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    Publication Date: 2021-10-22
    Description: Geobiology explores how Earth's system has changed over the course of geologic history and how living organisms on this planet are impacted by or are indeed causing these changes. For decades, geologists, paleontologists, and geochemists have generated data to investigate these topics. Foundational efforts in sedimentary geochemistry utilized spreadsheets for data storage and analysis, suitable for several thousand samples, but not practical or scalable for larger, more complex datasets. As results have accumulated, researchers have increasingly gravitated toward larger compilations and statistical tools. New data frameworks have become necessary to handle larger sample sets and encourage more sophisticated or even standardized statistical analyses. In this paper, we describe the Sedimentary Geochemistry and Paleoenvironments Project (SGP; Figure 1), which is an open, community-oriented, database-driven research consortium. The goals of SGP are to (1) create a relational database tailored to the needs of the deep-time (millions to billions of years) sedimentary geochemical research community, including assembling and curating published and associated unpublished data; (2) create a website where data can be retrieved in a flexible way; and (3) build a collaborative consortium where researchers are incentivized to contribute data by giving them priority access and the opportunity to work on exciting questions in group papers. Finally, and more idealistically, the goal was to establish a culture of modern data management and data analysis in sedimentary geochemistry. Relative to many other fields, the main emphasis in our field has been on instrument measurement of sedimentary geochemical data rather than data analysis (compared with fields like ecology, for instance, where the post-experiment ANOVA (analysis of variance) is customary). Thus, the longer-term goal was to build a collaborative environment where geobiologists and geologists can work and learn together to assess changes in geochemical signatures through Earth history. With respect to the data product, SGP is focused on assembling a well-vetted and comprehensive dataset that is tractable to multivariate statistical analyses accounting for multiple geological and methodological biases. Phase 1 of the project, which focused on the Neoproterozoic and Paleozoic, has been completed. Future phases will capture a broader range of geologic time, data types, and geography. The database contains tens of thousands of unpublished data points provided by consortium members, as well as detailed metadata that go beyond what is contained in papers. In many cases, these represent measurements that are tangential to a given published study but still of high utility to database studies; these allow the community to address questions that would be impossible to answer solely with the published data. For instance, in order to use a proxy such as Mo/TOC (total organic carbon) ratios in mudrocks deposited under a euxinic water column, the full suite of trace metal, iron speciation, and total organic carbon data is needed. Likewise, geospatial information is required to account for sampling biases, and many statistical learning approaches cannot accept, or have difficulty with, incomplete geological predictor variables. Ultimately, it is this complete data matrix that will allow for SGP’s most insightful analyses.
    Language: English
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 3
    Publication Date: 2021-02-03
    Description: We show how an extended period of quiet solar wind conditions contributes to a quiet state of the plasmasphere that expands up to L ~ 5.5, which creates the perfect conditions for wave-particle interactions between the radiation belt electrons and whistler-mode hiss waves. The correlation between the hiss waves and the plasma density is direct with hiss wave power increasing with plasma density, while it was generally assumed that these quantities can be specified independently. Whistler-mode hiss waves pitch angle diffuse and ultimately scatter freshly injected electrons into the atmosphere until the slot region is formed between the inner and outer belt and the outer belt is drastically reduced. In this study, we use and combine Van Allen Probes observations and Fokker-Planck numerical simulations. The Fokker-Planck model uses consistent event-driven pitch angle diffusion coefficients from whistler-mode hiss waves. Observations and simulations allow us to reach a global understanding of the variations in the trapped electron population with time, space, energy, and pitch angle that is based on the existing theory of quasi-linear wave-particle interactions. We show, for instance, the outer belt is pitch-angle homogeneous, which is explained by the event-driven diffusion coefficients that are roughly constant for equatorial pitch angle α0~〈60°, E〉100 keV, 3.5〈L〈Lpp~6. The impact of this work is to bring an improved understanding of the belt evolution based on the integration of high quality and highly temporally and spatially resolved measurements that are integrated in modern computations. We also propose the event-driven method as an accurate method (within ×2) to predict the electron flux decay after storms.
    Language: English
    Type: info:eu-repo/semantics/article
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  • 5
    Publication Date: 2024-04-08
    Description: We compared the performance of DREAM3D simulations in reproducing the long‐term radiation belt dynamics observed by Van Allen Probes over the entire year of 2017 with various boundary conditions (BCs) and model inputs. Specifically, we investigated the effects of three different outer boundary conditions, two different low‐energy boundary conditions for seed electrons, four different radial diffusion (RD) coefficients (DLL), four hiss wave models, and two chorus wave models from the literature. Using the outer boundary condition driven by GOES data, our benchmark simulation generally well reproduces the observed radiation belt dynamics inside L* = 6, with a better model performance at lower μ than higher μ, where μ is the first adiabatic invariant. By varying the boundary conditions and inputs, we find that: (a) The data‐driven outer boundary condition is critical to the model performance, while adding in the data‐driven seed population doesn't further improve the performance. (b) The model shows comparable performance with DLL from Brautigam and Albert (2000, https://doi.org/10.1029/1999ja900344), Ozeke et al. (2014, https://doi.org/10.1002/2013ja019204), and Liu et al. (2016, https://doi.org/10.1002/2015gl067398), while with DLL from Ali et al. (2016, https://doi.org/10.1002/2016ja023002) the model shows less RD compared to data. (c) The model performance is similar with data‐based hiss models, but the results show faster loss is still needed inside the plasmasphere. (d) The model performs similarly with the two different chorus models, but better capturing the electron enhancement at higher μ using the Wang et al. (2019, https://doi.org/10.1029/2018ja026183) model due to its stronger wave power, since local heating for higher energy electrons is under‐reproduced in the current model.
