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  • 1
    Publication Date: 2017-07-06
    Description: Over the past two decades, activity at Turrialba volcano, Costa Rica, has shifted from hydrothermal to increasingly magmatic in character, with enhanced degassing and eruption potential. We have conducted a survey of the δ 13 C signatures of gases at Turrialba using a portable field-based CRDS with comparison to standard IRMS techniques. Our δ 13 C results of the volcanic plume, high temperature vents and soil gases reveal isotopic heterogeneity in the CO 2 gas composition at Turrialba prior to its recent phase of eruptive activity. The isotopic value of the regional fault system, Falla Ariete (-3.4±0.1‰), is in distinct contrast with the Central crater gases (-3.9±0.1‰) and the 2012 high temperature vent (-4.4±0.2‰), an indication that spatial variability in δ 13 C may be linked to hydrothermal transport of volcanic gases, heterogeneities in the source composition, or magmatic degassing. Isotopic values of CO 2 samples collected in the plume vary from δ 13 C of -5.2 to -10.0 ‰, indicative of mixing between atmospheric CO 2 (-9.2 ± 0.1‰), and a volcanic source. We compare the Keeling method to a traditional mixing model (hyperbolic mixing curve) to estimate the volcanic source composition at Turrialba from the plume measurements. The predicted source compositions from the Keeling and hyperbolic methods (-3.0±0.5‰ and -3.9±0.4‰, respectively) illustrate two potential interpretations of the volcanic source at Turrialba. As of the 29 October 2014, Turrialba has entered a new eruptive period, and continued monitoring of the summit gases for δ 13 C should be conducted to better understand the dominant processes controlling δ 13 C fractionation at Turrialba.
    Electronic ISSN: 1525-2027
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 2
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    In:  Eos, Trans., Am. Geophys. Un., London, Army Corps of Engineers, Woodward-Clyde Consultants, vol. 80, no. 48, pp. 575, 579, 581, pp. 1062, (ISBN: 0-12-018847-3)
    Publication Date: 1999
    Keywords: Project report/description ; Volcanology ; Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Global Positioning System ; Gravimetry, Gravitation ; Geochemistry ; microgravity ; changes ; no ; deformation ; gas ; sulfur
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  • 3
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    Academic Press
    In:  San Diego, Academic Press, vol. Developments in Petroleum Science vol. 15B, no. Publ. No. 12, pp. 9, (3-540-24165-5, XXVI + 228 p.)
    Publication Date: 1999
    Keywords: Handbook of geophysics ; Handbook of geology ; Volcanology ; BIBTEX?
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  • 4
    Publication Date: 2019
    Description: Abstract Identification of unambiguous signals of volcanic unrest is crucial in hazard assessment. Processes leading to phreatic and phreatomagmatic eruptions remain poorly understood, inhibiting effective eruption forecasting. Our 5‐year gas record from Poás volcano, combined with geophysical data, reveals systematic behavior associated with hydrothermal‐magmatic eruptions. Three eruptive episodes are covered, each with distinct geochemical and geophysical characteristics. Periods with larger eruptions tend to be associated with stronger excursions in monitoring data, particularly in SO2/CO2 and SO2 flux. The explosive 2017 phreatomagmatic eruption was the largest eruption at Poás since 1953 and was preceded by dramatic changes in gas and geophysical parameters. The use of drones played a crucial role in gas monitoring during this eruptive period. Hydrothermal sealing and volatile accumulation, followed by top‐down reactivation of a shallow previously emplaced magma body upon seal failure, are proposed as important processes leading to and contributing to the explosivity of the 2017 eruption.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 5
    Publication Date: 2015-12-24
