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  • 1
    Publication Date: 2023-12-16
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Three volcanic arcs have been the source of New Zealand's volcanic activity since the Neogene: Northland arc, Coromandel Volcanic Zone (CVZ) and Taupō Volcanic Zone (TVZ). The eruption chronology for the Quaternary, sourced by the TVZ, is well studied and established, whereas the volcanic evolution of the precursor arc systems, like the CVZ (central activity c. 18 to 2 Ma), is poorly known due to limited accessibility to, or identification of, onshore volcanic deposits and their sources. Here, we investigate the marine tephra record of the Neogene, mostly sourced by the CVZ, of cores from IODP Exp. 375 (Sites U1520 and U1526), ODP Leg 181 (Sites 1123, 1124 and 1125), IODP Leg 329 (Site U1371) and DSDP Leg 90 (Site 594) offshore of New Zealand. In total, we identify 306 primary tephra layers in the marine sediments. Multi‐approach age models (e.g. biostratigraphy, zircon ages) are used in combination with geochemical fingerprinting (major and trace element compositions) and the stratigraphic context of each marine tephra layer to establish 168 tie‐lines between marine tephra layers from different holes and sites. Following this approach, we identify 208 explosive volcanic events in the Neogene between c. 17.5 and 2.6 Ma. This is the first comprehensive study of New Zealand's Neogene explosive volcanism established from tephrochronostratigraphic studies, which reveals continuous volcanic activity between c. 12 and 2.6 Ma with an abrupt compositional change at c. 4.5 Ma, potentially associated with the transition from CVZ to TVZ.〈/p〉
    Description: Plain Language Summary: Since 18 Ma, volcanic activity in New Zealand is dominantly sourced by the Coromandel Volcanic Zone (CVZ). Most caldera systems of the CVZ identified so far are located on Coromandel Peninsula in the NW of North Island, New Zealand, but studies of the CVZ are rare mainly due to the limited accessibility of its volcanic deposits, as well as missing stratigraphic continuity between different outcrops and the volcanic source. Here, our ocean drilling tephra record—mainly volcanic ash from explosive eruptions, distributed and falling out over the ocean—has a great potential to reveal the eruption history of the CVZ because it is preserved in marine sediments in a nearly undisturbed stratigraphic context. We analyzed ∼400 marine tephra layers from multiple ocean sediment cores off the coast of New Zealand for their geochemical glass compositions and identified 306 as largely undisturbed ash deposits. These primary ash deposits correspond to a total number of 208 Neogene volcanic events. Different dating methods result in a continuous marine tephra record for the last 12 Ma, equivalent to a unique and most complete eruptive history for the CVZ. This enables us to further unravel changes in the composition of the associated magmas with time.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉New Zealand's Neogene explosive volcanism based on the marine tephra record〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Geochemical fingerprinting of marine tephra layers across the study area to establish volcanic events〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Insights into geochemical variations with time, repose times and spatiotemporal distribution〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: DFG
    Description: Marsden project
    Description: https://doi.org/10.14379/iodp.proc.372B375.210.2023
    Keywords: ddc:551 ; marine tephrochronostratigraphy ; geochemical fingerprinting ; correlations of marine tephras between individual drill sites ; IODP ; ODP and DSDP drill sites ; neogene eruption record of New Zealand
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-07-04
    Description: Transports across the continental shelf edge enhance shelf-sea production, remove atmospheric carbon and imply an active boundary to ocean circulation. Overall transports across the varied shelf edge from south-west of Britain to north of Scotland are estimated (from a variety of measurements and models) as several m〈sup〉2〈/sup〉s〈sup〉−1〈/sup〉. This large value results from variable strong wind-forced and tidal currents and along-slope flow.Even a globally typical 1 m〈sup〉2〈/sup〉s〈sup〉−1〈/sup〉 across an estimated 5x10〈sup〉5〈/sup〉 km of shelf edge amounts to 500 Sv; large compared with oceanic transports and potentially important to shelf-sea and adjacent oceanic budgets. However, exchanges with periods ∼ one day or less may be effective only for water properties that evolve on such short time-scales. Thus transports’ significance depends on distinctive properties of the water, or its contents, and on internal shelf-sea circulation affecting further transport. Transports across the NW European shelf edge enable its disproportionately strong CO〈sub〉2〈/sub〉 “pump”.The complex context, and small scales of numerous processes enabling cross-slope transports, imply a need for models. Measurements remain limited in extent and duration, but widely varied contexts, particular conditions, events, processes and behaviours are now available for model validation. Variability still renders observations insufficient for stable estimates of transports and exchanges, especially if partitioned by sector and season; indeed, there may be significant inter-annual differences. Validated fine-resolution models give the best prospect of spatial and temporal coverage and of estimating shelf-sea sensitivities to the adjacent ocean.
