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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of agricultural and food chemistry 18 (1970), S. 135-142 
    ISSN: 1520-5118
    Source: ACS Legacy Archives
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 288 (1977), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of paleolimnology 2 (1989), S. 263-283 
    ISSN: 1573-0417
    Keywords: paleolimnology ; lake ; lake sediment ; Quaternary ; limnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract I describe Quaternary paleolimnology on the basis of a review of abstracts published for meetings of: (1) American Society of Limnology and Oceanography (ASLO), 10 meetings since 1980; (2) International Association of Theoretical and Applied Limnology (SIL), 4 since 1977, (3) International Symposia on Paleolimnology (ISP), 4 since 1967, and (4) International Union for Quaternary Research (INQUA), 5 since 1969. A total of 9538 abstracts were scanned to find 678 with paleolimnological content. A data base constructed from the 678 contains frequencies of coverage of techniques, parameters, themes, interpretive aspects, and character and geography of study sites. These data indicate that Quaternary paleolimnology has been a diverse science dealing with many of the same aspects of lakes as neolimnology but with a longer time perspective. Most frequently studied paleolimnological characteristics were trophic state, water chemistry (particularly salinity, pH, alkalinity (ANC), micronutrients and oxygen), water levels, lake morphology, and mixis and other hydrology. Lake biological parameters that received greatest attention were diatoms, pigments, Cladocera, Mallomonadaceae, non-siliceous algae, Ostracoda, and Mollusca. Most often considered to influence these characteristics and parameters were climate; catchment vegetation, soil, geology, land use and erosion; water chemistry; aerial and non aerial pollutants; sedimentation; and tectonism. Most frequent chronologic sequences were (1) late-glacial to present, and (2) modern (ca. 0.3 ka to present). Lakes in moist temperate and boreal regions were most heavily studied. Of the four series, INQUA covered the longest time scales (to late Tertiary), but emphasized the last 100 ka. INQUA stressed outside-lake geomorphology (as it relates to lake) and lake morphology, physical forcing functions (e.g., climate and tectonism), hydrologic factors including water levels, paleosalinities, and reconstruction of paleoclimates. In contrast, SIL and ASLO rarely covered pre-15 ka. Most SIL and ASLO abstracts dealt with only the most recent ∼ 0.3 ka. Of strong interest to SIL and ASLO were the effects of catchment vegetation and soils, land uses, and pollutants (e.g., acid deposition) on past lake chemistry, biology, and trophic conditions. To infer these conditions from sediment contents, frequent use was made of modern analogues and, starting in the 1970's of microfossil (mostly diatoms) transfer functions based on calibration data sets. In several respects, ISP subject coverage and approaches were intermediate between those of INQUA and SIL/ASLO. Major improvements in paleolimnology have occurred since the 1960's, particularly in the areas of chronology and use of multivariate statistical techniques for paleoenvironmental inference based on microfossils. I conclude this paper with several suggestions for further advancement of the science.
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 316 (1985), S. 436-438 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The understanding of the acidification of lakes through acidic inputs from the atmosphere has been limited by a paucity of direct measurement of p H and related water chemistry before 25 yr ago. Palaeolimnological reconstructions of lake-pH based on diatom remains in sediment has helped to fill ...
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of paleolimnology 12 (1994), S. 103-154 
    ISSN: 1573-0417
    Keywords: acidification ; alkalization ; pH ; alkalinity ; diatoms ; sediment chemistry ; New England ; catchment effects ; land use ; logging ; acidic deposition ; air pollutants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Studies of sediment cores from 12 acidic lakes in granitic, forested and uninhabited catchments in northern New England, U.S.A. produced diatom-inferred pH (IpH) 5.2 to 5.8 and alkalinity (Ialk) −12 to 31 µeq l−1, with slowly declining values at some lakes, for one to four centuries prior to logging. Increases of IpH (Δ0.05 to 0.60) and Ialk (Δ5 to 40 µeq l−1) correlate with logging in the catchments in the early-1800s to early-1900s. Recovery to pre-logging IpH and Ialk correlates with forest succession toward conifers, and is completed in the late-1800s to mid-1900s. Beginning at 1915–1920 (4 lakes), 1930–1950 (4 lakes) and 1965–1970 (4 lakes), IpH and Ialk start decreasing below pre-logging values due to atmospheric acidic deposition, leading to respective total decreases of 0.10 to 0.45 (X=0.25) and 5 to 25 µeq l−1 (X=15). Inputs of anthropogenic Pb, Zn, V, polycyclic aromatic hydrocarbons, and soot from the atmosphere are first detectable in early- to late-1800s sediment, and Cu in late-1800s sediment, increase rapidly in the late-1800s to mid-1900s, and level off or decrease since the 1960s — partly due to emission controls. Decreasing Ca, Mn, and possibly Zn relative to other metals and normalized to organic content, and increasing flux of Fe to the lakes, indicate soil and water acidification after 1900.
