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  • Chemical Engineering  (490)
  • Wiley-Blackwell  (489)
  • American Association for the Advancement of Science (AAAS)  (1)
  • American Institute of Physics
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  • Wiley-Blackwell  (489)
  • American Association for the Advancement of Science (AAAS)  (1)
  • American Institute of Physics
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1976-1982 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A 200-s PSA cycle involving both pressure equalization and product backfill steps has been experimentally studied on a four-bed system, where LINDE 5 A zeolites were used as the adsorbent to separate oxygen from air. This cycle is operated under a pressure ratio of 4.3. During the experiment, the pressure history and flow rates, as well as the concentration of the product stream have been continuously monitored. This is the first time detailed experimental data on a four-bed system are presented. Under favorable conditions, this system produces better than 90% oxygen at a recovery of 17%. For the low-pressure ratio, such a recovery could not have been achieved without the pressure equalization step and the reduced purge operation. Recovery and throughput, however, are not as high as one would expect from a linear local equilibrium model. The self-broadening effect of the purge wave has been identified as the major cause of underperformance.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 1569-1576 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical analysis for the pulse responses of a liquid chromatographic column packed with crystal powders having a particle size distribution and a nonlinear adsorption isotherm is presented. The mathematical model is solved numerically by the orthogonal collocation method. Based on the parametric analysis of the model, the effects of a symmetrical and moderately asymmetric PSD on the LC responses are shown to be negligible in comparison with the effects of other parameters, such as isotherm nonlinearity, whose effects are much more profound. The simulated responses are compared with the experimental response data for an LC column packed with silicalite crystals, and a good agreement is found between the theoretical and experimental results. Using the nonlinear LC model, the simultaneous determination of nonlinear adsorption isotherms and intraparticle diffusivities from LC pulse responses is demonstrated for liquids in porous adsorbents.
    Additional Material: 6 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1572-1574 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 272-280 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of simultaneous, noncatalytic solid-gas reaction systems has been analyzed in terms of the selectivity and effectiveness factor, based on the unreacted core shrinking model. The reaction systems discussed include the first-order independent, parallel, and consecutive reactions with the simultaneous influences of heat and mass transfer. The effects of various chemical and transport properties on the stability, selectivity, and effectiveness factor of the system are discussed. The pseudosteady state approximation is employed to reduce the mathematical difficulties.
    Additional Material: 8 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 526-528 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 610-612 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 848-856 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Solid-fluid reactions often involve two or more simultaneous reactions because either the feed contains multiple fluid reactants or the fluid products are reactive with the solid. Three types of simultaneous reactions, independent, parallel, and consecutive, are examined in terms of the selectivity and the effectiveness factor based on the unreacted core shrinking model under isothermal conditions. Criteria for high selectivities are derived, and effects of diffusion and chemical reaction are discussed.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 741-746 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Hydrodynamic characteristics of an in vitro membrane permeation system for controlled drug delivery studies were investigated by measuring dissolution rates of benzoic acid in various aqueous solutions of polyethylene glycol 400. The mass transfer coefficient was well correlated in terms of three dimensionless numbers: Sherwood, Schmidt, and Reynolds numbers. By using the correlation equation, the intrinsic permeation rate of testosterone through silicone membranes was precisely extracted from the experimental data obtained under various nonideal flow conditions.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 279-284 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient sorption rates of allene and methylacetylene in synthetic faujasite (Linde 13X) powder and self-bonded pellets are studied in a constant-volume, constant-pressure system at three temperatures. The intracrystalline diffusion coefficients are found to be in the order of 10-11 cm2/s and the activation energy for diffusion is 4.0 kcal/g-mole.A simple bipore distribution model for transient diffusion in macropores and micropores is presented. It agrees well with the experimental data and quantitatively predicts the macropore diffusion coefficients. The flow in the macropores is found to be in the Knudsen flow regime.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 147-152 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient diffusion of n-butane, iso-butane, and 1-butene in synthetic CaX(Na) spherical pellets is studied in a constant volume, well-stirred system. The intracrystalline diffusion coefficients are in the order of 10-14 cm2/s, and the activation energy is about 7.0 Kcal/g-mole. Experimental data agree well with a mathematical model developed to describe transient diffusion.
    Additional Material: 8 Ill.
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