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  • Lepidoptera  (86)
  • Coleoptera  (64)
  • oxidation  (37)
  • Springer  (185)
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  • 1985-1989  (107)
  • 1980-1984  (57)
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  • 1
    ISSN: 1573-1561
    Keywords: Spotted bollworm ; Earias vittella ; spiny bollworm ; Earias insulana ; Lepidoptera ; Noctuidae ; gas chromatography ; electroantennography ; pheromone traps ; hexadecanal ; (Z)-11-hexadecenal ; (E,E)-10,12-hexadecadienal ; (Z,E)-10,12-hexadecadienal ; (E,Z)-10,12-hexadecadienal ; octadecanal ; (Z)-11-octadecenal ; (E,E)-10,12-hexadecadien-1-ol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Ovipositor washings from virgin femaleEarias vittella (F.) (Lepidoptera: Noctuidae) moths were examined by gas chromatography (GC) linked to electroantennography (EAG). Six components were detected by the male moth. These were identified by comparison of their retention times with those of a range of synthetic standards on fused silica capillary GC columns as hexadecanal, (Z)-11-hexadecenal, (E,E)-10,12-hexadecadienal, octadecanal, (Z)-11-octadecenal, and (E,E)-10,12-hexadecadien-1-ol in 1∶2∶10∶2∶4∶1 ratio. Field testing in Pakistan showed that a 2∶10∶2 mixture of (Z)-11-hexadecenal, (E,E)-10,12-hexadecadienal, and (Z)-11-octadecenal was as attractive to maleE. vittella moths as the six-component mixture and equal in attractiveness to a virgin female moth. Omitting (Z)-11-hexadecenal or (Z)-11-octadecenal greatly reduced this attractiveness. It was found that synthetic lures must be protected from sunlight to prevent loss of attractiveness caused by isomerization of the conjugated diene aldehyde, and addition of (E,Z)-10,12-hexadecadienal, one of the products of isomerization, was shown to reduce attractiveness significantly. During this work, a 10∶1 mixture of (E,E)-10, 12-hexadecadienal and (Z)-11-hexadecenal was shown to be as attractive toE. insulana (Boisd.) male moths as a virgin female moth, and the attractiveness of this mixture was further increased by addition of (E,Z)-10,12-hexadecadienal.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical ecology 12 (1986), S. 647-658 
    ISSN: 1573-1561
    Keywords: Perennial ryegrass ; Lolium perenne ; Gramineae ; Argentine stem weevil ; Listronotus bonariensis ; Coleoptera ; Curculionidae ; Acremonium loliae ; Acremonium coenophialum ; endophyte ; bioassay ; induced resistance ; feeding deterrent ; peramine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Infection of ryegrass (Lolium perenne) by an endophytic fungus (Acremonium loliae) confers resistance against the Argentine stem weevil (Listronotus bonariensis). Extracts from ryegrass clones, infected and uninfected withA. loliae, were compared in a feeding choice bioassay, and several fractions were identified which affected stem weevil feeding behavior. One stem weevil feeding deterrent, peramine C12H17N5O, has been isolated from infected ryegrass and partially characterized as a basic indole derivative. Extracts from culturedA. loliae had no effect on stem weevil feeding behavior nor was peramine detected in the fungal cultures examined. Peramine and the other active substances are hydrophilic in contrast to the lipophilic properties reported for the neurotoxic lolitrems also isolated from ryegrass infected withA. loliae and associated with causing ryegrass staggers disorder in livestock. It is suggested that ryegrass staggers and stem weevil feeding deterrency may arise by different biochemical mechanisms.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Entomologia experimentalis et applicata 30 (1981), S. 151-156 
    ISSN: 1570-7458
    Keywords: Xyleborus ferrugineus ; pupae ; ecdysteroids ; pharate adult ; radioimmunoassay ; Coleoptera ; Scolytidae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Description / Table of Contents: Zusammenfassung Der Ecdysteroidtiter weiblicher Puppen von Xyleborus ferrugineus (Fabr.) wurde geschätzt, indem ganze Tiere homogenisiert und radioimmunologisch untersucht wurden. Ein ausgeprägtes Maximum an Ecdysteroiden wurde bei 36 Stunden Puppenent-wicklung beobachtet (743 pg/mg Körpergewicht). Der Titer nahm ab auf 299 pg/mg im Pharatstadium und auf 193 pg/mg unmittelbar vor Schlüpfen der Adulten. Qualitative Studien mit HPLC ergaben in frischen Puppen ein Verhältnis von 3:1 Ecdyson zu 20-Hydrooxyecdyson. Pharatstadien enthielten vor allem 20-Hydrooxyecdyson. Das beobachtete einzige Maximum im Titer stimmt überein mit den Resultaten bei andern untersuchten Coleopteren.
