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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 10 (1975), S. 1779-1787 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A model is presented to describe the creep behaviour of glassy polymers below the glass transition temperature. It consists of a Hookean spring in series with a non-Newtonian dashpot having an entropy spring in parallel. The shape of the response of this spring is deduced from a master curve, giving the extension as a function of logarithm of time, built from creep data, reported here and obtained on polycarbonate over a wide range of times and temperatures. The model takes into account a number of aspects of creep behaviour and predicts a threshold stress beneath which delayed yielding no longer occurs. Torsional creep data, obtained on Polyvinylchloride by Mallon and Benham are found to be in excellent agreement with the proposed model.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 14 (1979), S. 1817-1826 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The viscoelastic behaviour of three different samples of polycarbonate, with differing pre-treatment, is described here by a generalized non-linear Maxwell system, proposed previously. This model gives the variation of the tensile yield stress related to each sample as a function of temperature and strain rate. The response is checked over a large range of strain rates, at temperatures from 20 to 80° C. The model allows the determination of the damping peak arising from the molecular movements which it expresses. A correspondence is found with the intermediate loss peak location, which occurs for each sample just below the α transition. Results obtained from dynamic mechanical tests and differential scanning calorimetry show that the structure of the samples changes in the range of temperatures where the intermediate loss peak arises at 1 Hz.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 7 (1972), S. 176-183 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The tensile yield stress is compared with the uniaxial compression yield stress for specimens of polycarbonate tested at constant strain rate from −120 to + 120°C. The strain rate dependence of the tensile yield stress is also studied from − 140 to + 20°C. The yield behaviour is described by a modification of the Eyring theory of non-Newtonian viscosity where the deformation is supposed to involve two different flow processes. The validity of a yield criterion previously established by one of us, is checked throughout the range of temperatures explored; the proposed equation gives a good fit to the data provided it is applied separately to each flow process. Then the present investigation, combining the yield condition with the modified Eyring theory, provides a formalism which agrees with the data and accurately renders the temperature, strain rate and pressure dependence of the yield stress of polycarbonate.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 9 (1974), S. 1197-1201 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 34 (1999), S. 1701-1709 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The loss peak, called α′, appearing as a shoulder in the left wing of the α peak in dynamic mechanical measurements is used to follow the very long term ageing at room temperature of samples of Polycarbonate rejuvenated by cold rolling or by quenching prior to ageing. This peak shifts to higher temperature with increasing ageing time ta. An approximate linear increase with ln ta is found with a similar slope of about 8 K/decade for both kinds of samples. The shape and the magnitude of the peak are strongly dependent on the treatment given to the samples before ageing. It is assumed that ageing at room temperature and below results from an activated process additive to the annealing process prevailing at higher temperatures up to Tg. This ageing process which depends of the pretreatment is characterized by a lower activation energy than the annealing one. Taking these assumptions into account, experimental data are shown to agree reasonably with the predictions of a model previously proposed.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 7 (1972), S. 176-183 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The tensile yield stress is compared with the uniaxial compression yield stress for specimens of polycarbonate tested at constant strain rate from −120 to + 120°C. The strain rate dependence of the tensile yield stress is also studied from − 140 to + 20°C. The yield behaviour is described by a modification of the Eyring theory of non-Newtonian viscosity where the deformation is supposed to involve two different flow processes. The validity of a yield criterion previously established by one of us, is checked throughout the range of temperatures explored; the proposed equation gives a good fit to the data provided it is applied separately to each flow process. Then the present investigation, combining the yield condition with the modified Eyring theory, provides a formalism which agrees with the data and accurately renders the temperature, strain rate and pressure dependence of the yield stress of polycarbonate.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 8 (1973), S. 968-979 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The compression yield behaviour of PMMA has been investigated, here, over a wide range of experimental conditions which cannot be reached in tensile tests owing to the brittle nature of the material. The plot of the ratio of the compression yield stress to absolute temperature, as a function of the logarithm of the strain-rate, gives a set of parallel curves which can be accurately superimposed by shifting along a slanting straight line. A master curve is built from which the yield behaviour may be predicted for any state of stress, or value of temperature and strain-rate in the glassy range, using Bauwens' yield criterion. The validity of the procedure is checked for compression tests at low temperatures, for tensile tests in the range of experimental conditions where PMMA yields and for torsional tests under hydrostatic pressure (data of Wardet al). In every case, the fit is found to be quite accurate. A region of experimental conditions is determined where the compression yield behaviour may not be described by the Ree-Eyring treatment involving a hyperbolic sine function. In this region, the Bauwens approach, which consists of a modification of the Ree-Eyring theory, taking into account a distribution of relaxation times and linking the yield behaviour with theβ mechanical loss peak, is found to give an acceptable fit to the data.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 7 (1969), S. 735-742 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: It is shown that, at the yield stress, glassy polymers exhibit viscous flow which is in agreement with the generalized theory of Eyring. The study of the yield stress over a wide range of temperatures and strain rates provides evidence on the secondary transitions found by other methods. From our measurements we conclude that every secondary transition corresponds to the liberation of one of the degrees of freedom of a segment of the main chain.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 7 (1969), S. 1745-1754 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The yield-stress behavior of two glassy polymers is studied through the glass transition region over a wide range of strain rates. For temperatures below the glass transition temperature, the yield stress behavior could be described as a non-Newtonian flow in agreement with Eyring's theory, if one excepts a narrow range relating to the slowest strain rates. For temperatures above Tg, the yield-stress behavior is still nonlinear but fits the relations based on the concept of free volume.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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