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  • 1
    Publication Date: 2023-07-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉We present the results of salinity (ΔS) and temperature (ΔT) anomalies in the sea surface microlayer (SML) in relation to the underlying mixed bulk water (bulk). Several light to moderate rain events were recorded in the southern Pacific near Fiji using our remotely operated catamaran. Precipitation and evaporation drive freshwater fluxes across the sea surface (i.e., the SML) and are the most essential processes of the hydrologic cycle. However, measurements of the SML during precipitation are rare, but necessary to fully understand freshwater exchange at the air‐sea interface. Here we show that freshwater can mix rapidly with the bulk water through wind‐induced mixing, as ΔS and ΔT show a clear dependence on wind speed. At high wind speeds (5.1–11.6 m s〈sup〉−1〈/sup〉), anomalies approach zero (ΔS = −0.02 ± 0.49 g kg〈sup〉−1〈/sup〉, ΔT = −0.09 ± 0.46°C) but can reach ΔS = 1.00 ± 0.20 g kg〈sup〉−1〈/sup〉 and ΔT = −0.37 ± 0.09°C at lower wind speeds (0–2 m s〈sup〉−1〈/sup〉). We find shallow freshwater lenses and fronts, likely caused by past rainfall, with ΔS and ΔT of up to −1.11 g kg〈sup〉−1〈/sup〉 and 1.77°C, respectively. Our observations suggest that freshwater lenses can be very shallow (〈1 m depth) and missed by conventional measurements. In addition, the temperature and salinity in the SML respond to freshwater fluxes instantaneously. It highlights the role of the SML in a mechanistic understanding of the fate of freshwater over the ocean and, therefore, the global hydrologic cycle.〈/p〉
    Description: Plain Language Summary: Rain and evaporation are the most important processes in the global water cycle, causing either the supply to or the removal of freshwater from the upper ocean, thereby changing the salinity of the sea surface. Evaporation also removes heat and lowers the temperature on the ocean surface. We used the measurements of sea surface microlayer (SML) salinity and temperature as key indicators to study hydrologic cycle processes during our cruise with the RV Falkor in the South Pacific and found that freshwater mixes rapidly with the underlying bulk water during strong winds (5.1–11.6 m s〈sup〉−1〈/sup〉). We also detected shallow freshwater lenses and fronts, most likely caused by past rainfall, with ΔS and ΔT of up to −1.11 g kg〈sup〉−1〈/sup〉 and 1.77°C, respectively. Our observations suggest that freshwater lenses can occur at the sea surface and that the SML respond to freshwater fluxes instantaneously. It highlights the role of the SML for future studies of the global hydrologic cycle.〈/p〉
    Description: Key Points: Small scale air‐sea interactions (freshwater fluxes) during precipitation were investigated in the southern Pacific. Temperature and salinity anomalies occur with a high spatial variability.Measurements with remote controlled catamaran revealed shallow freshwater lenses, which were not detectable with ship based measurements.
    Description: German Research Foundation
    Description: https://doi.org/10.7284/908805
    Description: https://www.rvdata.us/search/cruise/FK191120
    Description: https://bec.icm.csic.es/
    Description: https://smos-diss.eo.esa.int/
    Description: https://doi.org/10.48670/moi-00165
    Description: https://disc.gsfc.nasa.gov/datasets/GPM_3IMERGHH_06/summary
    Keywords: ddc:551.46 ; salinity and temperature anomalies ; sea surface microlayer ; freshwater fluxes ; global hydrologic cycle ; research catamaran
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2018-05-12
    Description: This paper describes high-resolution in situ observations of temperature and, for the first time, of salinity in the uppermost skin layer of the ocean, including the influence of large surface blooms of cyanobacteria on those skin properties. In the presence of the blooms, large anomalies of skin temperature and salinity of 0.95°C and −0.49 practical salinity unit were found, but a substantially cooler (−0.22°C) and saltier skin layer (0.19 practical salinity unit) was found in the absence of surface blooms. The results suggest that biologically controlled warming and inhibition of salinization of the ocean's surface occur. Less saline skin layers form during precipitation, but our observations also show that surface blooms of Trichodesmium sp. inhibit evaporation decreasing the salinity at the ocean's surface. This study has important implications in the assessment of precipitation over the ocean using remotely sensed salinity, but also for a better understanding of heat exchange and the hydrologic cycle on a regional scale. ©2018. The Authors.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
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  • 3
    Publication Date: 2018-02-13
