ALBERT

Description: In this paper, we analyze the strong unidentified emission near 3.28 micron in Titan's upper daytime atmosphere recently discovered by Dinelli et al.We have studied it by using the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbons (PAHs), after absorbing UV solar radiation, are able to emit strongly near 3.3 micron. By using current models for the redistribution of the absorbed UV energy, we have explained the observed spectral feature and have derived the vertical distribution of PAH abundances in Titan's upper atmosphere. PAHs have been found to be present in large concentrations, about (2-3) 10(exp 4) particles / cubic cm. The identified PAHs have 9-96 carbons, with a concentration-weighted average of 34 carbons. The mean mass is approx 430 u; the mean area is about 0.53 sq. nm; they are formed by 10-11 rings on average, and about one-third of them contain nitrogen atoms. Recently, benzene together with light aromatic species as well as small concentrations of heavy positive and negative ions have been detected in Titan's upper atmosphere. We suggest that the large concentrations of PAHs found here are the neutral counterpart of those positive and negative ions, which hence supports the theory that the origin of Titan main haze layer is located in the upper atmosphere.

Description: No abstract

Description: Published

Description: 92-117

Description: 4V. Vulcani e ambiente

Description: restricted

Description: L’Italia e l’Indonesia hanno avviato nel 2005-2006 un progetto di cooperazione sulle tematiche della mitigazione del rischio vulcanico. Nell’ambito di questo progetto è stata individuata la zona ovest di Sumatra come area di intervento. In particolare è stato preso in considerazione il vulcanoMarapi. Questo vulcano ha avuto frequente attività eruttiva nelle ultime decine di anni. L’ultima eruzione si è verificata nel 2004. La sua attività, sebbene di moderata intensità, pone un problema di protezione civile, poiché dal 1980 ad oggi ha causato diversi feriti e alcune vittime tra i turisti che hanno visitato l’area craterica sommitale. Allo scopo di monitorare lo stato di attività del Marapi, nell’ambito del citato progetto è stata realizzata una rete sismica a larga banda composta da 4 stazioni e basata su sensori Guralp GMG-40T da 60s di periodo e su acquisitori di tipo GAIA2, prodotti presso l’Istituto Nazionale di Geofisica e Vulcanologia. La strumentazione è stata portata dall’Italia ed è stata installata da un gruppo di lavoro formato da italiani ed indonesiani. Oltre all’installazione della strumentazione in campagna è stato necessario allestire un vero e proprio Centro di Monitoraggio presso l’Osservatorio di Bukittinggi, in prossimità delle pendici nordoccidentali del vulcano, dotato di calcolatori per l’acquisizione, l’analisi dei dati e la loro archiviazione. Il sistema per ilmonitoraggio sismologico realizzato alMarapi costituisce un importante strumento di prevenzione del rischio associato all’attività di questo vulcano e sta permettendo di creare un ricco data set utile a caratterizzare la sismicità della struttura vulcanica e dell’area circostante. Da un’analisi preliminare dei dati registrati nel periodo 19/10/2006 - 24/11/2008 si evidenzia che il vulcanomanifesta una sismicità di tipo VT ed LP. Nell’ agosto 2007 sono stati inoltre registrati segnali probabilmente attribuibili a modesta attività esplosiva nell’area sommitale. Italy and Indonesia started a cooperation project in 2005-2006 to cover issues for the mitigation of volcanic risk. In this project, the west area of Sumatra was identified as the area for intervention. In particular, the Marapi volcano was considered. This volcano has shown frequent eruptive activity over recent decades, with the last eruption occurring in 2004. Although its activity is of moderate intensity, it creates a civil protection problem, because since 1980 it has resulted in several injuries and a number of deaths among the tourists who visit the summit crater area. To monitor the activity of Marapi volcano as part of this project, a broadband seismic network has been implemented that consists of four stations based on Guralp GMG 40T sensors with period of 60 s and on GAIA2 data-loggers, which are produced at the INGV. The instrumentation was brought from Italy and was installed by a working group comprising Italians and Indonesians. In addition to the instrumentation in the field, it was necessary to set up a monitoring centre in the Bukittinggi Observatory, which is near the north-western slopes of the Marapi volcano. This is equipped with computers for data acquisition, analysis and archiving. The system for seismological monitoring that has been realized atMarapi volcano is an important tool in the prevention of the risk associated with this volcano, and it is providing a rich dataset that will be of great use for the characterization of the seismicity of the Marapi volcanic structure and the surrounding area. A preliminary analysis of the data recorded during the period 19/10/2006 - 24/11/2008 evidences that the volcano shows VT and LP seismicity. In August 2007 were also recorded signals probably attributable to small explosive activity in the summit area.

