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  • Polymer and Materials Science  (6)
  • Engineering  (2)
  • 79.40
  • Epoxide hydrolase
  • Wiley-Blackwell  (8)
  • Springer  (2)
  • 1995-1999  (6)
  • 1975-1979  (4)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 10 (1976), S. 265-268 
    ISSN: 1432-0630
    Schlagwort(e): 79.40 ; 73
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract The field emission current from thin palladium films deposited on insulating tips in UHV was measured as a function of film thickness at relatively low field strengths. The observed periodic oscillations of the field emission current can be interpreted as the quantum size effect.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1432-2048
    Schlagwort(e): Epoxide hydrolase ; Epoxy fatty acid ; Glyoxysome kw]Ricinus ; Seed
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Epoxide hydrolase (EC 3.3.2.3) activity was measured with [1-14C]cis-9,10-epoxystearic acid as the substrate. Homogenates were prepared from the endosperm tissue of germinating seeds of castor bean (Ricinus communis L. zanzibariensis). The activity of fatty-acid epoxide hydrolase was characterized with respect to dependence on time, amount of protein, pH and temperature. Analyses of enzyme distribution in endosperm, cotyledons, root and hypocotyl showed the highest total activity in the endosperm, less in the cotyledons and low activity in the root and hypocotyl. The specific activity was similar for cotyledons and endosperm. Analysis of the temporal expression of the enzyme in the endosperm during germination revealed high activity already in the imbibed seed. Activity was maximal between days four to six and then decreased at the end of one week. Subcellular fractionation of endosperm revealed a dual distribution of activity between the glyoxysomal and the cytosolic fractions.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 50 (1976), S. 9-14 
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Verbindungen der Strukturformeln [π-C5H5M(CO)nX] (M = Fe, n = 2; M = Mo, n = 3; X = CH3, CH2C6H5, CH2Si(CH3)3, CH2OCH3, Sn(C6H5)3, SnCl3, HgCl, I), [Mn(CO)5CH3], und [(π-CH3C5H4)Mn(CO)3] wurden als Katalysatoren für die Härtung von Epoxidharzen unter verschiedenen Bedingungen geprüft. Es wurde gefunden, daß die Verbindungen [π-C5H5Fe(CO)2R] (R = CH3, CH2C6H5) und [π-C5H5Mo(CO)3CH3] wirksame lichtempfindliche Beschleuniger für die Anhydridhärtung von Expoxidharzen sind. Der Aktivierungsmechanismus wird diskutiert.
    Notizen: Compounds of the types [π-C5H5M(CO)nX] (M = Fe, n = 2; M = Mo, n = 3; X = CH3, CH2C6H5, CH2Si(CH3)3, CH2OCH3, Sn(C6H5)3, SnCl3, HgCl, I), [Mn(CO)5CH3], and [(π-CH3C5H4)Mn(CO)3] have been examined as catalysts for the cure of epoxy resins under various conditions. It was found that the compounds [π-C5H5Fe(CO)2R] (R = CH3, CH2C6H5) and [π-C5H5Mo(CO)3CH3] are active photosensitizing agents for the anhydride cure of certain epoxy resins. The mechanism of the process is discussed.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 56 (1976), S. 157-162 
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: 13C-und 1H-NMR-Untersuchungen haben überzeugend gezeigt, daß die Hauptkomponente des Epoxidharzes aus Phenolphthalein und Epichlorhydrin ein aromatischer Diglycidyläther mit einem Lactonring ist und nicht eine chinoide Verbindung mit Glycidylätherund Glycidylesterstruktur.
