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  • 1
    Publication Date: 2016-07-02
    Description: We report our ultrafast photoinduced desorption investigation of the coverage dependence of substrate–adsorbate energy transfer in carbon monoxide adlayers on the (111) surface of palladium. As the CO coverage is increased, the adsorption site population shifts from all threefold hollows (up to 0.33 ML), to bridge and near bridge (〉0.5 to 0.6 ML) and finally to mixed threefold hollow plus top site (at saturation at 0.75 ML). We show that between 0.24 and 0.75 ML this progression of binding site motifs is accompanied by two remarkable features in the ultrafast photoinduced desorption of the adsorbates: (i) the desorption probability increases roughly two orders magnitude, and (ii) the adsorbate–substrate energy transfer rate observed in two-pulse correlation experiments varies nonmonotonically, having a minimum at intermediate coverages. Simulations using a phenomenological model to describe the adsorbate–substrate energy transfer in terms of frictional coupling indicate that these features are consistent with an adsorption-site dependent electron-mediated energy coupling strength, η el , that decreases with binding site in the order: three-fold hollow 〉 bridge and near bridge 〉 top site. This weakening of η el largely counterbalances the decrease in the desorption activation energy that accompanies this progression of adsorption site motifs, moderating what would otherwise be a rise of several orders of magnitude in the desorption probability. Within this framework, the observed energy transfer rate enhancement at saturation coverage is due to interadsorbate energy transfer from the copopulation of molecules bound in three-fold hollows to their top-site neighbors.
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 2
    Publication Date: 2015-01-22
    Description: The morphology and electronic structure of vapor deposited 4,4′-biphenyldiisocyanide (BPDI) on a Au(111) surface were investigated using variable-temperature scanning tunneling microscopy. When deposited at room temperature, BPDI molecules form one-dimensional molecular chains similar to that recently observed for the structurally related 1,4-phenyl diisocyanide (PDI). Compared to PDI, the longer periodicity for the BPDI molecular chains is consistent with the addition of a second phenyl ring and supports a structural model in which the BPDI molecules lie parallel to the surface and interconnected by Au-adatoms. The molecular chains are mostly aligned along the 1 1 ̄ 0 direction of the Au(111) substrate, but exhibit frequent changes in angle that are consistent with directions between fcc and hcp three-fold hollow sites. Dispersion-corrected density functional theory calculations for one-dimensional chains of BPDI molecules bound end-to-end via their isocyanide groups to Au-adatoms reproduce the observed periodicity of the chains and show that this morphology is energetically favored over upright binding with one free —NC group. The spatially resolved conductance (dI/dV) map for BPDI on Au(111) exhibits a feature centered at −0.67 eV below the Fermi level which are delocalized along the chain with maxima at the Au-adatom and biphenyl positions. This occupied resonant feature is close to that previously observed for the PDI in both photoemission and conductance measurements and is attributed to an occupied interfacial state resulting from BPDI-Au interactions.
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 3317-3321 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The stresses present in palladium- and nickel-silicide thin films during deposition and subsequent annealing processes have been monitored using the absorption-edge–contour mapping technique employing synchrotron radiation. A miniature fabrication chamber has been constructed for this purpose. The magnitude and the sense of the film stresses vary with the deposition condition and the annealing process. Film relaxation occurs during annealing so that a state of no stress can be reached at annealing temperature. The origins of fllm stresses as well as the changes of stress magnitudes are discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 31 (1990), S. 1356-1373 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: A famous theorem by Poincaré and Bertrand formally describes how to interchange the order of integration in a double integral involving two principal-value factors. This theorem has important applications in many-body physics, particularly in the evaluation of response functions (or "loop integrals'') at either zero or finite temperatures. Of special interest is the loop containing an integration with respect to the energy of two causal propagators. It is shown that such a response function with two boson or two fermion lines behaves statistically like a boson, while the response function containing a boson and a fermion behaves like a fermion. Examples are given of typical loop integrals occurring in the solution of Dyson's equations for nuclear matter in the presence of delta, nucleon, and pion interactions. A "form factor'' that is essential for the convergence of the nucleon–pion loop integral is chosen to have little effect on the analogous nucleon–delta loop integral. The Poincaré–Bertrand (PB) theorem is then generalized to multiple integrals and higher-order poles. From the generalization of the theorem to triple integrals, it is shown that causality is rigorously maintained, at zero temperature, for convolutions with respect to the time of products of Green's functions and thus for Dyson's equations. Also, for finite temperature, the three-propagator loop integral satisfies the statistics appropriate for the loop as a whole, in direct analogy with the result for the two-propagator loop. The intimate connection between the PB theorem and analyticity (or causality) is clearly demonstrated. Although this work considers explicitly only nuclear physics examples, the results are relevant to other fields where many-body theory is used.