    Description: Porphyry and epithermal ore deposits, which are the products of magmatic hydrothermal fluids, are intimately associated with volcanoes in continental and island arcs above subduction zones, but the exact nature of this relationship has remained enigmatic. Although metal deposition is usually thought to occur during the waning stages of volcanism, numerous ore deposits have been demonstrated to be synvolcanic. Here we show how the formation of these deposits is tied to volcanic cycles. We relate the chemical variations in vapors from Merapi volcano, Indonesia, to different stages of its eruptive cycle. The chemical compositions of volcanic vapors from subduction zone volcanoes are then compared globally to those of fluid inclusions from porphyry-epithermal deposits. These data show that adiabatic decompression is the principal control on mineralization. The data also suggest that volcanic and subvolcanic magmatic-hydrothermal systems are under lithostatic pressure during quiescence but decompress rapidly during injections of mafic magma and explosive eruptions. During quiescence, the magma evolves through fractional crystallization and devolatilization, gradually becoming oxidized and enriched in gold and other incompatible metals. Upon the injection of sulfur-rich mafic magmas, subvolcanic intrusions brecciate the overlying rocks, the systems are depressurized, the volcanoes erupt explosively, supercritical fluids unmix into vapor and brine, and base metal sulfides precipitate.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 6
    Publication Date: 2014-05-31
    Description: Cosigüina volcano, in northwestern Nicaragua, erupted violently on 20–24 January 1835, producing pumice, scoria, ash fall deposits, and pyroclastic flows with a bulk tephra volume of ~6 km 3 . New geochemical data are presented for bulk-rocks, matrix glasses, melt inclusions and minerals from the 1835 deposits and a pre-1835 basaltic andesite tephra, with the aim of shedding light on the magmatic processes and associated timescales that led to the eruption. Our results reveal that the 1835 eruption was fed by a compositionally and thermally zoned magma reservoir situated ~4 km ( P H2O ~100 MPa) beneath the volcano. Small volumes of crystal-poor dacite (〈10 wt % phenocrysts, 63·8–64·8 wt % SiO 2 , ~950°C) and silicic andesite (〈10 wt % phenocrysts, 62·2 wt % SiO 2 , 960–1010°C) were erupted first, followed by relatively crystal-rich andesite (15–30 wt % phenocrysts, 57·4–58·8 wt % SiO 2 , 960–1010°C), which accounts for ~90% of the erupted magma. The pre-1835 basaltic andesite (~20 wt % phenocrysts, 52·4 wt % SiO 2 , 1110–1170°C) represents a mafic end-member for Cosigüina. The major and trace element compositions of the bulk-rocks, melt inclusions and matrix glasses suggest that (1) the pre-1835 basaltic andesite is a plausible parent for the 1835 magmas, (2) the 1835 andesite bulk-rocks do not represent true melts, but instead mixtures of silicic andesite liquid and a component of accumulated crystals dominated by plagioclase, and (3) the silicic andesite and dacite formed from the andesite magma through liquid extraction followed by fractional crystallization. Observed bimodal to trimodal crystal populations are consistent with a multi-stage, polybaric differentiation process, with calcic plagioclase (An 75–90 , An 90–95 ) and magnesian clinopyroxene (Mg# = 67–75), plus olivine and magnetite, forming from mafic andesite, basaltic andesite and basalt in the lower crust. The calcic plagioclase exhibits sieve textures, which may be the result of H 2 O-undersaturated decompression during magma ascent to the upper crust; An 50–65 plagioclase lacking a sieve texture, orthopyroxene (Mg# = 61 and 63–72), clinopyroxene (Mg# = 67), magnetite and apatite crystallized from andesite to dacite liquids in the shallow magma reservoir. An 75–90 plagioclase comprising entire phenocrysts or cores with An 50–65 rims in the 1835 magmas is cognate from earlier stages of differentiation and shows evidence of extensive diffusion of Mg when compared with similar An 75–95 crystals hosted in the pre-1835 basaltic andesite. Using plagioclase–melt Mg partitioning and modelling of the Mg diffusion process, we constrain the residence time of these crystals in the silicic liquids to more than 100 years and less than 2000 years, with detailed analysis of three crystals yielding ~400 years. We propose that magma reservoir zonation occurred on timescales of 10 2 –10 3 years at Cosigüina. The occurrence of H 2 O-rich fluid inclusions in all 1835 samples and volatile element systematics in melt inclusions imply that the magmas were saturated with a vapour phase (H 2 O, S, ± CO 2 ) during much of their evolution in the upper crust. Accumulation of free gas at the top of the magma reservoir may have led to overpressurization of the system, triggering the