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  • 1
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The Witwatersrand Basin has produced nearly 40% of all the world's gold and still contains reserves of -40,000 tonnes (ref. 7). In the late 1970s it also provided the western world with ~20% of its uranium supplies8. Conglomerates (extremely coarse sediments) host particulate gold and uraninite ...
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 66 (1999), S. 83-109 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Vier verschiedene Arten von metamorphen/hydrothermalen Flüssigkeitseinschlüssen wurden im Zuge von detaillierten mikrothermometrischen und spektroskopischen Untersuchungen an Flüssigkeiten in Proben von spätgebildeten Quarzgängen aus dem Gesamtbereich des Witwatersrand-Beckens identifiziert. Bei diesen Flüssigkeiten konnten wässerige, H2O-CO2-reiche, H2O-CH4-CO2-reiche und CH4-N2-reiche Typen unterschieden werden. Bei frühgebildeten Einschlüssen dominieren H2O- und CO2-reiche Flüssigkeiten. Die frühen Einschlüsse kommen entlang verheilter Bruchflächen vor und werden von einer späteren, gasreichen Generation durchkreuzt, die CH4, C2H6, N2, H2, und H2S enthält. Insbesondere Quarzgänge, die an Verwerfungen gebunden sind, enthalten Flüssigkeitseinschlüsse des letzteren Typs. Einige dieser Flüssigkeiten haben die Anwesenheit von Tochterkristallen und hydrokarbonischer Komponenten gemeinsam. Eine sehr späte Generation von wäßrigen Flüssigkeiten kommt in den meisten Proben in der Form von trans-granularen Einschlussbahnen vor. Berücksichtigung von P-V-T-X Bedingungen und Chlorit-Thermometrie, von Mineralparagenesen und Überlagerungsmächtigkeit weisen auf Bildungstemperaturen zwischen 200 und 400 °C, lokal bis zu 500 °C. Die Zusammensetzungen der Flüssigkeiten deuten an, daß die spät-bis post-diagenetischen C-O-H Flüssigkeiten, die auf die Sedimente einwirkten, Sauerstoffugazitäten im Bereich zwischen Q-F-M und Ni-NiO, für Temperaturen von 300 bis 400 °C, hatten. Dies erkärt, warum detritischer Uraninit in weiten Bereichen des Beckens auftritt und warum Remobilisierung von Gold entlang von Zonen hoher Fluidwegsamkeit stattfinden konnte.
    Notes: Summary Four metamorphic/hydrothermal fluid systems were identified in detailed microthermometric and spectroscopic investigations carried out on fluids trapped in late-stage quartz veins sampled throughout the Witwatersrand Basin. These include aqueous, H2O-CO2-rich, H2O-CH4-CO2-rich and CH4-N2-rich fluids. Early inclusion populations are dominated by H2O- and CO2-rich fluid systems. Cross-cutting these early fluid populations are trails of inclusions that contain CH4, C2H6, N2, H2 and H2S (vapour-rich inclusions). Fault-related quartz veins, in particular, are characterized by these later fluid types. A common feature of some of these later fluids is the presence of hydrocarbons and daughter crystals. A very late phase of aqueous fluids occurs in most samples as transgranular inclusion trails. P-V T-X considerations as well as chlorite geothermometry, mineral assemblages and burial conditions suggest entrapment temperatures of between 200°C and 400°C and locally up to 500°C. Fluid chemistry suggests that the post-depositional C-O-H fluids affecting the sediments have oxygen fugacities between Q-F-M and Ni-NiO in the range 300°C to 400°C. This accounts for the widespread preservation of detrital uraninite and gold remobilization along major fluid conduits.
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  • 3
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Hellglimmer von metamorph und hydrothermal überprägtem Basalt, Konglomerat, Quarzit und Pelit aus dem Ventersdorp Contact Reef im Witwatersrand Becken, Südafrika, wurden mittels der K-Ar Methode datiert, um das Alter der postsedimentären thermischen Überprägung einzugrenzen. Mineralkörner wurden in einzelne Fraktionen zwischen 〈 0.4 und 10μm separiert und auf deren Zusammensetzung, Paragenese und Textur mittels Röntgendiffraktometrie und Elektronenmikroskopie untersucht. Das Isochronenalter für alle Hellglimmerproben aus dem Metabasalt liegt bei 1994 ± 60 Ma, jenes für die Glimmer mit einer Korngröße 〈 2μm im Quarzit bei 1917 ± 66 Ma. Diese Altersspanne wird als Ausdruck einer lang anhaltenden hydrothermalen Veränderung des Ventersdorp Contact Reef interpretiert. Das ältere Alter ist etwas jünger als die Intrusion des Bushveld Komplex (2060–2054 Ma) und die Vredefort Katastrophe (2020 Ma) - zwei gut dokumentierte Ereignisse, die das Witwatersrand Becken erfaßten. Das jüngere Alter könnte mit der eburnischen Orogenese entlang des Westrandes des Kaapvaal Kratons in Zusammenhang stehen, während der es zu Fluid Migration und hydrothermaler Aktivität quer über den Kontinent vom Griqualand Becken bis in das Witwatersrand Becken kam. Die neuen K-Ar Alter bestätigen somit, daß die Zeitspanne von 2.0–1.9 Ga wesentlich für die Alteration und möglicherweise auch für die Mobilisierung von Gold im Witwatersrand Becken war.
