ISSN:
1573-4889
Keywords:
chromium
;
sulfur
;
chromia
;
growth-mechanism
;
Fe–Cr alloy
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract The growth mechanism of the flat and adherent scale formed at 900°C in 0.1 atm oxygen on chromium, which contained 1 ppm (wt) sulfur, 0.08 ppm (wt) chlorine, and 0.2 ppm (wt) phosphorus, has been found to be very different in adjacent parts of the scale, consistent with the results of previous tracer studies of the growth mechanism of chromia formed on chromium. In some places, it grew primarily by chromium transport, while in others it grew primarily by oxygen transport and in still others it grew by a mixture of both. New oxide formed within the outer part of the scale and, in some cases, throughout the scale. A tentative hypothesis is proposed to explain why growth mechanisms were different in different parts of the scale on the same specimen. The scale formed at 950°C on Fe–20%Cr–0.11%Si, which contained 15 ppm sulfur, grew predominantly by cation transport, with only a small amount of oxygen transport. In this case also, new oxide formed within the outer part of the scale.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1004646803204
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