    Language: English
    Type: info:eu-repo/semantics/conferenceObject
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  • 3
    Publication Date: 2021-09-10
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 27 (1994), S. 5498-5503 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 113 (1991), S. 3992-3994 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 50 (1978), S. 1135-1137 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  Samples of bovine muscle, liver and urine, zeranol-free (RM 508, RM 509 and RM 510, respectively) and zeranol-containing (RM 511, RM 512 and RM 513, respectively) were prepared and tested as candidate reference materials. Preliminary studies on achievement of target zeranol content, intercomparison of analytical methods (HPLC-RIA and GC-MS) and effects of lyophilisation and irradiation on zeranol content are described. The preparation of the materials and testing for homogeneity and stability of zeranol in the materials are discussed. The coefficients of variation for zeranol determinations for between-vial homogeneity (4.0%, 4.4% and 4.6% for muscle, liver and urine, respectively) are similar to those for the analytical method (4.0%, 7.3% and 6.8% for muscle, liver and urine, respectively) indicating that the materials are homogeneous. Stability data over a 12-month storage period at temperatures ranging from −18 °C to +37 °C indicate that the materials are sufficiently stable for use as reference materials. This paper is dedicated to the memory of Dr Hilary Stevenson (The Queen’s University of Belfast/DANI) who, together with Mr. W. Graham, facilitated the irradiation of the lyophilised materials.--〉
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 2106-2107 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The photodissociation and geminate recombination of iodine in cyclohexane has been studied by directly monitoring the vibrational coordinates using transient Raman spectroscopy. Energy relaxation as a function of vibrational energy gap has been measured for vibrational spacings of 210 to 130 cm−1. These vibrational levels correspond approximately to v=3 to v=52 with energies 740 to 9300 cm−1 above the zero point level. The results support earlier experiments in that over 100 ps is required to completely relax the vibrational energy.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 1469-1477 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Two color picosecond Raman spectroscopy has been utilized to measure interligand electron transfer in the excited MLCT states of mixed ligand Ru(II) complexes. No contribution to electron transfer was found from hot vibrational levels produced by photoexcitation. For thermally relaxed vibrational levels the first direct measurement of the upper limit to the rate of interligand electron hopping is reported. It was found that the rate from the thermally equilibrated vibrational states was ≤2×106 s−1. Low temperature Raman spectra indicate that the slow rate of electron transfer creates a nonstatistical energy distribution between dissimilar ligands. The implications of these results are discussed within the framework of electron transfer theory.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 3249-3250 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Direct measurements of dynamic charge localization in tris (2,2′-bipyridyl) ruthenium (II) have been performed in fluid solution for the first time. Using picosecond Raman spectroscopy it has been determined that charge localization occurs on a time scale of (very-much-less-than)30 ps for low-viscosity solvents. In high-viscosity solvents such as glycerol at room temperature, the charge localized species Ru(bpy)2(bpy)− appears on a time scale of 100 ps. It is clear from these data that solvent reorganization is one of the dominant mechanisms in electron trapping.
    Type of Medium: Electronic Resource
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