    Description: We investigated the influence of solar radiation on biogeochemical parameters of the sea surface microlayer (SML), including the spectroscopic composition of FDOM, and biotic and abiotic parameters. We calculated the humification index, biological index, and recently produced material index from the ultraviolet spectra to characterize the dynamic environment of the SML. The humification index ranged from 4 to 14 in the SML and 14 to 22 in underlying water (ULW). An inverse relation for this index as a function of solar radiation was observed, indicating photochemical decomposition of complex molecules present in fluorescent dissolved organic matter (FDOM). The biological index (along Leg 2) ranged from 1.0 to 2.0 for the SML and 1.0 to 1.5 for ULW. The index for recently produced material ranged from 0.25 to 0.8 for the SML and 0.5 to 1.0 for ULW. The FDOM enrichment process of the SML was influenced by the photochemical decomposition of highly aromatic-like fluorophores, as indicated by the calculated indices. Fluorescence intensity increased for humic C peaks (〉0.5 Raman units) in the North Sea samples and for humic M peaks (〉1.0 Raman units) for Jade Bay. Spearman analysis for FDOM enrichment in the SML as a function of PAR (for Leg 2) showed a weak positive correlation (Rho = 0.676, n = 11, p = 0.022). Abundance of small photoautotrophic cells (Rho = 0.782, n = 11, p = 0.045) and of bacteria (Rho = 0.746, n = 11, p = 0.0082) also showed a positive correlation as a function of PAR. Overall, we found positive trends between the intensity of available light and the response of the constituents within the SML, highlighting the role of the surface microlayer as a distinctive habitat characterized by unique photochemical processes.
    Electronic ISSN: 2325-1026
    Topics: Geosciences
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  • 4
  • 5
    Publication Date: 2014-02-19
    Description: Four carbonate system variables were measured in surface waters during a cruise traversing northwestern European shelf seas in the summer of 2011. High resolution surface water data were collected for partial pressure of carbon dioxide (pCO2; using two independent instruments) and pHT, in addition to discrete measurements of total alkalinity and dissolved inorganic carbon. We thus overdetermined the carbonate system (four measured variables, two degrees of freedom) which allowed us to evaluate the level of agreement between the variables. Calculations of carbonate system variables from other measurements generally compared well (Pearson's correlation coefficient always ≥ 0.94; mean residuals similar to the respective uncertainties of the calculations) with direct observations of the same variables. We therefore conclude that the four independent datasets of carbonate chemistry variables were all of high quality, and as a result that this dataset is suitable to be used for the evaluation of ocean acidification impacts and for carbon cycle studies. A diurnal cycle with maximum amplitude of 41 μatm was observed in the difference between the pCO2; values obtained by the two independent analytical pCO2; systems, and this was partly attributed to irregular seawater flows to the equilibrator and partly to biological activity inside the seawater supply and one of the equilibrators. We discuss how these issues can be addressed to improve carbonate chemistry data quality on research cruises.
    Print ISSN: 1810-6277
    Electronic ISSN: 1810-6285
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 6
    Publication Date: 2014-01-15
    Description: We present here a high resolution surface water pH dataset obtained in the Northwest European shelf seas in summer 2011. This is the first time that pH has been measured at such a high spatial resolution (10 measurements h–1) in this region. The aim of our paper is to investigate the carbonate chemistry dynamics of the surface water using pH and ancillary data. The main processes controlling the pH distribution along the ship's transect, and their relative importance, were determined using a statistical approach. The study highlights the impact of biological activity, temperature and riverine inputs on the carbonate chemistry dynamics of the shelf seas surface water. For this summer cruise, the biological activity formed the main control of the pH distribution along the cruise transect. Variations in chlorophyll and nutrients explained 29% of the pH variance along the full transect and as much as 68% in the northern part of the transect. In contrast, the temperature distribution explained ca. 50% of the pH variation in the Skagerrak region. Riverine inputs were evidenced by high dissolved organic carbon (DOC) levels in the Strait of Moyle (northern Irish Sea) and the southern North Sea with consequent remineralisation processes and a reduction in pH. The DOC distribution described 15% of the pH variance along the full transect. This study highlights the high spatial variability of the surface water pH in shelf seawaters where a range of processes simultaneously impacts the carbonate chemistry.
