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  • 1
    ISSN: 1520-6041
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1440-1738
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract A 1800 m deep borehole was drilled at Nojima Hirabayashi, Japan to penetrate through the Nojima Fault, which was activated at the time of the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake). Three fracture zones were recognized in cores at approximate depths of 1140 m, 1300 m and 1800 m. The mode of distribution of fault rocks, minerals and chemical elements were analyzed in an interval between depths of 1108 m and 1161 m, focusing on the fracture zone at the depth of 1140 m. Foliated blue-gray fault gouge constituted the central part of the fracture zone. The degree of fracturing appeared to be greater in the hanging wall than in the footwall. The relative amounts of minerals were estimated qualitatively. In the analyzed interval, not only were quartz, orthoclase, plagioclase, biotite and hornblende detected in the parent rock (granodiorite), but also kaolinite, smectite, laumontite, stilbite, calcite, ankerite and siderite, which are related to hydrothermal alteration. In particular, biotite disappeared both in the hanging wall and footwall across the central fault zone; it disappeared over a wider range in the hanging wall than in the footwall. The amounts of major chemical elements were analyzed quantitatively. Concentrations of Al2O3, Fe2O3, MnO, TiO2, and P2O5 all decreased throughout the interval except at some points. H2O+ and CO2 increased throughout the interval. Na2O increased in the region outside the central plane, whereas MgO and CaO increased in the hanging wall and decreased in the footwall. SiO2 and K2O decreased in the hanging wall and increased in the footwall. These results elucidate the higher degree of fracturing and chemical changes present in the hanging wall of the 1140 m fracture zone than in the footwall.
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  • 3
    ISSN: 1440-1738
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Characteristics of deformation and alteration of the 1140 m deep fracture zone of the Nojima Fault are described based on mesoscopic (to the naked eye) and microscopic (by both optical and scanning electron microscopes) observations of the Hirabayashi National Research Institute for Earth Science and Disaster Prevention (NIED) drill core. Three types of fault rocks; that is, fault breccia, fault gouge and cataclasite, appear in the central part of the fault zone and two types of weakly deformed and/or altered rocks; that is, weakly deformed and altered granodiorite and altered granodiorite, are located in the outside of the central part of the fault zone (damaged zone). Cataclasite appears occasionally in the damaged zone. Six distinct, thin foliated fault gouge zones, which dip to the south-east, appear clearly in the very central part of the fracture zone. Slickenlines plunging to the north-east are observed on the surface of the newest gouge. Based on the observations of XZ thin sections, these slickenlines and the newest gouge have the same kinematics as the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake), which was dextral-reverse slip. Scanning electron microscopy observations of the freeze-dried fault gouge show that a large amount of void space is maintained locally, which might play an important role as a path for fluid migration and the existence of either heterogeneity of pore fluid pressure or strain localization.
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  • 4
    ISSN: 1440-1738
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract An 1800 m borehole was drilled into the Nojima Fault Zone at Ogura, Awaji Island, Hyogo prefecture, Japan. The chemical compositions and isotope ratios of gases extracted from the drill core were investigated. Major components were carbon dioxide (CO2) and methane (CH4). Microcracks in granodiorite outside the fracture zone were occupied mainly by CO2, and this CO2 is interpreted to have generated biogenically at shallow depths based on the measured δ13C value of –17 to –22. The CO2 gas was probably transported with underground water to deeper portions to fill microcracks in the basement granodiorite with CO2. However, the pores in the fracture zone are occupied predominantly by CH4. The ratio of CH4 to ethane (C2H6), 80 to100, and δ13C of CH4, –40 to –52, suggest that CH4 and C2H6 formed by the thermal decomposition of organic materials at temperatures above 75°C. We interpret that they originated at depths from organic materials and migrated upwards through the fault zone. It is interpreted that the concentration of CO2 in the fracture zone has decreased by the replacement with CH4 and/or by the consumption of CO2 in fault clay minerals. Although hydrogen (H2) and helium (He) were minor components of the gases from cores, they increased in quantity in the fracture zone. High concentration of H2 in the fracture zones is consistent with the idea that H2 was generated by radical reactions on the fresh surface of fractured rocks during the earthquake. The 3He/4He ratio of 0.723 Ra in the fracture zones suggests that He is of radiogenic origin; that is, it is not from the mantle.
