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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 184 (1983), S. 733-735 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Five new copolyesters 3a - e were prepared by reacting β-(4-methoxy-3 methyl)phenylglutaconic acid dichloride (1 b) with diols 2 a - e. The polymers were characterized by IR and TG. All polymers were found to decompose in the range of ≈200 to ≈650°C.
    Additional Material: 3 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 2239-2247 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The cation-exchange resins based on α-pinene and furfural were characterized systematically as to their polyfunctionality, rate of exchange and thermal stability. Equilibrium studies for univalent and bivalent ions were also conducted.
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 2229-2237 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A crosslinked polymer based on α-pinene and furfural suitable for processing into ion exchangers was prepared. The polymer has been processed chemically into different types of cation exchange resins. The role of various parameters such as catalyst concentration, proportion of crosslinking agent, etc., for preparing the polymer is systematically studied and presented. Similarly, the conditions for preparing the various cation exchange resins (sulfonic, phosphonic, and hydroxy phosphonic acid type from the polymer) are also described. A probable/possible composition for the repeating unit in the basic polymer is proposed and supported by experimental evidences.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Pfropf-Copolymerisation von Vinylacetat (VAC) und Methylacrylat (MA) auf Himachali-Wolle wurde bei 40, 45, 50 und 60°C in wäßrigem Medium mit einem KPS-FAS-System als Redoxinitiator untersucht. Eine maximale Pfropfung wurde mit VAC und mit MA bei 60°C erhalten. Ein Einfluß der Art des Vinylmonomeren auf die Pfropfung wurde untersucht. Die Pfropfausbeute wurde bestimmt als Funktion (a) der Monomerkonzentration, (b) des molaren Verhältnisses von FAS : KPS, (c) der Reaktionszeit und (d) der Temperatur. Die maximale Pfropfung wurde mit VAC und mit MA bei einem molaren Verhältnis von FAS : KPS = 0, 713 : 1 gefunden. Reaktionsgeschwindigkeit (Rp) und Induktionszeit (Ip) wurden als Funktion der gesamten anfänglichen Monomerkonzentration bestimmt. Es wurde gefunden, daß MA, ein Akzeptormonomeres, mehrfach reaktiver ist als VAC, ein Donormonomeres.
    Notes: Graft copolymerization of vinyl acetate (VAC) and methyl acrylate (MA) onto Himachali wool was studied at 40, 45, 50, and 60°C in aqueous medium by using (KPS-FAS) system as redox initiator. The maximum grafting of both VAC and MA occurred at 60°C. The nature of vinyl monomer was found to influence grafting. The percentage of grafting was determined as functions of (a) concentration of monomer, (b) molar ratio of FAS/KPS, (c) reaction time and (d) temperature. Maximum grafting of both VAC and MA occurred at a molar ratio of FAS:KPS = 0.713 : 1. The rate of grafting (Rp) and the induction period (Ip) of VAC and MA were determined as a function of total initial monomer concentration. MA, an acceptor monomer was found to be several times more reactive than VAC, a donor monomer.
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 1-14 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Kinetics of radiation-induced grafting of acrylamide (Aam) and acrylic acid (Aa) to nylon 6 fabric were investigated employing a mutual radiation technique. Copper sulfate was used as the radical scavenger to reduce homopolymer formation. Formic acid was used for swelling, and its effect on grafting was studied. Maximum amount of grafting was doubled when formic acid was used for swelling nylon prior to, but not during, irradiation. The rate of grafting was not significantly affected if it was carried out in an atmosphere of air instead of nitrogen. The effect of monomer concentration, dose rate, and total dose on grafting has been studied. Rate of grafting was significantly higher when lower dose rates and monomer concentrations were used. Saturation grafting was proportional to monomer concentration up to 2.1M. Initial rate of grafting was proportional to monomer concentration. The rate of grafting of Aam was proportional to the dose rate to the power 0.25-1.0. A synergestic effect was noticed during grafting with mixtures of Aam and Aa (80:20; 20:80). Grafted fabrics showed considerable increase in moisture regain. Dyeability and tensile properties of the grafted fabrics were not significantly affected by grafting. Aa-grafted fabrics did not melt up to 320°C, whereas untreated nylon melts at 215°C.
    Additional Material: 8 Ill.
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  • 6
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The processes of sorption and diffusion of water in anisotropic glass ribbon-reinforced composite films of controlled structural and physical characteristics were investigated in terms of the film properties, e.g., geometry, orientation, and volume fraction of the filler; molding characteristics of the composite film; and the adhesion between the glass ribbon and continuous cellulose acetate matrix. While the diffusion of water through unfilled cellulose acetate film was found to be a simple activated process with very little concentration dependence, the diffusion behavior of glass ribbon-reinforced cellulose acetate was found to be anomalous and concentration dependent.
    Additional Material: 11 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 3559-3577 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ultrafiltration membranes were prepared from cellulose nitrate under different conditions and were characterized using a solution of 1.0% dextran-150 having a salinity of 1500 ppm. The role of various parameters such as polymer concentration, ratio of ether to alcohol, methanol as the solvent, and other additives is systematically studied and presented. Similarly, the effect of operational and hydraulic parameters on the membrane performance is evaluated and the minimum activation energy for the solvent permeability is experimentally deduced.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 235-241 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In an attempt to compare relative reactivities of vinyl monomers toward grafting, methyl methacrylate (MMA) and acrylic acid (AAc) were grafted separately to Himachali wool in aqueous medium by using ceric ammonium nitrate (CAN) as redox initiator. Nitric acid was found to catalyze the reaction. Percent grafting was determined as a function of concentration of nitric acid, concentration of CAN, concentration of monomer, time, and temperature. Optimum conditions for maximum grafting were evaluated for each monomer and were found to depend upon the nature of the monomer. Reactivities of MMA and AAc toward grafting were compared with those of methyl acrylate (MA), ethyl acrylate (EA), and vinyl acetate (VAc) reported earlier from this laboratory and were found to follow the order MA 〉 EA 〉 MMA 〉 VAc 〉 AAc. An explanation for the observed order of reactivity of different vinyl monomers is presented.
    Additional Material: 1 Ill.
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  • 9
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In an attempt to ascertain the role of - SH groups of Himachali wool during graft copolymerization, poly(viny acetate) (PVAc) and poly(methyl acrylate) (PMA) were graft copolymerized onto reduced wool by using potassium persulfate - ferrous ammonium sulfate (KPS - FAS) redox pair in aqueous medium. Reduction of wool was carried out by sodium bisulfite solution of varying concentrations for different reaction periods. Concentration of reducing agent and the extent of reduction were found to influence grafting of vinyl monomers. Maximum grafting of methyl acrylate (MA) and vinyl acetate (VAc) occurred when wool was reduced by 1% and 0.5% NaHSO3 solution, respectively, for 24 h. Increase in percent grafting of MA onto reduced wool compared to that of unreduced wool has been ascribed to the production of more - SH groups by reduction of - SS - groups of wool fiber.
    Additional Material: 4 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 16 (1978), S. 289-296 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The equilibrium melting temperature, volume, and enthalpy and entropy changes on melting of poly(ethylene terephthalate) have been analyzed and heats of fusion have been newly measured with an automated scanning calorimeter to yield the following data: 553°K, 16.9 cm3/mole, 2.69 kJ/mole, and 48.6 J/deg/mole, respectively. A more detailed discussion of annealed samples obtained from etched starting materials shows that the density of the noncrystalline regions may be variable.
    Additional Material: 5 Ill.
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