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  • 1
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    Unknown
    PANGAEA
    In:  Swedish Museum of Natural History
    Publication Date: 2023-09-30
    Keywords: Arctic Ocean; ARK-XXII/2; CTD/Rosette, ultra clean; CTD-UC; Date/Time of event; DEPTH, water; Elevation of event; Event label; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; Latitude of event; Longitude of event; Neodymium; Neodymium-143/Neodymium-144 ratio; Neodymium-143/Neodymium-144 ratio, error; Polarstern; PS70/271-2; PS70/272-1; PS70/276-1; PS70/279-2; PS70/400-1; PS70/407-1; PS70/411-1; PS70 SPACE DAMOCLES; Sample code/label; see comment; ε-Neodymium; ε-Neodymium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 90 data points
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  • 2
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    Unknown
    PANGAEA
    In:  Supplement to: Clayton, Robin E; Nederbragt, Alexandra J; Malinovsky, Dmitry; Andersson, Per S; Thurow, Juergen W (2007): Data report: iron isotope geochemistry of mid-Cretaceous organic-rich sediments at Demerara Rise (ODP Leg 207). In: Mosher, DC; Erbacher, J; Malone, MJ (eds.) Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 207, 1-14, https://doi.org/10.2973/odp.proc.sr.207.109.2007
    Publication Date: 2024-01-09
    Description: Fe isotope measurements are presented for 10 samples from the Cenomanian-Turonian black shale unit in Hole 1260B at Demerara Rise. The samples bracket the latest Cenomanian ocean anoxic event and were selected to ascertain whether Fe isotopes can be used to gain a better understanding of oceanic redox conditions during the mid-Cretaceous. Three extraction procedures were used to provide Fe extracts that represent the Fe oxide (average FeCBD = 0.07 wt%, N = 8), Fe oxide-sulfide-carbonate (average FeAR = 0.34 wt%, N = 10), and total Fe fractions (average FeHF = 0.81 wt%, N = 10). Fe isotope measurements were conducted on all FeAR extracts as a priority as these were considered to best reflect changes in the redox environment. d56Fe values range between 0.02 per mil ± 0.09 per mil and -0.77 per mil ± 0.05 per mil and appear to correlate negatively with the C/N ratio and oxygen index of total organic carbon. Isotopic measurements of two Fe oxide (FeCBD) extracts show a much heavier isotopic composition (d56Fe = 0.74 per mil ± 0.08 per mil and 0.63 per mil ± 0.04 per mil), which suggests isotopic partitioning between different mineral components in the sediment.
    Keywords: 207-1260; COMPCORE; Composite Core; DEPTH, sediment/rock; DSDP/ODP/IODP sample designation; Iron; Joides Resolution; Leg207; MC-ICP-MS Thermo-Finnigan Neptune; Ocean Drilling Program; ODP; Percentage; Sample code/label; South Atlantic Ocean; Weighted; δ56Fe; δ56Fe, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 84 data points
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  • 3
    Publication Date: 2020-07-09
    Description: Abstract A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river-influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high-resolution pan-Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25�50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle-reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s�1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
    Publication Date: 2021-03-16
    Description: 231Pa, 230Th and 232Th were analyzed in filtered seawater (n=70) and suspended particles (n=39) collected along a shelf-basin transect from the Barents shelf to the Makarov Basin in the Arctic Ocean during GEOTRACES section GN04 in 2015. The distribution of dissolved 231Pa and 230Th in the Arctic Ocean deviates from the linear increase expected from reversible scavenging. Higher 232Th concentrations were observed at the shelf, slope and in surface waters in the deep basin, pointing at lithogenic sources. Fractionation factors (FTh/Pa) observed at the Nansen margin were higher compared to FTh/Pa in the central Nansen Basin, possibly due to the residual occurrence of hydrothermal particles in the deep central Nansen Basin. Application of a boundary scavenging model quantitatively accounts for the dissolved and particulate 230Th distributions in the Nansen Basin. Modelled dissolved 231Pa distributions were largely overestimated, which was attributed to the absence of incorporation of water exchange with the Atlantic Ocean in the model. 231Pa/230Th ratios of the suspended particles of the Nansen Basin were below the 231Pa/230Th production ratio, but top-core sediments of the Nansen margin and slope have high 231Pa/230Th-ratios, suggesting that scavenging along the Nansen margin partly acts as a sink for the missing Arctic 231Pa.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 5
    Publication Date: 2019-07-17
    Description: Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES program as well as a proof-of-concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes, and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium (T1/2=5.75 y), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange, and rivers. Model-derived shelf 228Ra fluxes are combined with TEI/ 228Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn, and Zn inputs and exceed published estimates of atmospheric deposition by factors of ~3-23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 6
    Publication Date: 2018-08-08