Description: INGV Istituto Nazionale di Geofisica e Vulcanologia

Description: Published

Description: 5-21

Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive

Description: N/A or not JCR

Description: open

Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the most important greenhouse gas after carbon dioxide. It has recently been established that geogenic gases contribute significantly to the natural CH4 flux to the atmosphere (Etiope et al., 2008). Volcanic/geothermal areas contribute to this flux, being the site of widespread diffuse degassing of endogenous gases (Chiodini et al., 2005). In such an environment soils are a source rather than a sink for atmospheric CH4 (Cardellini et al., 2003; Castaldi and Tedesco, 2005; D’Alessandro et al., 2009; 2011; 2013). Due to the fact that methane soil flux measurements are laboratory intensive, very few data have been collected until now in these areas. Preliminary studies (Etiope et al., 2007) estimated a total CH4 emission from European geothermal and volcanic systems in the range 4-16 kt a-1. This estimate was obtained indirectly from CO2 or H2O output data and from CO2/CH4 or H2O/CH4 values measured in the main gaseous manifestations. Such methods, although acceptable to obtain order-of-magnitude estimates, completely disregard possible methanotrophic activity within the soil. At the global scale, microbial oxidation in soils contributes for about 3-9% to the total removal of methane from the atmosphere. But the importance of methanotrophic organisms is even larger because they oxidise the greatest part of the methane produced in the soil and in the subsoil before its emission to the atmosphere. Environmental conditions in the soils of volcanic/geothermal areas (i.e. low oxygen content, high temperature and proton activity, etc.) have been considered inadequate for methanotrophic microrganisms. But recently, it has been demonstrated that methanotrophic consumption in soils occurs also under such harsh conditions due to the presence of acidophilic and thermophilic Verrucomicrobia. These organisms were found in Italy at the Solfatara di Pozzuoli (Pol et al., 2007), in New Zealand at Hell’s Gate (Dunfield et al., 2007) and in Kamchatka, Russia (Islam et al., 2008). Both the Italian and the Hellenic territories are geodynamically very active with many active volcanic and geothermal areas. Here we report on methane flux measurements made at Pantelleria (Italy) and at Sousaki and Nisyros (Greece). The total methane output of these three systems is about 10, 19 and 1 t a-1, respectively (D’Alessandro et al., 2009; 2011; 2013). The total emissions obtained from methane flux measurements are up to one order of magnitude lower than those obtained through indirect estimations. Clues of methanotrophic activity within the soils of these areas can be found in the CH4/CO2 ratio of the flux measurements which is always lower than that of the respective fumarolic manifestations, indicating a loss of CH4 during the travel of the gases towards earth’s surface. Furthermore laboratory methane consumption experiments made on soils collected at Pantelleria and Sousaki revealed, for most samples, CH4 consumption rates up to 9.50 µg h-1 and 0.52 µg h-1 respectively for each gram of soil (dry weight). Only few soil samples displayed no methane consumption activity. Finally, microbiological and molecular investigations allowed us to identify the presence of methanotrophic bacteria belonging to the Verrucomicrobia and to the Alpha- and Gamma-Proteobacteria in the soils of the geothermal area of Favara Grande at Pantelleria. While the presence of the former was not unexpected due to the fact that they include acidophilic and thermophilic organisms that were previously found in other geothermal environments, the latter are generally considered not adapted to live in harsh geothermal environments. Their presence in the soils of Pantelleria could be explained by the fact that these soils do not have extremely low pH values (〉5). Indeed thermotollerant methanotrophic Gamma-proteobacteria, have been previously found in the sediments of thermal springs in Kamchatka (Kizilova et al., 2012). Such species could find their niches in the shallowest part of the soils of Favara Grande were the temperatures are not so high and they thrive on the abundant upraising hydrothermal methane.

