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  • Chemistry  (49)
  • Mixing  (4)
  • 78.50G  (2)
  • Wiley-Blackwell  (49)
  • American Geophysical Union  (4)
  • Springer  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 54 (1992), S. 19-21 
    ISSN: 1432-0630
    Keywords: 61.12Dw ; 72.10 ; 78.50G
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The formation of silicon oxide precipitates from Czochralski grown silicon depends on the time and temperature of the heat treatment as well as on the initial content of interstitially dissolved oxygen. Samples containing between 5×1017 Oi/cm3 and 13×1017 Oi/cm3 have been heated at 750° C for 96 h. SiO2 precipitates of various shape and size have been obtained and investigated by means of small angle neutron scattering (SANS) in the Q-range 0.05 Å−1〈Q〈0.2 Å−1. The obtained SANS patterns reveal a typical anisotropy of their intensity distribution, which splits into a central peak at Q〈0.1 Å−1 due to the shape of the individual particles and a number of weak intensities for large Q-values, originating from a correlation between defects, possibly between the precipitates. While these correlation peaks in the SANS patterns are seen best for rather low values of about (5–7)×1017 Oi/cm3 oxygen content, the central peak anisotropy is most pronounced for higher values of ca 10×1017 Oi/cm3. The integrated intensity of the central peak increases with increasing initial oxygen content. For comparison, untreated samples of the same initial oxygen content do not reveal any anisotropic SAN scattering or a broadened central peak beam.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 61.12Dw ; 72.10 ; 78.50G
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Czochralski grown silicon crystals contain interstitially dissolved oxygen which diffuses on heating to form precipitates of silica. We have examined these precipitates by small angle neutron scattering (SANS) in the Q-range 0.05 Å−1〈Q〈0.4 Å−1. The obtained SANS patterns reveal pronounced anisotropic intensity distributions which resemble the symmetry of the host crystal. The SANS spectra show an anisotropic central peak at Q〈0.1 Å−1 due to the single particle shape and a number of weak intensities for larger Q-values. These weak side maxima are considered correlation peaks or quasi-elastic interference peaks. They show, however, an unexpected and distinct temperature dependence: with decreasing temperature below values of 220 K their intensity is lost slowly, but reversibly. At T = 50 K only the central peak from the single-particle scattering remains unchanged. Upon heating, the correlation peaks regain their former value of intensity and Q-position without any evidence of thermal hysteresis.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 98 (1965), S. 1233-1245 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Elektrophile Substituenten mit Carbonylgruppen erhöhen struktur- und stellungsabhängig das Redoxpotential von o-Benzochinonen so stark, daß sie aus entsprechend substituierten Brenzcatechinen mit Tetrachlor-o-chinon präparativ nicht mehr zugänglich sind (Tab. 1). Führt man in diese Verbindungen Methoxylgruppen ein, so werden die Redoxpotentiale so weit gesenkt, daß aus den Brenzcatechinen mit Tetrachlor-o-chinon die zugehörigen o-Chinone entstehen.  -  Im Blick auf das Lignin- und Melaninproblem wurden o-Chinone der Kaffeesäure und substituierter Kaffeesäuren untersucht (Tab. 3) und 4.5-Dihydroxy-1-methoxycarbonyl-inden (XX) dargestellt.  -  Ist die Carbonylgruppe oder C=C-Doppelbindung Bestandteil eines planar angegliederten Ringes (vgl. I und II bzw. XX), so liegt das Redoxpotential unter demjenigen des o-Benzochinons; die Art dieser elektronischen Wechselwirkungen ist noch unbekannt.
    Additional Material: 3 Tab.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 98 (1965), S. 2009-2015 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden Angaben zur Arbeitsweise und Meßgenauigkeit gemacht. Die ermittelten Halbstufenpotentiale werden auf Standardbedingungen bezogen und entsprechen den Redoxstandardpotentialen mit guter Näherung. Die Konzentration der Brenzcatechinderivate und das Lösungsmittel beeinflussen die Halbstufenpotentiale.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 98 (1965), S. 2016-2045 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die polarographisch ermittelten Standard-Redoxpotentiale von 121 Brenzcatechin-Derivaten, darunter 28 substituierten-1′.2′-Dihydroxy-6.7-benzo-tropolonen, werden mitgeteilt. Dem Substituenteneinfluß auf das Redoxpotential entsprechen Inkremente, die sich bei mehrfacher Substitution annähernd additiv verhalten. Die Redoxpotentiale werden diskutiert.
    Additional Material: 12 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 2271-2275 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus D-Gluconsäure-δ -lacton wurden mit aliphatischen Diaminen die Mono- und Diacylverbindungen erhalten und durch Derivate charakterisiert.  -  Eine Imidazolinbildung tritt unter den angewandten milden Reaktionsbedingungen nicht ein.
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  • 7
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymethoxy-acetophenone werden in Polyphosphorsäure ent- bzw. umacetyliert; die Entacetylierung folgt der 1. Ordnung. Aus 1.2.4.5-Tetramethoxy-benzol (1a) entsteht mit Eisessig/Polyphosphorsäure 2.4.5-Trimethoxy-acetophenon (2a).
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 28 (1945), S. 576-582 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 18 (1976), S. 1497-1506 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A chemostat in which mammalian cells can be raised in continuous suspension culture is described. It is constructed from commercially available parts. This apparatus has the advantage over earlier models in that the medium can be pumped off free of cells, thus suddenly increasing the cell concentration in the culture. The apparatus has been successfully used in studies on contact inhibition.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 9 (1986), S. 308-309 
    ISSN: 0935-6304
    Keywords: High performance liquid chromatography, HPLC ; Reverse phase ; Internal standard ; Trimellitic anhydride ; Air sample ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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