ISSN:
1076-5174
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Certain abundant peaks in the electron impact mass spectra of a series of trans-4-benzoylamino-2H-1-benzopyran-3-ols involve the formation of a substituted N-alkylated benzonitrile ion by a mechanism involving migration of oxygen, in a postulated four-centre skeletal rearrangement, leading to the loss of a benzopyranone. The presence of a small range of differing substituents at three locations in this series was studied for their effects on this proposed mechanism.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jms.1190300712
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