ISSN:
1434-4475
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reaction of fluorosilanes with lithium salts of bulky amines like tetramethyl-piperidine and di-tert. butylamine leads to stable aminofluorosilanes of the type R-SiF2-NR′R″ [R=F, C(CH3)3, C6H5, C6H4N(CH3)2]. Lithium salts of silylamines react analogously: R2Si(NR′-SiF2R″)2 (R=R′= =CH3, R″=C6H5). An eight membered Si−N-ring is obtained in the reaction of a disubstituted silylaminofluorosilane with the dilithium salt of a silylamine. The mass-,1H-, and19F-NMR spectra of the above mentioned compounds are reported.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00897691
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