eruption. Catastrophic release of this exsolved vapour and syn-eruptive devolatilization of the melt injected several teragrams of S into the atmosphere. Our data, coupled with independent evidence from ice cores and tree rings, indicate that the Cosigüina eruption had a sizeable atmospheric impact comparable with or larger than that of the 1991 Pinatubo eruption. Stratigraphic evidence shows that Cosigüina has produced 〉15 compositionally zoned explosive eruptions in the past, suggesting that similar future eruptions are likely. The products of the 1835 eruption of Cosigüina share many features with compositionally zoned eruptive sequences elsewhere, such as the climactic eruption of Mount Mazama, the ad 79 ‘Pompei’ eruption of Vesuvius and the 1912 eruption of Novarupta–Katmai.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 7
    Publication Date: 2014-03-15
    Description: Understanding magmatic systems feeding volcanoes is critical for accurate interpretation of monitoring data and, ultimately, eruption forecasting. Following 3 months of precursory unrest, the first historical eruption at El Hierro, Canary Islands, took place ~2 km offshore from October 2011 to March 2012. Our detailed petrological analysis of lava samples reveals that at least two distinct magmas initially supplied from reservoirs in the mantle underwent hybridization at 15–25 km depth, i.e., also largely within the upper mantle beneath El Hierro. Diffusion chronometry applied to zoned olivine crystals indicates that magma mixing began during the period of preeruptive seismicity and continued for weeks after the eruption onset. Our data also capture a magma stagnation level at 10–15 km depth in the lower crust, consistent with lateral propagation of an intrusion over substantial distances before rapid magma transit to the seafloor. The remarkable spatial and temporal correlation of petrological and geophysical data at El Hierro suggests that the observed seismicity records magma mixing and forceful intrusion as well as subsequent reservoir dynamics. These results demonstrate that eruptions at El Hierro are controlled principally by deep-seated processes, with little influence from shallow crustal levels, and have important implications for monitoring of renewed unrest at long-dormant volcanoes.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 8
    Publication Date: 2016-04-29
    Description: Rocks from the 23 Ma Lake City caldera show diverse chemical affinities attesting to a complex magmatic system beneath the caldera. Field and geochemical data from ignimbrites and intrusions constrain magma storage and magma interactions during the formation of the caldera. Two geochemically distinct magma batches erupted during caldera formation: batch A, consisting of rhyolites and trachytes, and batch B, consisting of dacites and trachyandesites. The ignimbrites of the Lower, Middle, and Upper Sunshine Peak Tuff represent the bulk of erupted batch A magma, with an increasing proportion of trachyte to rhyolite as the eruption progressed. Overall, the observed trends of major and trace elements are consistent with the sequential eruption of a magmatic system with a rhyolitic upper portion and trachytic lower portion. The Middle Sunshine Peak Tuff contains two distinct types of pumice clast, while the Upper Sunshine Peak Tuff contains four distinct pumice clast types, with one type chemically related to batch B magma. The link between the rhyolite and trachyte of batch A is supported by major- and trace-element geochemical modeling of an initially trachytic magma that fractionated and was subjected to crystal/melt segregation following 50%–60% crystallization. Compositional gaps and chemical heterogeneity in the bulk ignimbrite composition show that the proportions of these different magma types varied significantly during eruption. We propose that the fractionating batch A and B magmas formed distinct magma pods, some containing residual magma mush, that were tapped during different phases of caldera formation. After collapse, dacite lavas of batch B were erupted concurrent with resurgent uplift from shallow intrusion of both residual mingled batch A and batch B magma. In summary, our observations suggest (1) a complex magma chamber geometry from two fractionating magma batches, and (2) magma replenishment and accelerated periods of magma reorganization in the shallow magma plumbing system during a single caldera cycle at Lake City.