    Language: English
    Type: info:eu-repo/semantics/article
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 2208-2213 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Both NO and CO preferentially chemisorb on step sites of the Pt(112) crystal orienting the intermolecular bond in the downstairs direction. Using the digital electron stimulated desorption-ion angular distribution method (ESDIAD), an elliptical angular distribution of the desorbing O+ ions was detected from the NO/Pt(112) system, with the longer axis of the ellipse normal to the step-edge direction. On the other hand, the O+ ESDIAD pattern from the CO/Pt(112) system shows an approximately cylindrical symmetric shape. Heating of the crystal leads to broadening of the ion desorption patterns in both cases without change in the patterns' elliptical or circular cross-sectional geometry. These results are interpreted as being due to ion desorption from NO molecules bonded to two Pt atoms on the step edge and vibrating with a longer amplitude in the direction perpendicular to the step. In the case of CO, bonded to a single Pt atom, the amplitude of vibration is approximately the same in directions parallel and perpendicular to the step edge. Thus, in certain cases ESDIAD patterns may be used to determine the hybridization state of adsorbates.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 7245-7254 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The structure of chemisorbed CO on the steps of Pt(112) {Pt[3(111)×(001)]} was monitored as a function of coverage by the digital electron stimulated desorption-ion angular distribution method (ESDIAD), digital low-energy electron diffraction (LEED), and temperature-programmed desorption (TPD). The ESDIAD method applied to the desorption of an electronically excited, neutral CO species (the metastable a3 π-CO state) avoids the influence of image potential effects on the trajectory of desorbing species, yielding true desorption angles, equivalent to Pt-CO bond orientations. CO adsorbs exclusively on step sites at low coverage with a 20° "downstairs'' tilt from the [112] direction (designated "0°''). LEED indicates (2×n) order (i.e., two-fold order along the steps but no order up/down the steps) exists when the steps are half-filled (about 0.19 ML). At 0.24 ML, CO is still adsorbed only on the step sites but one-dimensional CO–CO repulsions between nearest neighbors result in CO tilting along the steps. Terrace CO (+13°) adsorption is observed above 0.24 ML before all the step sites fill. All step CO molecules reorient with new tilt angles up (0°) and down (−38°) the steps when the steps sites saturate (0.53 ML), and (3×1) order is observed by LEED. The surface reorders at saturation (0.79 ML) to (2×1) order. Changes in CO desorption energies, pre-exponential factors and sticking coefficients with coverage in the literature for Pt[n(111)×(001)] surfaces can be directly correlated with structural transformations on the partially filled steps due to CO–CO repulsions.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 7255-7264 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The relative shape of the hindered translation potential energy well for CO chemisorbed on the step sites of a Pt(112) single crystal was determined with digital electron stimulated desorption–ion angular distribution (ESDIAD). The angular displacement of the CO molecule in its hindered translation well predominately determines the half-width at half-maximum (HWHM) of the neutral a3π CO species (CO*) produced by ESD, a species which may be imaged in an ESDIAD apparatus. Variations in the CO* ESDIAD HWHM as a function of temperature are due to population of higher levels of the hindered translational mode. By monitoring the CO* ESDIAD HWHM for CO coverages on the step below 50% step saturation (0.17 monolayer) as a function of temperature, we show that the steepness of the hindered translation potential well is different for CO vibrations up, down, and along the step edge, following the trend: down the steps〉up the steps〉along the steps. There is no coverage dependence in the CO* ESDIAD HWHM values up or down the steps, but the HWHM values along the steps at 0.17 monolayer CO are significantly broader than those from lower coverages in the temperature range of 150–350 K. We interpret this to indicate the production of transient structures of tilted CO on adjacent step sites formed from preferential diffusion of CO molecules laterally on the step sites. Thus, the experiments probe directly the anisotropy of lateral diffusion of the adsorbate on step sites.
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  • 9
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 175 (1955), S. 634-635 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Fig. 1. A, vanillic acid; B, syringic acid Fig. 1 shows the result when birch extracts were sprayed with diazotized sulphanilio acid. With this spray, vanillic acid gives an orange spot and syringic acid a red spot. Both extracts showed strong spots of each of these acids, whereas the control ...
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