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  • 5
    ISSN: 1618-0860
    Keywords: Keywords: Acidic condition, Growth, Lateral root, Lettuce, Low pH, Root hair
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 36 (1998), S. 421-428 
    ISSN: 0887-624X
    Keywords: poly(siloxane)-supported zirconocene catalysts ; polymerizations of ethene and propene ; copolymerization of ethene with 1-octene ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(siloxane)s with bisindenyl, bisfluorenyl, bis(1,2,3,4-tetramethylcyclopentadienyl), bis(2,4,7-trimethylindenyl) and monoindenylmethyl side groups were synthesized by condensation of the corresponding dichlorosilanes and water. For reference, diphenylsilanediol or hydroquinone was also employed in place of water. A series of poly(siloxane)-supported zirconocene catalysts were then prepared from these precursors and applied to ethene and propene polymerizations as well as to the copolymerization of ethene with 1-octene in the presence of methylalumoxane. The polymerization activity of the new supported metallocenes depends drastically upon the substituents in the siloxane backbone. The zirconocene catalysts supported on poly(bisindenylsiloxane) and poly(bisfluorenylsiloxane) give the highest activities for ethene and propene polymerizations, respectively. The weight-average molecular weights of the polymers are also markedly dependent upon the substituents. On the other hand, the molecular mass distributions (MMD) are generally not so sharp, suggesting that the active species formed in these supported catalysts are not uniform. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 421-428, 1998
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 16 (1995), S. 905-911 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Three kinds of zirconocene catalysts, supported on polysiloxanes substituted with methylindenyl, methyl-fluorenyl and two indenyl groups, respectively, were prepared and applied to propene and ethylene polymerizations using methylaluminoxane as cocatalyst. Both the activity and stereospecificity of these catalysts were found to lie between those of corresponding homogeneous and SiO2-supported catalysts. Surprisingly, all the catalysts gave a mixture of atactic and isotactic poly(propylene), plausible reasons for which are briefly discussed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 16 (1995), S. 379-385 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: From a detailed analysis of poly[ethylene-co-(1-hexene)] obtained with typical metallocene catalysts, it was found that metallocene catalysts give two kinds of copolymers which differ in crystallinity. It may be thus plausible to assume that there are two kinds of active species in metallocene catalysts.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 16 (1995), S. 821-830 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Several kinds of polystyrene-supported metallocene catalysts were prepared and used in the polymerizations of propylene and ethylene with methylaluminoxane (MAO) as cocatalyst. It was found that these catalysts are stable even at 70°C. They display fairly high activities when the polymerizations are conducted at high temperatures.
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 198 (1997), S. 229-237 
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polysiloxanes with bisindenyl, bisfluorenyl, and bis(1,2,3,4-tetramethyl)cyclopentadienyl side groups were synthesized by condensation of the corresponding dichlorosilane compounds and water to obtain supported ziroconocene catalysts. The polymerization of ethene was conducted over these catalysts combined with methylalumoxane. The polymerization activity depends markedly upon the substituents and decreases in the order: bisindenyl ≫ bisfluorenyl ≫ bis(1,2,3,4-tetramethylcyclopentadienyl). All the supported catalysts give linear polyethene with fairly high molecular weights. The catalyst with bisindenyl groups was found to be composed of a toluene-soluble and a toluene-insoluble fraction. The polymerization profile (activity versus time curve) was analyzed with the toluene-soluble and -insoluble fraction as well as the corresponding homogeneous system. The homogeneous system, which exerts the highest activity in the initial phase, was completely deactivated after several hours whereas the activity of the supported catalyst, especially of the toluene-insoluble fraction, was unchanged during 12 h even at 70°C. Polysiloxanes with different content of bisindenyl groups were also synthesized via the co-condensation with dimethyldichlorosilane and applied as the carrier. However, the activity per Zr atom decreases remarkably with an increase in dimethylsilane units.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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