    Notes: Abstract Ecdysteroid titers were estimated on the whole body homogenates of Xyleborus ferrugineus (Fabr.) female pupae during development by radioimmunoassay. A distinct peak of ecdysteroids was observed at 36-hr pupal development (743 pg/mg body wt). Titer declined to 299 pg/mg by the pharate adult stage and to 193 pg/mg body wt just before adult emergence. Qualitative studies by HPLC revealed a ratio of 3:1 ecdysone to 20-hydroxyecdysone in the initial pupal stage. Pharate adults had mainly 20-hydroxyecdysone. The observed single peak in ecdysteroid titer agrees with findings in other studied coleopteran species.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Entomologia experimentalis et applicata 30 (1981), S. 123-127 
    ISSN: 1570-7458
    Keywords: Sex Pheromones ; Repellent ; Heliothis armigera ; Heliothis zea ; Lepidoptera ; Noctuidae ; cotton bollworm ; corn earworm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Description / Table of Contents: Résumé L'examen en olfactomètre a porté sur les réactions face à d'autres femelles de la même espèce, de femelles vierges ou ayant copulé d'Heliothis armigera Hübner et H. zea Boddie. Le lot comprenait 8 femelles, vierges ou ayant copulé en présence d'une femelle vierge ou ayant copulé. Les 4 combinaisons possibles de femelles vierges et de femelles ayant copulé ont été examinées avec 12 répétitions pour chaque espèce. Un extrait de l'extrémité de l'abdomen de femelles vierges d'une espèce a été présenté aux femelles de l'autre espèce pour examiner les possibilités de réactions interspécifiques aux phéromones. Pour chaque espèce, les réactions interspécifiques de répulsion entre femelles ont été hautement significatives par rapport aux témoins, à l'exception toutefois des réactions de femelle ayant copulé face à des femelles ayant elles aussi copulé. Les répulsions moyennes chez H. armigera et H. zea pour les 8 femelles de chaque expérience ont été: a) vierges en présence d'une vierge: 7,33 et 7,66; b) vierges en présence d'une femelles ayant copulé: 5,76 et 5,58; c) femelles ayant copulé en présence d'une vierge: 4,67 et 4,83. Les différences sont hautement significatives entre chaque paire de moyennes et entre chaque paire et le lot témoin; 3,17; 3,17; 3,42; 4,00 pour H. armigera; 3,17; 3,50; 2,83 et 3,75 pour H. zea. Les femelles vierges des deux espèces, H. armigera et H. zea ont présenté une réaction de répulsion en présence d'un extrait de l'abdomen de l'autre espèce; les répulsions moyennes étant respectivement 5,53 et 5,33 contre 3,83 et 3,58 pour le lot trémoin. On peut en conclure que ces répulsions doivent entraîner une tendance à la répartition uniforme.
    Notes: Abstract An olfactometer was used to determine the effect of pheromones released by females of the bollworms Heliothis armigera (Hübner) and H. zea (Boddie) on females of the same species. Four combinations of virgin and mated females were tested for repellency of one to the other. Evidence is presented that females of the two bollworms were repelled by females of the same species. In addition, extracts of virgin female abdomens of each species repelled virgin females of the other species.