    Print ISSN: 0016-7606
    Electronic ISSN: 1943-2674
    Topics: Geosciences
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  • 9
    Publication Date: 2013-03-23
    Description: The Valles Caldera complex in north–central New Mexico, USA, represents the type example of a resurgent caldera system, characterized by eruption of two voluminous high-silica rhyolite ignimbrites, the Otowi and Tshirege Members of the Bandelier Tuff. Central resurgence of ~1000 m occurred within 27 ± 27 kyr following eruption of the Tshirege, or Upper Bandelier Tuff (UBT). This process was accompanied by small-volume eruptions of the Deer Canyon Rhyolite, followed closely by the Redondo Creek Rhyodacite. The Cerro del Medio Rhyolite lava dome complex is a product of ring fracture volcanism following resurgence. We have combined cathodoluminescence (CL) imaging and titanium-in-quartz geothermometry techniques for single quartz crystals from (1) different stratigraphic horizons of the UBT ignimbrite, (2) samples of the Deer Canyon Rhyolite and (3) the Cerro del Medio Rhyolite lavas to build an evolutionary model of the Valles Caldera lifecycle. CL imaging reveals that ~70% by volume of the UBT ignimbrite contains unzoned quartz crystals (average concentration 28 ± 2 ppm Ti), recording relatively stable conditions. The abrupt appearance of compositionally zoned quartz crystals within the mid-to-late erupted UBT ignimbrite units 3–5 reveals evidence for interaction with hotter magma. Corresponding titanium-in-quartz measurements of outer, high-intensity CL rims (average of 71 ± 9 ppm Ti) reveal temperature increases of between ~35 and 140°C relative to the initial, volumetrically large Upper Member eruptions (flow units 1 and 2). These temperature increases mimic those originally reported in the literature. Compared with the temperature increases, changes in pressure appear to play a secondary role. We have also discovered an interesting heterogeneity within the Deer Canyon Rhyolite lavas, with strong spatial control on the eruption of porphyritic lavas containing complexly zoned quartz crystals on the western parts of the resurgent dome. Conversely, crystal-poor to aphyric lavas containing small, unzoned quartz crystals are confined to eastern parts of the resurgent dome. The Cerro del Medio Rhyolite lavas are sparsely porphyritic to aphyric, and contain unzoned quartz with titanium concentrations more than 40 ppm higher than the cores of UBT quartz. The quartz-free Redondo Creek Rhyodacite is the most primitive silicic material erupted during the Valles Caldera cycle. Intrusion of this hotter magma into a residual UBT crystal mush zone may have facilitated eruption and geochemical–thermal heterogeneity within the Deer Canyon Rhyolite, resurgence of the caldera, and expulsion of hot, crystal-poor rhyolite batches from the mush zone, which were subsequently erupted as the Cerro del Medio complex.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 10
    Publication Date: 2015-07-24
    Description: Seamounts formed adjacent to mid-ocean ridges are the most abundant on Earth, numbering several orders of magnitude higher than hotspot-related seamounts. The Taney Seamounts are a linear NW–SE-trending, near mid-ocean ridge chain consisting of five volcanoes located on the Pacific plate 300 km west of San Francisco, California. Taney Seamount-A, the largest and oldest in the chain, has four well-defined calderas. These calderas have clear cross-cutting relationships, creating a relative chronology. The caldera walls and intracaldera pillow mounds were sampled systematically by a remotely operated vehicle to obtain stratigraphically controlled samples, a unique aspect of this study. Changes in lava geochemistry are consistent with an open-system sub-caldera reservoir that undergoes periodic collapse, replenishment, shallow crystallization, and eruption. Replenishing magmas contain large, anorthite-rich plagioclase crystals that exhibit sieve textures and zoning indicating interaction with percolating melt. The enrichment of elements in the lavas that are incorporated in plagioclase (e.g. aluminum, strontium) provides chemical evidence for the interaction between mantle-derived melts and plagioclase cumulates in the lower oceanic crust or upper mantle (8–12 km), prior to magmas entering the sub-caldera plumbing system. Based on trace element variations, the erupted lavas vary from typical peridotite-derived normal mid-ocean ridge basalt (N-MORB) compositions to those with an apparent residual garnet signature. Geochemical and thermodynamic modeling shows that decompression melting of a MORB mantle peridotite re-fertilized by garnet pyroxenite partial melts can reproduce the garnet signature observed in the Taney-A edifice lavas. Hence the magmatic architecture of Taney Seamount-A is characterized by the melting of a mixed lithology mantle, melt–rock interaction in the upper mantle to lower oceanic crust, and open-system evolution in a sub-caldera magma reservoir.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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