    Notes: Summary White micas from metamorphosed and hydrothermally-altered basaltic lavas, conglomerates, quartzites and shales in and around the Ventersdorp Contact Reef of the Witwatersrand Basin, South Africa, were dated by the K-Ar method to constrain post-depositional thermal and mineralization processes. The minerals were separated into various grain sizes between 〈 0.4 and 10μm, and characterized in terms of composition, paragenetic sequence and texture, by XRD, SEM and TEM techniques. The K-Ar isochron of all white micas in the basaltic lavas suggests an age of 1994 ± 60 Ma, and that of the smaller mica particles (〈 2μm) in the quartzites defines a younger age of 1917 ± 66 Ma. This range is considered to reflect the timing of long-lived hydrothermal alteration in the Ventersdorp Contact Reef. The older age is slightly younger than the intrusion of the Bushveld Complex (2060–2054 Ma) and the Vredefort catastrophism (2020 Ma), which are well-documented events that were superimposed onto the Witwatersrand Basin. The younger age may be associated with the Eburnian orogenesis along the western edge of the Kaapvaal Craton resulting in continental-scale fluid migration and hydrothermal activity that extended throughout the Griqualand Basin and even into the Witwatersrand Basin. The K-Ar ages obtained here for the white mica fractions of the Ventersdorp Contact Reef in the Witwatersrand Basin confirm that the period between 2.0 and 1.9 Ga was significant, as far as alteration, and possibly also gold mobilization, was concerned.
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  • 4
    Publication Date: 2007-10-08
    Description: The chemical composition of gold within the Archaean metasedimentary rocks of the Witwatersrand Supergroup displays significant heterogeneity at the micro-, meso-and regional scales. A detailed electron microbeam analytical and petrological study of the main auriferous horizons in the Central Rand Group throughout the Witwatersrand Basin indicates that gold has been remobilized late in the paragenetic sequence over distances of less than centimetres. Contemporaneous chlorite formation was strongly rock-buffered. Gold mobilization occurred under fluid-poor conditions at temperatures that did not exceed 350 {degrees}C. Widespread circulation of mineralizing fluids within the Central Rand Group is not supported by the gold and chlorite chemical data. Brittle deformation that affects most of the paragenetic sequence of the Central Rand Group late in its post-depositional history is followed by sequences of mineral growth and dissolution that appear throughout the Central Rand Group and have consistent textural relationships with gold. The consistent location within the paragenetic sequence, the wide regional and stratigraphic extent of the brittle deformation, together with mineral chemical and petrological data suggest that the Vredefort Impact Event (2.02 Ga) was the cause of this late deformation, and that post-impact fluid-poor metamorphism resulted in crystallization of a significant proportion of the gold on and within mineral grains that were deformed during this event.