Description: Published

Description: Patras, Greece

Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi

Description: open

Description: Volcanic and geothermal systems emit endogenous gases by widespread degassing from soils, including CH4, a greenhouse gas twenty-five times as potent as CO2. Recently, it has been demonstrated that volcanic or geothermal soils are not only a source of methane, but are also sites of methanotrophic activity. Methanotrophs are able to consume 10–40 Tg of CH4 a−1 and to trap more than 50% of the methane degassing through the soils. We report on methane microbial oxidation in the geothermally most active site of Pantelleria (Italy), Favara Grande, whose total methane emission was previously estimated at about 2.5Mga−1 (t a−1). Laboratory incubation experiments with three top-soil samples from Favara Grande indicated methane consumption values of up to 59.2 nmol g−1 soil d.w. h−1. One of the three sites, FAV2, where the highest oxidation rate was detected, was further analysed on a vertical soil profile, the maximum methane consumption was measured in the topsoil layer, and values greater than 6.23 nmol g−1 h−1 were still detected up to a depth of 13 cm. The highest consumption rate was measured at 37 C, but a still detectable consumption at 80 C (〉1.25 nmol g−1 h−1) was recorded. The soil total DNA extracted from the three samples was probed by Polymerase Chain Reaction (PCR) using standard proteobacterial primers and newly designed verrucomicrobial primers, targeting the unique methane monooxygenase gene pmoA; the presence of methanotrophs was detected at sites FAV2 and FAV3, but not at FAV1, where harsher chemical–physical conditions and negligible methane oxidation were detected. The pmoA gene libraries from the most active site (FAV2) pointed to a high diversity of gammaproteobacterial methanotrophs, distantly related to Methylocaldum-Metylococcus genera, and the presence of the newly discovered acido-thermophilic Verrucomicrobia methanotrophs. Alphaproteobacteria of the genus Methylocystis were isolated from enrichment cultures under a methane-containing atmosphere at 37 C. The isolates grow at a pH range of 3.5 to 8 and temperatures of 18–45 C, and consume 160 nmol of CH4 h−1 mL−1 of culture. Soils from Favara Grande showed the largest diversity of methanotrophic bacteria detected until now in a geothermal soil. While methanotrophic Verrucomicrobia are reported as dominating highly acidic geothermal sites, our results suggest that slightly acidic soils, in high-enthalpy geothermal systems, host a more diverse group of both culturable and uncultivated methanotrophs.

