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  • 1
    Publication Date: 2022-10-07
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Pasquier, B., Hines, S. K., Liang, H., Wu, Y., Goldstein, S. L., & John, S. G. GNOM v1.0: an optimized steady-state model of the modern marine neodymium cycle. Geoscientific Model Development, 15(11), (2022): 4625–4656. https://doi.org/10.5194/gmd-15-4625-2022.
    Description: Spatially distant sources of neodymium (Nd) to the ocean that carry different isotopic signatures (εNd) have been shown to trace out major water masses and have thus been extensively used to study large-scale features of the ocean circulation both past and current. While the global marine Nd cycle is qualitatively well understood, a complete quantitative determination of all its components and mechanisms, such as the magnitude of its sources and the paradoxical conservative behavior of εNd, remains elusive. To make sense of the increasing collection of observational Nd and εNd data, in this model description paper we present and describe the Global Neodymium Ocean Model (GNOM) v1.0, the first inverse model of the global marine biogeochemical cycle of Nd. The GNOM is embedded in a data-constrained steady-state circulation that affords spectacular computational efficiency, which we leverage to perform systematic objective optimization, allowing us to make preliminary estimates of biogeochemical parameters. Owing to its matrix representation, the GNOM model is additionally amenable to novel diagnostics that allow us to investigate open questions about the Nd cycle with unprecedented accuracy. This model is open-source and freely accessible, is written in Julia, and its code is easily understandable and modifiable for further community developments, refinements, and experiments.
    Description: This work has been supported by the Simons Foundation (grant no. 426570SP to Seth G. John), the National Science Foundation (grant no. OCE-1736896 to Seth G. John and grant no. OCE-1831415 to Steven L. Goldstein and Sophia K. V. Hines), the Investment in Science Fund at WHOI and the John E. and Anne W. Sawyer Endowed Fund in Support of Scientific Staff (Sophia K. V. Hines), and the Storke Endowment of the Department of Earth and Environmental Sciences, Columbia University (Steven L. Goldstein).
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2018-08-15
    Description: One of the key activities during the initial phase of the international GEOTRACES program was an extensive international intercalibration effort, to ensure that results for a range of trace elements and isotopes (TEIs) from different cruises and from different laboratories can be compared in a meaningful way. Here we present the results from the intercalibration efforts on neodymium isotopes and rare earth elements in seawater and marine particles. Fifteen different laboratories reported results for dissolved 143Nd/144Nd ratios in seawater at three different locations (BATS 15 m, BATS 2000 m, SAFe 3000 m), with an overall agreement within 47 to 57 ppm (2σ standard deviation of the mean). A similar agreement was found for analyses of an unknown pure Nd standard solution carried out by 13 laboratories (56 ppm), indicating that mass spectrometry is the main variable in achieving accurate and precise Nd isotope ratios. Overall, this result is very satisfactory, as the achieved precision is a factor of 40 better than the range of Nd isotopic compositions observed in the global ocean. Intercalibration for dissolved rare earth element concentrations (REEs) by six laboratories for two water depths at BATS yielded a reproducibility of 15% or better for all REE except Ce, which seems to be the most blank-sensitive REE. Neodymium concentrations from 12 laboratories show an agreement within 9%, reflecting the best currently possible reproducibility. Results for Nd isotopic compositions and REE concentrations on marine particles are inconclusive, and should be revisited in the future.
    Type: Article , PeerReviewed
    Format: text
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