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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 669-677 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dynamic loss energy measurements for characterizing adhesion using Vibron DDV-II have been applied to the tire cord-rubber composite system, and the relationships between these dynamic measurements and static adhesion test (H-block pull test and strip peeling test) were also investigated. Tested samples were the commercial nylon 66 tire cord and poly(ethylene terephthalate) tire cord with two adhesive systems. The degree of adhesion (adhesion factor) was obtained as the energy dissipation at the tire cord-to-rubber interface as measured by dynamic testing. It was shown that energy dissipation is increased at the filament-matrix interface when the composite is subjected to continuous cyclic loading if a condition of poor adhesion exists. The test was based upon the separation of the total energy dissipation in a composite under cyclic loading into a portion associated with viscous properties of the constituent materials and a second portion resulting from the lack of perfect bonding in the interfacial regions. The strip peeling measurement of adhesion exhibited an approximately linear correlation with the dynamic loss energy measurement of adhesion. The dynamic energy loss measurement is suggested as a potential source of information on the rheological characteristics of the interfacial region of bonding.
    Additional Material: 5 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 1695-1700 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Vibron Viscoelastometer is useful for obtaining dynamic mechanical properties of film and fibers in atmospheres at 0 and 100% relative humidity. No apparatus has previously been available for obtaining dynamic mechanical properties in a gas medium; however an apparatus and procedure have been developed for measuring these dynamic properties in a gas medium using the Vibron instrument. This technique will be useful in studies on the effects of different gases on polymers in the process and on the effects of gas treatments on materials. A new gas cell which is adaptable for other mechanical testing instruments such as the Instron, Tensometer, and Torsion Pendulum is also discussed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 2593-2596 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 529-534 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Rheovibron viscoelastometer is useful for obtaining dynamic tensile, shear, and bending mechanical properties of films and fibers over a wide teḿperature range. In recent years a modification that makes measurement on materials in a liquid or gas medium possible has been reported. A new compression grip and procedure were used for measuring dynamic mechanical properties of a fiber mass in the compression mode using the Rheovibron instrument. The dynamic compression properties on nylon, polyester, and acrylic fibers are presented.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 3221-3224 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Rheovibron viscoelastometer is useful for obtaining dynamic tensile mechanical properties of films and fibers over a wide temperature range. Numerous studies of dynamic tensile mechanical properties have been made in the temperature range of -160°C to 250°C in an atmosphere at 0% relative humidity. However, no studies exist which show the measurement of dynamic shear mechanical properties of materials using the Vibron instrument. A new shear grip and procedure was developed for measuring dynamic mechanical properties of material in the shear mode using the Rheovibron instrument. The dynamic shear properties on a polyurethane elastomer and polyester film are presented. This technique will be useful in studies on the dynamic shear characterization of materials in conjunction with end use performance.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 1413-1417 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method is presented which permits the quantitative characterization of interfilament friction of staple yarns using loss tangent tanδ data measured directly from samples nondestructively with the Rheovibron DDV-II viscoelastometer. The procedure is derived from a phenomenological model of the structure's mechanical behavior in which its energy dissipation capacity consists of both filament internal viscous friction and a filament-to-filament coulomb friction mechanism. By treating the coulomb dissipation in terms of an additional effective viscous component, the loss tangent of the model representing the structure can be analytically expressed in terms of the internal filament viscous properties, a fiber-to-fiber coulomb parameter, and an undetermined assembly dispersion factor which is representative of strength. By measuring effective loss tangent data for the staple yarn and a constituent filament at two separate frequencies and considering the magnitude of the coulomb mechanism to be independent of the test frequency in the range employed, both the coulomb friction dissipation and the assembly dispersion factor can be quantified. Using this procedure, loss tangent data from tests on a series of staple yarns (nylon, polyester, and acrylic fiber) are used to calculate both assembly dispersion and interfilament coulomb friction factors.
    Additional Material: 2 Tab.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 89-96 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new technique is presented which permits the quantitative characterization of the dynamic viscoelastic properties of polymer melts and liquids. A new sample holding system with oscillatory shear platen and modification of the amplifier and oscillating unit made it possible to measure rheological properties of the viscous liquids using the Rheovibron. The dynamic shear modulus, viscosity, and internal friction of acrylic dope, and silicone fluids are obtained by using the new procedure and developed mathematical expressions. This technique will be useful in studies on the rheological properties characterization of polymer melts and liquids in conjunction with process parameters.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1647-1651 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method for measurement of dynamic flexile mechanical properties was developed by a modification of the Rheovibron viscoelastometer. The Rheovibron instrument is useful for obtaining dynamic tensile mechanical properties of films and fibers over a wide temperature range. A new flexile grip and procedure were used for measuring dynamic mechanical properties of material in the flexile mode using the Rheovibron instrument. The dynamic flexile properties on polyester, nylon 66, and acrylic fiber are presented.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 7 (1969), S. 1059-1073 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Nylon 66 films exhibiting form I melting behavior show the γ mechanical relaxation at -140°C. Samples which have form II melting behavior do not show this relaxation. The γ relaxation disappears when material having form I behavior is converted to material having form II behavior by annealing or by cold drawing. The form I and form II types of melting behavior are also found in poly(ethylene terephthalate); the interconversions and thermal behavior of the forms are analogous to the nylon 66 case. In poly(ethylene terephthalate), the β relaxation at -40 to -60°C is present only when form I melting behavior is found. Conversion to form II melting behavior by annealing or drawing (80°C) again causes the relaxation to disappear. No β relaxation was found in amorphous polymer. The γ dispersion in nylon 66 and the β dispersion in poly(ethylene terephthalate) can therefore be associated with the crystalline structure responsible for form I melting behavior. Form I melting behavior has been associated with foldedchain crystals based on previous work. It is therefore postulated that the γ dispersion in nylon 66 and the β dispersion in poly(ethylene terephthalate) are associated with motions in the chain folds. This assignment is not inconsistent with the change in the γ dispersion of nylon 66 with the number of backbone CH2 units, since these will affect the fold structure.
    Additional Material: 10 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 6 (1968), S. 787-793 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Time-temperature superposition can be successfully applied to both the stress relaxation and dynamic mechanical properties of oriented PET fibers. Two curves result; one is the time dependence of the modulus at constant temperature, while the other is the shift, log aT, of this curve along the time scale as a function of temperature. This temperature dependence is less than that for both unoriented PET and typical amorphous polymers above Tg. It is about the same as that for oriented nylon 66 and unoriented glassy poly(methyl methacrylate). The isothermal modulus has the same time dependence as that of the unoriented PET; however, it is a factor of 3.3 larger. The modulus curve is almost identical in both shape and magnitude with that of oriented nylon 66. However, a temperature of 82°C. is required to place the viscoelastic dispersion region of PET at the same time scale as nylon 66 at 25°C. This temperature increase is the major difference in viscoelasticity between these two oriented polymers.
    Additional Material: 6 Ill.
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