ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Transition Metal Substituted Phosphanes, Arsanes, and Stibanes, XLVI. Some Reactions of the Ferrio-phosphane C5Me5(CO)2Fe — PPh2 and Molecular Structure of its Borane AdductThe reaction of Na[Fe(CO)2C5Me5] (1) with Ph2PCl in benzene results in the formation of the title complex 2. Treatment of 2 with elemental sulfur, MeI, or BH3 · THF produce the iron-substituted derivatives C5Me5(CO)2Fe — P(S)Ph2 (3), [C5Me5(CO)2Fe — P(Me)Ph2]I (4) or C5Me5(CO)2Fe — PPh2 — BH3 (5), respectively. The structure of the ferrio-phosphane-borane 5 is elucidated by X-ray crystal structure analysis.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19851180339
Permalink