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 32 (1991), S. 1651-1651 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 6801-6807 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A Nb hot-electron bolometer designed for operation as a sensor of millimeter waves and far-infrared radiation has been analyzed. This optically coupled detector has a very wide spectral bandwidth, a response speed of ∼1 ns determined by electron-phonon scattering, and an impedance of 50 Ω. The geometry employed here has traditionally been affected by stability problems manifesting as random voltage fluctuations, which have hindered the usefulness of these bolometers. This issue has been addressed by exploring the underlying physical causes and adapting the fabrication technique. Analytical results on substrate-induced bolometric effects are summarized and other factors concerning detector performance addressed, and the reality of an isothermal regime of operation is questioned. A noise equivalent power of 4 pW/Hz1/2 was measured at 100 μm, with a coupling efficiency close to unity that was achieved by reducing the optical reflection losses. Operation of a similar device is shown able to resolve the macropulses of FELIX, the Free-Electron Laser for Infrared eXperiments, into its 40 ns spaced micropulses. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 3156-3166 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: An inexpensive alternative to commercial high-power microwave pulse generators is described. The present high-power microwave pulse generator utilizes a surplus MIT model 3 Mark II hard tube modulator and 2J51 magnetron. The basic design and technical details of the pulse generator are presented. The pulse generator is designed to produce 8.5–9.6 GHz pulses with pulse lengths ranging from 2 to 4 μs, with a nominal power output of 20 kW and a maximum duty cycle of 0.001.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 3656-3661 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this article we present results and analysis from measurements of the field distributions from standard magnetic force microscope tips. These measurements are made using Lorentz microscopy and tomographic reconstruction techniques with the field reconstructed in a plane situated about 50 nm from the end of the magnetic force microscope (MFM) tip; this corresponds approximately to the sample plane in the MFM. By examination of the experimental results and comparison with simulated field distributions from point and extended charge distributions, we conclude that the magnetization configuration of the tip is best represented by an extended charge distribution and that the point pole approximation represents only, at best, the central part of the field distribution. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 620-623 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Several improvements for a previously described semiautomated system for spin-wave instability threshold measurement in microwave ferrites are described. The effects of sample size, sample position in the microwave cavity, and method of data interpretation on the threshold field hcrit are also reported. The data were obtained by the parallel pumping technique at 8.92 GHz. Sphere-shaped samples of polycrystalline yttrium iron garnet were used for the measurements. The results show that the initial, "exact'' instability onset, the "extrapolated'' onset from the loss increase above threshold, and the "visual'' onset estimate from the above threshold response can vary by more than 0.5 Oe for hcrit values of 3 Oe or so. Large samples, above 1 mm in diameter, lead to an overestimation of hcrit due to errors in the microwave cavity perturbation theory analysis which forms the basis of the measurement. The amount of overestimation is about 0.1 Oe for a diameter of 2 mm and 0.2 Oe at 3 mm. Sample position relative to the cavity end wall does not appear to be critical. Imaging effects are small for hcrit measurements in the YIG-like materials of interest here.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 3689-3692 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The growth of the Pd2Si thin fllms on Si(111) substrates has been monitored by an in situ x-ray diffraction technique in vacuum and in helium atmosphere from 160 to 250 °C. A familiar parabolic growth rate was found, confirming the diffusion-controlled film growth process. The activation energies were found to be 1.34 and 1.37 eV for the measurements performed in vacuum and helium environment, respectively. Stress relaxation in the growing Pd2Si fllm was observed when the reaction temperature exceeds 200 °C. The relaxed films showed a higher degree of texture as evidenced by the rocking curve measurements.
    Type of Medium: Electronic Resource
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