    Description: In seawater, particle reactive 231Pa and 230Th are uniformly produced by decay of soluble 235U and 234U. Due to differences in particle reactivity, 230Th tends to be removed to the sediment close to its production site, while 231Pa is more prone to lateral transport and is removed to the sediments in areas of high particle flux (i.e. boundary scavenging). Due to a combination of perennial ice cover, large shelf areas and river runoff, boundary scavenging in the Arctic Ocean strongly impacts the distribution of 231Pa and 230Th in the water column. Here, 231Pa and 230Th were analyzed in seawater and particles from the Arctic GEOTRACES section GN04 along the Barents shelf and in the Nansen basin. Key observations include lower concentrations of dissolved 231Pa and 230Th on the Barents shelf compared to the Nansen basin, indicating enhanced removal of 231Pa and 230Th near the margin. The particulate nuclide/total nuclide ratio increases from the surface (0.2% for 231Paxs and 0.7% for 230Thxs) to the seafloor (11% for 231Paxs and 71% for 230Thxs), highlighting the role of deep scavenging. The fractionation factor between 231Pa and 230Th (FTh/Pa) ranges from ~3 to 25 and generally increases with depth. Comparison between suspended particles and sediments will be provided. Further, dissolved 231Paxs and 230Thxs concentrations in the Nansen basin are lower compared to concentrations measured 20 years ago1 . This might reflect changes in particle flux and/or changes in circulation patterns. 1 Scholten, J., Rutgers van der Loeff, M., 1995. Distribution of 230Th and 231Pa in the water column in relation to the ventilation of the deep Arctic basins. Deep. Res. Part II 42, 1519–1531.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 7
    Publication Date: 2021-12-08
    Description: Abstract A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river-influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high-resolution pan-Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600Â km horizontally and ~25-50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle-reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (10^6 m3 s-1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 8
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015920, doi:10.1029/2019JC015920.
    Description: A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river‐influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high‐resolution pan‐Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25–50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle‐reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s−1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
    Description: Funding for Arctic GEOTRACES was provided by the U.S. National Science Foundation, Swedish Research Council Formas, French Agence Nationale de la Recherche and LabexMER, Netherlands Organization for Scientific Research, and Independent Research Fund Denmark. Data from GEOTRACES cruises GN01 (HLY1502) and GN04 (PS94) have been archived at the Biological and Chemical Oceanography Data Management Office (Biological and Chemical Oceanography Data Management Office (BCO‐DMO); https://www.bco-dmo.org/deployment/638807) and PANGAEA (https://www.pangaea.de/?q=PS94&f.campaign%5B%5D=PS94) websites, respectively. The inorganic carbon data are available at the NOAA Ocean Carbon Data System (OCADS; doi:10.3334/CDIAC/OTG.CLIVAR_ARC01_33HQ20150809).
    Description: 2020-10-08
    Keywords: Arctic Ocean ; Transpolar Drift ; trace elements ; carbon ; nutrients ; GEOTRACES]
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 9
    Publication Date: 2022-05-26
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Philosophical Transactions of the Royal Society A 374 (2016): 20160076, doi:10.1098/rsta.2016.0076.
    Description: Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as well as a proof of concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium (T1/2 = 5.75 yr), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange and rivers. Model-derived shelf 228Ra fluxes are combined with TEI/ 228Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn and Zn inputs and exceed published estimates of atmospheric deposition by factors of approximately 3–23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean.
    Description: This paper would not have been possible without the financial support of a number of national funding agencies (US NSF OCE-1458305 to M.A.C.; US NSF OCE-0963026 to P.J.L.; Korea NRF-2013R1A1A1058203 to E.Y.K.; U.K. NERC NE/G016267/1 to M.C.L. and A.M.; U.K. NERC NE/K009532/1 to W.B.H.)
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Aquatic geochemistry 6 (2000), S. 385-411 
    ISSN: 1573-1421
    Keywords: hydrogeochemistry ; element ratios ; 87Sr/86 ; Ba/Sr ; weathering ; semi-arid ; Kafue River ; Zambezi River
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Frequent sampling during an annual cycle of dissolved(〈0.45 μm) and suspended (〉0.45 μm) elementshas been conducted in the Kafue River at Raglan'sFarm, upstream from the mining activities within theCopperbelt Province, Zambia. Additional sampling ofsediment and interstitial pore water was conductedduring low water discharge. The presence of carbonateswithin the drainage basin naturally gives rise to highelement concentrations in the dissolved phase(Ca = 626, Mg = 494, Na = 360 and K = 24 mmol l-1).During the rainy season the relative composition ofthe dissolved elements indicated a wash out ofaccumulated weathering products and mineralisedorganic material from the unsaturated zone of the soilprofile. High concentrations of dissolved Al, Fe andMn were measured during high water discharge. At lowwater discharge the sediment was a major source of Fe,Mn and associated Co and Cu to the water column.Enhanced concentrations of dissolved and suspended S,Co and Cu during the rainy season indicated thatatmospheric deposited particles from the mining areawere washed out into the river. Autochthonousformation of particles rich in Si indicated diatomproduction during low water discharge.
    Type of Medium: Electronic Resource
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