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  • 5
    ISSN: 1570-7458
    Keywords: Lepidoptera ; Pyralidae ; navel orangeworm ; Amyelois transitella ; pheromone mimic ; mating disruption ; Z,Z-1,12,14-heptadecatriene ; Z,Z-11,13-hexadecadienal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Description / Table of Contents: Résumé Le Z-Z-1,12,14-heptacécatriène, qui mime l'aldéhyde Z-Z-11,13-hexadécadénial, principal composé de la phéromone de A. transitella Walker, a été essayé pour interrompre les accouplements dans la nature. Un conditionnement avec plastique stratifié a mieux dispersé le triène que la présentation en capsules de polyéthylène. Comme dans le cas des autres produits examinés précédemment, ce triène a interrompu l'attraction sexuelle (réduction du nombre de mâles capturés dans les pièges, réduction du nombre d'accouplements) de A. transitella dans les vergers d'amandiers, pendant moins longtemps que l'aldéhyde. Placé dans des pièges contenant des femelles vierges, il est efficace comme l'aldehyde pendant 5 semaines, pendant 3 semaines lorsqu'il est placé autour des pièges et pendant 13 jours quand il est utilisé dans des parcelles de 9 arbres. Des essais ultérieurs avec d'autres présentations et des quantités plus élevées de triène devraient montrer si ce produit peut être utilisé pour l'interruption des accouplements. Les analogues de phéromones ont généralement une plus grande stabilité et un coût de synthèse moins élevé que les aldéhydes.
    Notes: Abstract A novel olefinic analog, Z,Z-1,12,14-heptadecatriene, was synthesized from Z,Z-11,13-hexadecadienal, a major pheromone component of the navel orangeworm, Amyelois transitella (Walker) (Lepidoptera: Pyralidae), and evaluated as a potential disruptant of mating communication in commercial almond orchards. The effectiveness of the triene as a disruptant was compared to that of the aldehyde by evaluating the reduction in captures of feral males in female-baited traps and the reduction in mating success for females. The triene was highly effective in bringing about reductions in male captures in traps in all tests relative to controls. This effectiveness lasted as long as 5 weeks in one test and was influenced by type of dispenser, release rate and proximity of dispensers to female-baited traps. In none of the tests did the triene outperform the aldehyde in reducing male captures. The results of mating success tests showed the triene to be ineffective relative to controls (26% reduction) while the aldehyde yielded 100% reductions in matings during a 6-day period.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Entomologia experimentalis et applicata 48 (1988), S. 157-163 
    ISSN: 1570-7458
    Keywords: sweet potato weevil ; Cylas formicarius elegantulus ; Coleoptera ; Curculionidae ; sweet potato ; Ipomoea batatas ; feeding ; host-plant preference ; leaf surface chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Description / Table of Contents: Résumé L'étude a porté sur la consommation pendant 12 h, en boîtes de Pétri de diamètre 9 cm, de rondelles de 2 cm de diamètre de feuilles de 4 cultivars,—Centennial, Jewel, Resisto, Regal—, d'I. batatas par C. formicarius elegantulus. Les charançons ont consommé le long des nervures, préférant la face inférieure à la face supérieure des feuilles. Un index de consommation a été calculé en fonction de la longueur de nervure ayant servi à la consommation, rapportée à la longueur totale des nervures de la surface exposée. Les niveaux de consommation des mâles et des femelles étaient semblables. En présence de choix binaires, le cultivar Centennial a été le plus consommé, et le cultivar Resisto, le moins, par les femelles. De telles préférences n'ont pas été observées en l'absence de choix. La composition chimique de la surface de la feuille a été analysée par chromatographie en phase gazeuse. 8 pics principaux identiques ont été observés chez les 4 cultivars, mais ils avaient différentes hauteurs.
    Notes: Abstract A bioassay was developed to quantify the feeding of adult sweet potato weevils, Cylas formicarius elegantulus (Summers) (Coleoptera; Curculionidae) on the foliage of four cultivars (Centennial, Jewel, Resisto and Regal) of sweet potato (Ipomoea batatas (L.) Lam.) (Convolvulaceae). Weevils fed along the leaf veins, preferring the lower to the upper leaf surface. Males and females had similar levels of feeding. Different levels of feeding by female weevils were observed between cultivars in dual-choice bioassays with Centennial, a susceptible cultivar in field-plot experiments, being most preferred and Resisto least preferred. However, these feeding differences were not observed in no-choice bioassays. Little difference was observed in the leaf surface chemistry of the four cultivars.