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  • 5
    Publication Date: 1991-05-01
    Print ISSN: 0022-1376
    Electronic ISSN: 1537-5269
    Topics: Geosciences
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  • 6
    Publication Date: 2015-08-26
    Description: In our complementary geochemical study (Part 1), the Malaysian granitoids of the Southeast Asian tin belt were divided into a Middle Permian to Late Triassic I-type–dominated Eastern province (Indochina terrane) and a Triassic to Early Jurassic transitional I/S-type Main Range province (Sibumasu terrane), separated by the Bentong-Raub suture zone which closed in the Late Triassic. Previous geochronology has relied on only a few U-Pb zircon ages together with K-Ar and whole rock Rb-Sr ages that may not accurately record true magmatic ages. We present 39 new high-precision U-Pb zircon ion microprobe ages from granitoids and volcanics across the Malay Peninsula. Our results show that ages from the Eastern province granitoids span 289–220 Ma, with those from the Main Range province granitoids being entirely Late Triassic, spanning 227–201 Ma. A general westerly younging magmatic trend across the Malay Peninsula is considered to reflect steepening and roll-back of the Bentong-Raub subduction zone during progressive closure of Paleo-Tethys. The youngest ages of subduction-related granites in the Eastern province roughly coincide with the youngest ages of marine sedimentary rocks along the Paleo-Tethyan suture zone. Our petrogenetic and U-Pb zircon age data support models that relate the Eastern province granites to pre-collisional Andean-type magmatism and the western Main Range province granites to syn- and post-collisional crustal melting of Sibumasu crust during the Late Triassic. Tin mineralization was mainly associated with the latter phase of magmatism. Two alternative tectonic models are discussed to explain the Triassic evolution of the Malay Peninsula. The first involves a second Late Triassic to Jurassic or Early Cretaceous east-dipping subduction zone west of Sibumasu where subduction-related hornblende and biotite–bearing granites along Sibumasu are paired with Main Range crustal-melt tin-bearing granites, analogous to the Bolivia Cordilleran tin-bearing granite belt. The second model involves westward underthrusting of Indochina beneath the West Malaya Main Range province, resulting in crustal thickening and formation of tin-bearing granites of the Main Ranges. Cretaceous granitoids are also present locally in Singapore (Ubin diorite), on Tioman Island, in the Noring pluton, of the Stong complex (Eastern Province), and along the Sibumasu terrane in southwest Thailand and Burma (Myanmar), reflecting localized crustal melting.
    Print ISSN: 0016-7606
    Electronic ISSN: 1943-2674
    Topics: Geosciences
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  • 7
    Publication Date: 2015-04-16
    Description: Gold mineralization at the Damang deposit is unique among currently known orogenic gold deposits in Ghana, comprising gold hosted within metasediments of the Tarkwaian System and contained in a subhorizontal, extensional quartz vein array that formed during regional compression. The Damang region has an extended paragenesis involving numerous structural, metamorphic, igneous, and metasomatic events. Orogenic gold mineralization occurred late in the geologic paragenesis at Damang, postdating regional metamorphism and an earlier episode of hydrothermal alteration, locally termed "pink hematite" alteration, associated with the intrusion of mafic sills and dikes. This earlier pink hematite alteration event involves extensive silicification that changed the rheology of the altered rocks and promoted later fracturing. Following peak regional metamorphism at around 2005 Ma, the Damang region underwent a short period of rapid exhumation, as constrained through numerical thermal modeling of existing pressure-temperature-time data. This exhumation triggered the generation of a subhorizontal fracture array that was fed by fluids released through decompression-driven metamorphic devolatilization. The interaction between these fluids and the host rock resulted in precipitation of gold in association with sulfide-carbonate-potassic alteration halos around quartz veins. Such postpeak metamorphic, exhumation-driven, devolatilization is unlikely to be a singular occurrence and represents a potentially important source of fluid for orogenic gold deposits elsewhere in Ghana, West Africa, and globally.
    Print ISSN: 0361-0128
    Topics: Geosciences
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  • 8
    Publication Date: 2015-08-26
    Description: The Malaysian granitoids of the Southeast Asian tin belt have been traditionally divided into a Permian to Late Triassic "I-type"–dominated arc-related Eastern province (Indochina terrane) and a Late Triassic "S-type"–dominated collision-related Main Range province (Sibumasu terrane), separated by the Bentong-Raub Paleo-Tethyan suture that closed in the Late Triassic. The present study, however, shows that this model is oversimplified and that the direct application of Chappell and White’s (1974) I- and S-type classification cannot account for many of the characteristics shared by Malaysian granitoids. Despite being commonly hornblende bearing, as is typical for I-type granites, the roof zones of the Eastern province granites are hornblende free. In addition, the Main Range province granitoids contain insignificant primary muscovite, and are dominated by biotite granites, mineralogically similar to many of the plutons of the Eastern province. In general, the Malaysian granitoids from both provinces are more enriched in high field strength elements than typical Cordilleran I- and S-type granitoids. The mineralogy and geochemistry of the Eastern province granitoids, and their relationship with contemporaneous volcanics, confirm their I-type nature. The bulk liquid lines of descent of both granitic provinces largely overlap with one another. Sr-Nd isotopic data further demonstrate that the Malaysian granitoids, especially those of the Main Range, were hybridized melts derived from two "end-member" source regions, one of which is isotopically similar to the Kontum orthoamphibolites and the other akin to the Kontum paragneisses of the Indochina block. However, there are differences in the source rocks for the two provinces, and it is suggested in this paper that these are related to differing proportions of igneous and sedimentary protoliths. The incorporation of sedimentary-sourced melts in the Eastern province is insignificant, which allowed the granites in this belt to maintain their I-type nature. The presence of minor primary tin mineralization in the Eastern province compared to the much more significant tin endowment in the Main Range is considered to reflect the incorporation of a smaller proportion of sedimentary protolith in the melt products of the former.
