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Tin(II) Fluoride Compounds with Mixed Acidoligands: Synthesis and Crystal Structure of NH4[SnF2(NCS)]

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Abstract

The NH4[SnF2(NCS)] compound was obtained and its structure was determined. The tin atom is surrounded by two fluorine atoms (Sn–F 2.060 Å) and one nitrogen atom of the NCS group (Sn–N 2.351 Å). The coordination polyhedron of tin(II) is a distorted trigonal pyramid with a stereochemically active lone electron pair at the vertex.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    Yu. V. Kokunov, D. G. Detkov, Yu. E. Gorbunova, M. M. Ershova & Yu. N. Mikhailov

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  1. Yu. V. Kokunov
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  2. D. G. Detkov
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  3. Yu. E. Gorbunova
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  4. M. M. Ershova
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  5. Yu. N. Mikhailov
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Kokunov, Y.V., Detkov, D.G., Gorbunova, Y.E. et al. Tin(II) Fluoride Compounds with Mixed Acidoligands: Synthesis and Crystal Structure of NH4[SnF2(NCS)]. Russian Journal of Coordination Chemistry 26, 857–860 (2000). https://doi.org/10.1023/A:1026674808129

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  • DOI: https://doi.org/10.1023/A:1026674808129

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