ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Stereoselective Synthesis of Alcohols, I. Synthesis of One-Carbon Homologous Allyl Alcohols from Aldehydes or KetonesThe high yield conversion of aldehydes and ketones 2 to the one-carbon homologous allyl alcohols 3 is achieved by condensation to the vinyl sulfoxides 7, isomerisation to the allyl sulfoxides 9, and subsequent [2,3]sigmatropic rearrangement.
Notes:
Die Umwandlung von Aldehyden und Ketonen 2 in die um ein C-Atom reicheren Allylalkohole 3 gelingt durch Umsetzung zu den Vinylsulfoxiden 7, deren Isomerisierung zu den Allylsulfoxiden 9 und nachfolgende [2,3]sigmatrope Umlagerung.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19801130304
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