    Print ISSN: 0016-7606
    Electronic ISSN: 1943-2674
    Topics: Geosciences
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  • 9
    Publication Date: 2012-07-01
    Description: Three principal granite provinces are defined across SE Asia, as follows. (1) The Western Thailand–Myanmar/Burma province consists of hornblende–biotite I-type granodiorite–granites and felsic biotite–K-feldspar (± garnet ± tourmaline) granites associated with abundant tin mineralization in greisen-type veins. New ion microprobe U–Pb dating results from Phuket Island show zircon core ages of 212 ± 2 and 214 ± 2 Ma and a thermal overprint with rims of 81.2 ± 1.2 and 85–75 Ma. (2) The North Thailand–West Malaya Main Range province has mainly S-type biotite granites and abundant tin mineralization resulting from crustal thickening following collision of the Sibumasu plate with Indochina during the Mid-Triassic. Biotite granites around Kuala Lumpur contain extremely U-rich zircons (up to 38000 ppm) that yield ages of 215 ± 7 and 210 ± 7 Ma. (3) The East Malaya province consists of dominantly Permian–Triassic I-type hornblende–biotite granites but with subordinate S-type plutons and A-type syenite–gabbros. Biotite–K-feldspar granites from Tioman Island off the east coast of Malaysia also yield a zircon age of 80 ± 1 Ma, showing Cretaceous magmatism in common with province 1. Geological and U–Pb geochronological data suggest that two east-dipping (in present-day coordinates) subduction zones are required during the Triassic, one along the Bentong–Raub Palaeo-Tethyan suture, and the other west of the Phuket–Burma province 1 belt.Supplementary material: A full description of U–Pb analytical methods used and data tables are available at www.geolsoc.org.uk/SUP18523.
    Print ISSN: 0016-7649
    Topics: Geosciences
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  • 10
    Publication Date: 2012-12-04
    Description: The Land’s End and Tregonning-Godolphin granites of the 〉250 km-long Permian Cornubian Batholith are heterogeneous medium- to coarse-grained peraluminous biotite-, tourmaline-, and lithium-mica granites traditionally thought to be emplaced as massive magmatic diapirs. Although S-type characteristics are dominant (quartz + biotite + muscovite + tourmaline ± topaz ± lithium-micas in the melt, numerous greisen and pegmatite veins, Sn-W mineralization), some characteristics of evolved I-type granites are also exhibited (hornblende-bearing enclaves, elevated Nd , Cu mineralization, batholithic dimensions). Here, we present an investigation focusing on the contact metamorphism and deformation of the aureole rocks adjacent to the Land’s End and Tregonning granites as an approach to better determine the method of granite emplacement and the depth at which it occurred. New 1:5000-scale geological maps are presented for ~15 km of coastal exposure of the granites and their aureoles. We propose that the granites were emplaced non-diapirically by intrusion of sills that amalgamated to form a sheeted laccolith-type body. Granite contacts cleanly truncate all faults, folds, and cleavages generated during both Variscan convergence and subsequent latest Carboniferous–Early Permian (end-Variscan) extension, and it is likely that granite was emplaced during continuation of this extensional episode. There is evidence for stoping of the country rocks by an outward-migrated sill and dyke network, and uplift and doming of the host rocks can be partially attributed to laccolith inflation. Host meta-siltstones of the Devonian Mylor Slate Formation formed a contact aureole of cordierite + biotite + chlorite ± andalusite "spotted slates." Several interspersed pillow basalts and dolerites, previously affected by hydrothermal alteration, underwent isochemical contact metamorphism to form cordierite- and orthoamphibole-bearing hornfels, including cordierite-anthophyllite rocks that are present in Kenidjack cliff, NW Land’s End aureole. THERMOCALC P-T modeling and pseudosection construction for these rocks in the large Na 2 O-CaO-K 2 O-FeO-MgO-Al 2 O 3 -SiO 2 -H 2 O-TiO 2 -Fe 2 O 3 (NCKFMASHTO) chemical system indicates contact metamorphism occurred at 1.5 ± 1.0 kbar and 615 ± 50 °C. This ultra-low pressure metamorphism equates to a likely emplacement depth of 5–6 km for the adjacent granite sheets. The Cornubian Batholith is highly composite and likely comprises an amalgamation of discrete shallow-seated sheeted laccoliths that are dyke-fed from a common lower-crustal/upper-mantle melt region to result in the batholith’s mixed S-type/I-type character.
    Electronic ISSN: 1553-040X
    Topics: Geosciences
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