    Notizen: 13C- and 1H-NMR studies have shown conclusively that the main component of the epoxy resin derived from phenolphthalein and epichlorohydrin is an aromatic diglycidyl ether containing a lactone ring, rather than a glycidyl ether-glycidyl ester compound containing a quinoid ring.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    ISSN: 1057-9257
    Schlagwort(e): gallium nitride ; nanocrystallites ; detonation ; gallium azide ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: High quality nanoscale, phase-pure hexagonal gallium nitride (GaN) crystallites have been synthesized by the thermal induced detonation of molecular precursors of the type (R3N)Ga(N3)3 (R=CH3, C2H5, etc.). The method allows the control of the particle size regime from 2 to about 1000 nm. X-ray diffraction and Rietveld simulations revealed an anisotropic platelet-like shape of the particles. The obtained GaN material was as well characterized by transmission electron microscopy and electron diffraction, photoluminescence spectroscopy, SEM, IR, RAMAN, thermal gas effusion/mass spectrometry, thermal analysis, elemental analysis. Gas absorption measurements (BET method) showed a specific surface area of about 90 m2 · g-1. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 13 (1979), S. 339-342 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 29 (1995), S. 619-626 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: The mechanisms of wear in ultra-high-molecular-weight polyethylene (UHMWPE) acetabular cups were investigated on both laboratory simulator-tested cups and a clinically retrieved component. Two different levels of wear process were identified: one characterized by the formation and detachment of platelet-like flakes from initial machining marks, and the other by the formation of fine ripples and fibrils by repeated passes of microscopic asperities on the femoral head. Both wear processes could be described by a criterion of critical plastic strain. A theoretical model was developed to account for the generation of the microscopic wear particles based on such a critical strain criterion. Its predictions of the dependence of the UHMWPE wear rate on surface roughness and applied load were in excellent agreement with previously published experimental correlations. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 21 (1997), S. 361-378 
    ISSN: 0363-9061
    Schlagwort(e): elastic half-space ; homogeneous ; non-homogeneous ; contour integral approach ; surface displacement ; arbitrarily shaped loading area ; Engineering ; Civil and Mechanical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Geologie und Paläontologie
    Notizen: A numerical technique is presented for the analysis of surface displacements of a non-homogeneous elastic half-space subjected to vertical and/or horizontal surface loads uniformly distributed over an arbitrarily shaped area. The non-homogeneity considered is a particular form of power variation of Young's modulus with depth. Since the exponent which determines the degree of non-homogeneity may vary from zero to unity, both the homogeneous half-space and the Gibson soil may be included as limiting cases in a single numerical scheme. In order to account for the arbitrary shape of the loading, the boundary of the loaded area is linearized piecemeal. This enables the modeling of any load pattern according to the desired degree of accuracy. Special attention is focused on the integration scheme, since the singularity associated with the Green's function becomes progressively more pronounced the greater the non-homogeneity parameter gets. The performance of the numerical procedure is studied using analytical solutions for rectangular shaped areas. Further comparisons with well-known solutions based on integral transform techniques for a uniformly distributed load acting on a circular area of the non-homogeneous soil mass show excellent agreement as well. © 1997 John Wiley & Sons, Ltd.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 21 (1997), S. 379-395 
    ISSN: 0363-9061
    Schlagwort(e): elastic half-space ; homogeneous ; non-homogeneous ; integration free approach ; surface displacement ; rectangular shaped loading area ; Engineering ; Civil and Mechanical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Geologie und Paläontologie
    Notizen: An alternative approach for calculating the surface displacements of a non-homogeneous half-space acted upon by a vertical and/or horizontal load, uniformly distributed over a rectangular area, is presented in this part of the paper. The procedure proposed proves to be extremely efficient since the displacements can be found without numerical integration for this special loading pattern. Comparisons with solutions for rectangular loaded areas on Boussinesq- and Gibson-type soil show perfect agreement. In the case of the non-homogeneous half-space the procedure was checked using the method outlined in the first part of this paper revealing that both approaches come up with identical answers. Some results of a parametric study are presented for the surface displacements of a non-homogeneous half-space subject to vertical and horizontal loading. In this study both the material properties of the soil mass, i.e. Young's modulus and Poisson's ratio and the aspect ratio of the loading are varied. These results are presented in the form of influence charts which may readily be used in hand calculations for estimating the displacements of footings on a non-homogeneous soil. © 1997 John Wiley & Sons, Ltd.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Acta Polymerica 46 (1995), S. 64-67 
    ISSN: 0323-7648
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Permittivity ∊′ and dielectric loss ∊″ of novolac have been determined in the temperature interval from  - 150 to 150°C and in the frequency interval from 102.5 to 106 Hz. Novolac exhibits a main and a secondary relaxation process. For the main relaxation a master curve of ∊″ was calculated, the shape of which was described by the Havriliak - Negami function (HN). The parameters of the HN fit were interpreted by a model that relates the values to the polymer structure. Furthermore, the temperature dependence of the dielectric relaxation times was analyzed by a WLF approach for the main relaxation and an Arrhenius approach for the secondary relaxation. The dielectric relaxation times of the main relaxation were correlated with the electrical conductivity and the melt viscosity.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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