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  • 1
    Call number: SR 90.1076(18) ; SR 90.1076(18)
    In: Geoskrifter
    Type of Medium: Series available for loan
    Pages: 154 S.
    ISBN: 8787529408
    Series Statement: Geoskrifter 18
    Language: English
    Location: Lower compact magazine
    Location: Lower compact magazine
    Branch Library: GFZ Library
    Branch Library: GFZ Library
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  • 2
    Publication Date: 2021-05-04
    Description: The oil expulsion efficiency of organic-rich shale during peak oil generation influences the generation of shale gas at high maturity, while the gas expulsion and loss efficiency affect the enrichment and preservation of shale gas. Two series of semiclosed hydrous pyrolysis experiments were performed under in situ geological conditions on Devonian shale sample as comparable analogue to evaluate the generation and preservation potential of shale gas in the Wufeng-Longmaxi Formation shale in the southeastern Sichuan Basin. The results indicate that the maximum oil expulsion efficiency of the Wufeng-Longmaxi shale is 68.8%. Retained oil is the main source of shale gas formed at high maturity. When the value of equal vitrinite reflectance (EqVRo) reaches 3.18%, the total gas generative potential from the retained oil and kerogen is 214.06 mL/g TOC, while that from kerogen is only 69.84 mL/g TOC. Overall, retained oil-formed gas at high maturity (EqVRo 〉1.30%) accounts for 60.82%–68.26% of the total gas, and the kerogen-formed gas is between 31.74% and 39.18% of the total gas. Based on the analysis of the JY2 well, Wufeng-Longmaxi shales with TOC contents 〉1.5% lose 60–80% of the total gas, while shales with TOC contents 〈1.5% lose 70–100% of the total gas. A TOC content of 1.5% can still meet the 2 m3/t gas content as evaluation standard for selecting favorable marine shale gas play areas in China.
    Type: info:eu-repo/semantics/article
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  • 3
    Publication Date: 2021-06-14
    Description: A change from a humid to an arid climate occurred during the Middle Jurassic. Information about this transitional phase is stored in two oil shales: the lower and upper units of the shale member of the Shimengou Formation (J2s) in the northern Qaidam Basin (NQB), Northwest China. The drastic changes in lithofacies are also reflected in the organic and inorganic inventory of the two oil shales, and suggests the existence of this aridification event. Thus, the two units varied greatly in organic matter source, productivities and depositional environments. The lower unit is interpreted as lacustrine sediment deposited under a humid climate with a high terrigenous organic matter portion besides algal biomass. Furthermore, the high sedimentation rate and large organic matter size prevented organic matter degradation. In contrast, deposition of the upper unit was coincident with progressive aridification, which resulted in minor terrigenous organic matter input, and enhanced algal biomass deposition. Its preservation was favored by an enhanced salinity and stratification of water column with an underlying anoxic bottom water condition. Today, the sediments of the upper unit are characterized by a high total organic carbon (TOC) content and type I kerogen. In summary, two depositional scenarios of source rock formation under different climatic conditions are introduced to highlight the effect of progressive aridification on the evolution of source rocks. Moderate aridification in the transition period (early stage of aridification) is suggested to have promoted the formation of lacustrine source rocks with the potential to generate waxy oil. The occurrence of similar lacustrine source rocks is also predictable when deposited while similar aridification events, particularly in the Jurassic with its frequent climate changes.
    Type: info:eu-repo/semantics/article
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  • 4
    Publication Date: 2021-04-29
    Description: This study aims to characterize the geological properties and to evaluate the gas potential of the lower Paleozoic shales in the Yichang area by integrating a series of analyses on geology and geochemistry, well logging data, and 2D seismic interpretation. The thickness of the lower Cambrian Shuijingtuo shale is less than 10 m in the southeast but may exceed 120 m in the southwest area. The thickness of the upper Ordovician Wufeng shale and the lower Silurian Longmaxi shale (hereafter referred to as the Wufeng-Longmaxi shale) gradually increases in thickness from 〈10 m in the south to 40–50 m in the northeast. The organic matter of the above two sets of black shale is mainly dominated by type I and II1 kerogen. The thickness of black shale units with TOC 〉 2% is more than 10–20 m, commonly located at the bottom of the shale intervals. Black shales near the Huangling anticline have low thermal maturity due to its relatively shallow burial. The predominant minerals are quartz and clay minerals. Carbonate contents of the Shuijingtuo shale are relatively high compared to the Wufeng-Longmaxi shale. Pores are more developed in the Wufeng-Longmaxi shale than those in the Shuijingtuo shale. Natural fractures are common in the Shuijingtuo shale but are rare in the Wufeng-Longmaxi shale. The well logging and lab analytical results both indicate that the natural gas content in the black shales is relatively high. The prospective area of the Shuijingtuo interval for shale gas production is nearly 670 km2, located in the southwestern region. In contrast, the prospective area of the Wufeng-Longmaxi interval for shale gas production is approximately 1590 km2, situated in the eastern area.