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  • 6
    ISSN: 1573-0417
    Keywords: scaled chrysophytes ; pH reconstructions ; algal microfossils ; lake acidification ; paleolimnology ; New England ; CCA ; DCA ; PCA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Scaled chrysophytes in the surface sediments of 58 soft-water northern New England lakes were analyzed to assess their usefulness for inferring pH. The distributions of many taxa are correlated with lakewater pH and associated variables. Canonical correspondence analysis (CCA) and clustering grouped chrysophyte taxa according to their distributions along the pH gradient. For example, Chrysodidymus synuroideus, Mallomonas hindonii, and M. hamata commonly occur in acidic waters (pH〈5.5), whereas M. caudata and M. pseudocoronata are common in circumneutral to alkaline waters. Of the five predictive models developed to infer pH, CCA based calibration had the lowest standard error (0.35 pH units). A CCA based predictive model was also developed to infer total alkalinity. The study provides strong evidence that, in the absence of past measured pH data, stratigraphic studies of sedimentary chrysophyte scales will provide accurate reconstructions of pH in northern New England lakes.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-5117
    Keywords: pH ; alkalinity ; indicators
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A series of laboratory and field studies were conducted to evaluate the reliability of colorimetric pH indicators in dilute, acidic surface waters in New England. Laboratory studies consisted of comparing colorimetric and electrometric pH results in synthetic solutions with a range of ionic strength and buffering capacity. Field studies involved simultaneous colorimetric and electrometric pH determinations in 52 New England lakes with differing water chemistry. Colorimetric indicators deviated from electrometric pH results at low alkalinities and near the end of their operating range. They agreed with electrometric values, within 0.2 unit, at alkalinities of 20 µeq 1-1 and greater, or near the center of their operating range. Changing ionic strength without changing buffering capacity did not affect results. When indicators were selected that bracketed sample pH, colorimetric determinations of pH in New England lakes agreed well with electrometric determinations.
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  • 8
    ISSN: 1573-5117
    Keywords: paleolimnology ; acidic precipitation ; lake acidification ; heavy metal pollution ; diatoms ; cladocerans
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Sediment cores from nine lakes in southern Norway (N) and six in northern New England (NE) were dated by 137Cs, 210Pb and in NE also by pollen, and were analyzed geochemically and for diatoms. Cores from two N and three NE lakes were analyzed for cladocerans. 137Cs dating is unreliable in these lakes, probably due to mobility of Cs in the sediment. In Holmvatn sediment, an up-core increase in Fe, starting ca. 1900, correlates with geochemical indications of decreasing mechanical erosion of soils. Diatoms indicate a lake acidification starting in the 1920's. We propose that soil Fe was mobilized and runoff acidified by acidic precipitation and/or by soil acidification resulting from vegetational succession following reduced grazing. Even minor land use changes or disturbances in lake watersheds introduce ambiguity to the sedimentary evidence relating to atmospheric influences. Diatom counts from surface sediments in 36 N and 31 NE lakes were regressed against contemporary water pH to obtain coefficients for computing past pH from subsurface counts. Computed decreases of 0.3–0.8 pH units start between I890 and I930 in N lakes already acidic (pH 5.0–5.5) before the decrease. These and lesser decreases in other lakes start decades to over a century after the first sedimentary indications of atmospheric heavy metal pollution. It is proposed that the acidification of precipitation accompanied the metal pollution. The delays in lake acidification may be due to buffering by the lakes and watersheds. The magnitude of acidification and heavy metal loading of the lakes parallels air pollution gradients. Shift in cladoceran remains are contemporary with acidification, preceding elimination of fishes.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 30 (1986), S. 311-318 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Historical evidence of acid deposition and its effects which was presented at Muskoka, Ontario in September, 1985 is summarized. This evidence consists of written records of the past chemistry and biology of atmospheric, terrestrial, and aquatic systems; it also includes evidence from archived collections which were “revisited”, from tree rings, and from the chemical and biological “records” in lake sediment and peat from which histories of airborne contaminants and ecosystem responses to these contaminants were inferred.
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  • 10
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The PIRLA project is an interdisciplinary paleoecological study designed to provide reconstructions of the recent acidification histories of a representative set of lakes in four acid-sensitive regions in North America. We are trying to determine if lakes in the study regions have acidified, and if so, to what extent, over what time period and why. Sediment cores from 5 to 15 lakes in each region are being analyzed for several characteristics. Diatoms and chrysophytes are being used to reconstruct lakewater pH. Results for three Adirondack lakes with current pH of 4.8 to 5.0 indicate a decrease in pH beginning in the 1930's–1950's. Increased atmospheric deposition of strong acids appears to be the primary factor responsible for the pH decline. Two lakes (pH 4.4 and 4.7) in New England show clear evidence of acidification probably due to acidic deposition. Preliminary reconstructions for two lakes in Michigan (pH 4.4 and 5.6), one in Wisconsin (pH 5.3), and one in Minnesota (pH 6.8) suggest no recent pH decrease. For, the one Florida lake (pH 4.4) analyzed, inferred pH decreases by about 0.5 unit, beginning in the 1950s; the cause has not been determined.
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