tetrahedral environment involving two η5-bonded cyclopentadienyl rings of a propane-2,2-diyldicyclopentadienyl ligand [Ti—Cg = 2.045 (2) Å; Cg is the centroid of the cyclopentadienyl ring] and two Br atoms [Ti—Br = 2.5115 (7) Å]. The presence of the short 2,2-propylidene bridge between the two cyclopentadienyl rings constrains the Cg—Ti—Cg angle to a value of 121.32 (9)°. The Ti and central C atoms are located on a crystallographic C 2 axis.
Electronic ISSN:
1600-5368
Topics:
Chemistry and Pharmacology
,
Geosciences
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