    Type: info:eu-repo/semantics/article
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  • 5
    Publication Date: 2022-07-26
    Description: The Peshawar Basin, Pakistan, is a renowned example of a middle Paleozoic lithological succession filled with 0.8-Ma-age mega lake sedimentation, and also the site of two tectonic major thrusts named the Main Mantle Thrust (MMT) and Main Boundary Thrust (MBT), respectively. Unfortunately, two geologically significant geosites, known as the Nowshera Reef Complex (NRC) and Gohati Rhyolite deposits (GRD), have limited research and international geological exposure, and are at risk of mining destruction as they are currently not geoheritage sites. The NRC is a spectacular example of a complete reef setting including back, fore, and core reef sections, which are seldom found in the world. An equally important geosite worth preserving is the GRD. For evaluating the geoconservation merit of geosites, a geoscientific inventory method has been applied in this study. The method considers representativeness, integrity, accessibility, and scientific and esthetic value criteria of each geosite. The quantification of the geosites is based on four categories of values: intrinsic value, scientific value, tourism value, and value of management. The final results indicate that both the geosites hold international significance in the relevance score (IR), and have high tourist potential due to their esthetic and intrinsic value. These results reflect the high representation of geological and geomorphological processes documented at the geosites. Despite these results, both geosites are currently on the verge of permanent destruction due to pervasive mining excavation acquiring construction materials. Unfortunately, some outcrops have already been completely mined, but some are only at risk and can be saved. The conclusions raise the need for planning and implementing management procedures to increase the conservation and sustainability parameters of the proposed NRC and GRD geosites.
    Language: English
    Type: info:eu-repo/semantics/article
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  • 6
    Publication Date: 2021-04-07
    Description: The assessment of the gas generation potential of highly to overmature shale is key for shale gas evaluation, but it is always fraught with challenges. In this study, immature shale samples with type-I kerogen were investigated for their oil expulsion efficiencies (EEs) by means of pyrolysis in sealed gold tubes to investigate the influence of EEs on the gas generation process. Experimental results were then applied as an analogue to evaluate the gas generation potential of the Lower Cambrian Niutitang shale reservoir in South China. The results demonstrate that the gas yields of C1–C5 alkanes obviously decrease with increasing EEs and are a result of thermal cracking gas caused by a decrease of the oil retention. The change of the gas drying index (i.e., C1/C1–5) indicates that EasyRo of 1.81% calculated from pyrolysis temperature indicates the start of a significant cracking of heavy hydrocarbon gases (C2–5). Before, the generated gas is mainly wet gas, whereas at higher maturities, C2+ alkanes are substantially cracked into methane. The iC4/nC4 and iC5/nC5 ratios exhibit a gently increasing trend, which may result from the catalytic role of clay minerals. Considering the semiquantitative statistical analysis of solid bitumen, the EEs of the Lower Cambrian Niutitang shale in South China were calculated. The gas generation potential of the Niutitang shale of two selected wells is in the range of 4.21–37.62 m3/t and 2.53–11.15 m3/t, respectively, whereas the gas contents of these two wells are low. This mismatch indicates that the gas accumulation in the Niutitang shale reservoir is related to preservation conditions rather than based exclusively on the generation potential of the shale. This study offers a conceptual approach to evaluate the gas generation potential of organic-rich shale after hydrocarbon expulsion and enhances the accuracy of the prediction of highly mature and overmature shale gas resources in South China.
    Type: info:eu-repo/semantics/article
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 10 (1971), S. 1229-1236 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 8 (1969), S. 4403-4410 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Munksgaard International Publishers
    Indoor air 3 (1993), S. 0 
    ISSN: 1600-0668
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Medicine
    Notes: The aim of the present study is to demonstrate the technical feasibility of the membrane absorber as an air cleaner with small-scale modules. Six small-scale membrane modules with different fibre lengths and fibre diameters have been investigated. Each module has been tested as a membrane absorber treating air with 4 different chemicals, formaldehyde, nitrogen dioxide, ammonia and acetone, with tap water. The pressure drop and the filtration efficiency has been measured at different flow rates. From these results the optimal membrane module has been selected for the following reasons: low pressure drop, small required membrane surface area and high filtration efficiency. The experiments were continued with the selected module for ETS in a test room. Water soluble compounds were removed with an efficiency of at least 95%. The efficiency was inconsistent for NO, (not expected) and low for hydrocarbons (as expected). The sensory filtration efficiency was also measured with two different methods, the threshold method and the decipol method. Both efficiencies were about 50%. Recommendations for future research are given.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Soil Science Society of America journal 64 (2000), S. 527-532 
    ISSN: 1435-0661
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Type of Medium: Electronic Resource
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