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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 510-511 (Mar. 2006), p. 938-941 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: To compare with the human cortical bone, the biomimetic properties ofnano-hydroxyapatite/polyamide 66 composite (n-HA/PA66) were preliminarily studied qualitatively and quantitatively with TEM, XRD in crystal morphology, phase composition and crystal structure. A series of structure parameters such as cell lattice parameters (a and c), mean crystallite size and micro-strain were calculated to characterize quantitatively the microstructure of n-HA/PA66 andhuman cortical bone at the atomic level. The results show that n-HA/PA66 is a good biomimetic biomaterial. But there still are some differences between n-HA/PA66 and human cortical bone. Compared to human cortical bone, the crystal microstructure of n-HA/PA66 is denser, the crystal lattice of n-HA is more perfect and the distortion of crystal lattice decreases
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 510-511 (Mar. 2006), p. 890-893 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Nano-hydroxyapatite (n-HA) slurry was synthesized at normal pressure, and (Cu2+, Zn2+)-bearing nano-hydroxyapatite (Cu-Zn-HA) was prepared by ion exchange reaction in water medium. The properties of n-HA and Cu-Zn-HA were characterized by AAS, TEM, XRD and FTIR. The results of XRD analysis indicate that Cu2+ and Zn2+ can occupy Ca2+ sites and enter the crystal lattice of hydroxyapatite. Through the antibacterial experiments, it was found that Cu-Zn-HA had better antibacterial ability on Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). After heat treatment at 400℃ for an hour, the materials still had good antibacterial effect. The accelerated aging method was employed to test antibacterial durability of the material and the results indicated that the durability was good. The results of the security assessment, including skin stimulation testof rabbit, acute toxicity test by stomach filling and the micronucleus test in bone marrow polychromatic erythrocytes of mice, showed that the security of the material was excellent
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 510-511 (Mar. 2006), p. 894-897 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new method was studied for improving stainless steel antibacterial capability. TheNa2FeO4 coating was prepared on steel surface throughout NaOH treatment, then steel samples were immersed into the solution coantaining Ag+, Zn2+ and TiO2. The antibacterial-ions were fixated firmly on the stainless steel with chemical bond. Scanning electronic microscopy(SEM), X-ray(XRD) and atomic absoption spectroscopy(AAS) were employed to analyze the materials, and the results showed that the antibacterial membrane included silver citrate and silver peroxide. Quinn test was also carried out, in which Staphylococus and E.coli. the results showed that the steel has a bacteriostasis rate of 99.48% to Staphylococus, and 99.09% to E.coli
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 510-511 (Mar. 2006), p. 78-81 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper a series of silver ions-substituted hydroxyapatites (HA) were prepared. The antibacterial activities of these materials on textiles against bacteria have been investigated. Titania (TiO2) was selectively added into the materials to decrease the silver-ions concentration to get the same active antimicrobial effects. The microstructure, the shape and size, concentration of silver, and the groups of the composite materials were characterized using transmission electronmicroscopy (TEM), infrared spectroscopy (IR), Atomic absorption spectroscopy (AAS), and X-ray diffraction (XRD). The results showed that there was a dose dependent-effect of silver-ions concentration from the disk diffusion test. The higher the silver-ions concentration, the better theantibacterial activity of the composite materials was. Keeping silver-ions concentration constant, the antibacterial activity of the materials for adding Titania was better than that of without Titania. Moreover, the addition of Titania would inhibit the discolouration of the composite materials. The antibacterial activities of the composite materials differentiate to some extent with the bacterial strains
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  • 5
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The compatibility efficiency on different compatibilizer for nano-hydroxyapatite(n-HA) reinforced polyamide 66 (PA66) and high density polyethylene (HDPE) blends at a composition of 40/42/18 as functionalized biomaterial was investigated by mechanical properties testing and scanning electron microscopy (SEM). The results showed that mechanical properties of compatibilized blends were much improved by the compatibilizers of maleic anhydride graftedpolyethylene (PE-g-MAH) and ethylene/methacrylic acid ionomer-sodium ion (ION) compared with the uncompatibilized blends. Blends had peak mechanical values of different compatibilizer. Both PE-g and ION formed adhesion during melt mixing and stabilized the morphology and significantly reduced the size of dispersed PE phase. PE-g gave the blends with PE spheres ranging from 1 to 4µm and ION with well-dispersed spheres with an average diameter of 1µm. The moreenlarged interphase of the blends containing ION reduced the lower interfacial energy to increase the miscibiliy of the blends. Consequently, ION had better contribution to rigidity properties than PE-g for n-HA/PA/PE blends
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