    Print ISSN: 1810-6277
    Electronic ISSN: 1810-6285
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 7
    Publication Date: 2012-10-19
    Description: To study the effects of the physical environment on carbon and nutrients cycles dynamics in the north eastern shelf of the Gulf of Cádiz, changes in currents, tides, salinity, temperature, carbon system parameters (fugacity of CO2 (fCO2), dissolved organic carbon, dissolved inorganic carbon and pH) and others related (dissolved oxygen, total dissolved nitrogen, nutrients and suspended particulate matter) were measured in transects across the Guadalquivir Estuary and Bay of Cádiz mouths. Thus, the main objective of this study is to investigate the influence of these inner ecosystems on the carbon and nutrient distributions in the adjacent continental shelf. Three cruises have been undertaken in June 2006, November 2006 and February 2007, each one covering one complete tidal cycle during June, both systems were exporting components to the adjacent continental shelf of the Gulf of Cádiz. In an annual scale, Guadalquivir Estuary exported components while Bay of Cádiz imported them. Diurnal variability of fCO2 could have a potentially important implication on the estimate of air-sea CO2 fluxes. Monthly studies should be undertaken to completely understand this dynamic system.
    Print ISSN: 1810-6277
    Electronic ISSN: 1810-6285
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 8
    Publication Date: 2013-07-04
    Description: To study the effects of the physical environment on carbon and nutrient cycle dynamics on the north-eastern shelf of the Gulf of Cádiz, changes in currents, tides, salinity, temperature, carbon system parameters (fugacity of CO2 (fCO2), dissolved organic carbon, dissolved inorganic carbon (DIC) and pH) and other related parameters(dissolved oxygen, total dissolved nitrogen (TDN), nutrients and suspended particulate matter) were measured in transects across the Guadalquivir estuary and Bay of Cádiz mouths. The main objective of this study is to investigate the influence of these inner ecosystems on the carbon and nutrient distributions on the adjacent continental shelf. Three cruises were undertaken in June 2006, November 2006 and February 2007. During the whole study period, Guadalquivir estuary exported components at a rate of 3 Gmol of SiO2, 4 Gmol of DIN, 3 Gmol of TDN, 31 Gmol of DOC and 604 Gmol of DIC per year. On the other hand, Bay of Cádiz imported 3 Gmol of SiO2, 1 Gmol of DIN, 2 Gmol of TDN, 33 Gmol of DOC and 562 Gmol of DIC per year. Diurnal variability of fCO2 could have a potentially important implication on the estimate of air–sea CO2 fluxes. Tides influence velocity and transport of carbon and nutrients: we found statistically significant differences (p 〈 0.0001, n = 220) between the flood tide (the mean velocity was 4.85 cm s–1) and the ebb tide (the mean velocity was −5.67 cm s–1). Biological activity and diurnal changes have also an important role on the carbon and nutrient dynamics. Seasonal carbon and nutrient variations were found. During June, both systems were exporting components to the adjacent continental shelf of the Gulf of Cádiz, whereas in February both systems were importing. Monthly studies should be undertaken to completely understand this dynamic system.
    Print ISSN: 1726-4170
    Electronic ISSN: 1726-4189
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 9
    Publication Date: 2014-08-19
    Description: Four carbonate system variables were measured in surface waters during a cruise aimed at investigating ocean acidification impacts traversing northwestern European shelf seas in the summer of 2011. High-resolution surface water data were collected for partial pressure of carbon dioxide (pCO2; using two independent instruments) and pH using the total pH scale (pHT), in addition to discrete measurements of total alkalinity and dissolved inorganic carbon. We thus overdetermined the carbonate system (four measured variables, two degrees of freedom), which allowed us to evaluate the level of agreement between the variables on a cruise whose main aim was not intercomparison, and thus where conditions were more representative of normal working conditions. Calculations of carbonate system variables from other measurements generally compared well with direct observations of the same variables (Pearson's correlation coefficient always greater than or equal to 0.94; mean residuals were similar to the respective accuracies of the measurements). We therefore conclude that four of the independent data sets of carbonate chemistry variables were of high quality. A diurnal cycle with a maximum amplitude of 41 μatm was observed in the difference between the pCO2 values obtained by the two independent analytical pCO2 systems, and this was partly attributed to irregular seawater flows to the equilibrator and partly to biological activity inside the seawater supply and one of the equilibrators. We discuss how these issues can be addressed to improve carbonate chemistry data quality on future research cruises.
    Print ISSN: 1726-4170
    Electronic ISSN: 1726-4189
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
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