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  • 7
    ISSN: 1420-9071
    Keywords: Acid fluoride ; aldehyde ; mating disruption ; pheromone analogs ; Heliothis ; Lepidoptera ; fluorination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Substitution of fluorine for the aldehydic hydrogen provides behaviorally active, chemically reactive pheromone mimics. In male moths of the tobacco budwormHeliothis virescens, Z9–14:Acf and Z11–16:Acf cause hyperactivity and irreversible extension of the genitalia in over 80% of treated moths. In addition, a combination of the two components leads to 10–50% of the pairs involving one treated partner becoming locked in copula.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 45 (1989), S. 580-583 
    ISSN: 1420-9071
    Keywords: Thiosemicarbazones ; anti-juvenile hormone ; insect growth regulator ; Lepidoptera ; juvenile hormone biosynthesis inhibitor
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary A new class of anti-juvenile hormone agents is described. Active anti-juvenile hormone compounds were either diazine thiosemicarbazones or aryl substituted pyridyl thiosemicarbazones, synthesized from substituted benzaldehydes. While many analogs in these classes showed feeding and growth inhibition in a variety of insects, a select group caused formation of precocious pupal characteristics inAgrotis ipsilon (black cutworm) andHeliothis virescens (tobacco budworm) and black cuticle and precocious pupae inManduca sexta (tobacco hornworm). They were active only by diet incorporation. The symptoms of precocious development could be reversed by co-administration of a juvenoid. One of the active compounds was shown to inhibit juvenile hormone biosynthesis in vitro by corpora allata of the cockroachDiploptera punctata. However, none of the compounds were active inhibitors of purified chicken liver prenyl transferase.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 14 (1980), S. 263-277 
    ISSN: 1573-4889
    Keywords: oxidation ; Ni-Cr alloys ; two-phase alloys
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Oxidation of the relatively simple, two-phase alloy Ni-70 wt.%Cr in oxygen between 1073 and 1473°K results in the formation of a Cr2O3 scale containing less than O.5 wt.% Ni in solid solution. The oxidation kinetics are irreproducible for an initial period, which is brief at 1073 and 1273°K but much more pronounced at 1473°K, both in duration and degree. This behavior is associated with the failure of the protective Cr2O3 scale. However, after longer periods a compact layer of Cr2O3 becomes established under isothermal conditions and results in a change to more reproducible kinetics, especially at 1073 and 1273°K. Oxidation causes chromium depletion and the formation of a single-phase zone which separates the scale and the two-phase bulk alloy. The depth of Cr2O3 internal oxide coincides with this zone. The oxidation behavior is compared with that of more Ni-rich, single-phase Ni-Cr alloys, with particular reference to the effects of the constitution of the underlying alloy and the integrity of the protective oxide.
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  • 10
    Electronic Resource
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    Springer
    Oxidation of metals 18 (1982), S. 295-314 
    ISSN: 1573-4889
    Keywords: Nickel-manganese alloys ; oxidation ; solid solution scales ; internal oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Ni-Mn alloys containing up to 38% Mn have been oxidized in pure oxygen between 873 and 1273 K and the parabolic rate constants measured. The scale morphologies and oxide compositions are interpreted in terms of modifications to the scale on pure Mn caused by the presence of Ni. The scales are composed predominantly of two layers at all temperatures, giving the sequences of phases alloy/cubic monoxide (Ni, Mn)O/ternary spinel, with the cubic (Ni, Mn)O layer always having the greater thickness. There is limited evidence for a third, very thin, outer layer in the scales on all alloys at 873 K and for Ni-38%Mn at 1073 K, which is tentatively considered to be Mn2O3, giving layers in the order alloy/cubic monoxide/ternary spinel/Mn2O3, by analogy with the scale formed on pure Mn. The distribution of the alloy components in the scale is discussed in relation to the Ni-Mn-O phase diagram and in terms of recent theoretical treatments of solid solution scale formation on binary alloys, as far as the available diffusion data allow. The occurrence of internal and intergranular oxidation and the formation of a Mn-depleted zone coincident with the band of uniform internal oxide are considered briefly.
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