ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The direct electrochemical synthesis of fluorides of Tl in nonaqueous solvents in the presence of tetraalkylammonium fluoride polyhydrofluorides has been carried out. 2. It has been shown that the anodic dissolution of thallium in a glass cell in the presence of a tetraalkylammonium fluoride polyhydrofluoride results in the formation of Tl2SiF6 and the previously unknown compound Tl3[SiF6]F. 3. An x-ray structural investigation of the compound Tl3[SiF6]F has been carried out. It has been shown that the structure is built up from hexafluorosilicate anions (SiF6 2−), thallium cations (Tl+), and fluoride ions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00957038
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