Description: Published

Description: 5865–5875

Description: 4V. Vulcani e ambiente

Description: JCR Journal

Description: open

Description: Twenty-five lava fountains occurred on Mt. Etna from January 2011 to April 2012. In summer 2012 volcanic activity resumed in a milder form within the Bocca Nuova crater, before it came to an essential halt in August 2012. All these unrests offer rich material for testing automatic procedures of data processing and alert systems, running 24/7, in the context of volcano surveillance. We focus on the seismic background radiation – volcanic tremor – which plays a key role in the monitoring of Mt. Etna. Since 2006 a multistation alert system has been established in the INGV operative centre of Catania exploiting STA/LTA ratios. Besides, also the spectral characteristics of the signal, which change correspondingly to the type of volcanic activity, can be exploited for warning purposes. Here we apply Self Organizing Maps and Fuzzy Clustering which offer an efficient way to visualize signal characteristics and its development with time. All these techniques allow to identify early stages of eruptive events, and automatically flag a critical status before this becomes evident in conventional monitoring techniques. Changes of tremor characteristics are related to the position of the source of the signal. The location of the sources exploits the distribution of the amplitudes across the seismic network. The locations were extremely useful for warning, throughout both the flank eruption in 2008 as well as the 2011 lava fountains, during which a clear migration of tremor sources towards the eruptive centres could be noticed in advance. The location of the sources completes the picture of an imminent volcanic unrest, and corroborates early warnings flagged by the changes of signal characteristics. Real time data processing requires computational efficiency, robustness of the methods and stability of data acquisition. The amplitude based multi-station approach is not sensitive to the failure of single stations and therefore offers a good stability. The single station approach, exploiting unsupervised classification techniques, limits logistic efforts, as only one or few key stations are necessary. Both strategies have proven to be insensitive to disturbances (undesired transients like earthquakes, noise, short gaps in the continuous data flow). False alarms were not encountered so far. Stable data acquisition and processing come with a properly designed data storage solution. The reliability of data storage and its access is a critical issue. A cluster architecture has been realized for failover protection, including a Storage Area Network system, which allow easy data access following predefined user policies. We present concepts of the software architectures deployed at INGV Osservatorio Etneo in order to implement this tremor-based multi approach system. We envisage the integration of seismic data and those originating from other scientific fields (e. g., volcano imagery, geochemistry, deformation, gravity, magneto-telluric). This will facilitate cross-checking of evidences encountered from the single data streams, in particular allow their immediate verification with respect to ground truth.

Description: Published

Description: Nicolosi (Catania, Italy)

Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive

Description: 5.6. TTC - Attività di Sala Operativa

Description: open

Description: Eighteen paroxysmal episodes occurred on Mt Etna in 2011, and provided rich material for testing automatic procedures of data processing and alert systems in the context of volcano monitoring. The 2011 episodes represent a typical picture of activity of Mt Etna: in 2000 and 2001, before the 2001 flank eruption, more than one hundred lava fountains were encountered. Other major lava fountains occurred before the flank eruptions of 2002/03 and 2008. All these fountains, which are powerful but usually short lived phenomena, originated from the South-East Crater area and caused the formation of thick ash clouds, followed by the fallout of material with severe problems for the infrastructure of the metropolitan area of Catania. We focus on the seismic background radiation – volcanic tremor – which plays a key role in the surveillance of Mt Etna. Since 2006 a multi-station alert system has been established in the INGV operative centre of Catania exploiting STA/LTA ratios. Besides, it has been demonstrated that also the spectral characteristics of the signal changes correspondingly to the type of volcanic activity. The simultaneous application of Self Organizing Maps and Fuzzy Clustering offers an efficient way to visualize signal characteristics and its development with time, allowing to identify early stages of eruptive events and automatically flag a critical status before this becomes evident in conventional monitoring techniques. Changes of tremor characteristics are related to the position of the source of the signal. The location of the sources exploits the distribution of the amplitudes across the seismic network. The locations were extremely useful for warning throughout both a flank eruption in 2008 as well as the 2011 lava fountains, during which a clear migration of tremor sources towards the eruptive centres could be noticed in advance. The location of the sources completes the picture of an imminent volcanic unrest and corroborates early warnings flagged by the changes of signal characteristics. On-line data processing requires computational efficiency, robustness of the methods and reliability of data acquisition. The amplitude based multi-station approach offers a reasonable stability as it is not sensitive to the failure of single stations. The single station approach, based on our unsupervised classification techniques, is cost-effective with respect to logistic efforts, as only one or few key stations are necessary. Both systems have proven to be robust with respect to disturbances (undesired transients like earthquakes, noise, short gaps in the continuous data flow), and false alarms were not encountered so far. Another critical aspect is the reliability of data storage and access. A hardware cluster architecture has been proposed for failover protection, including a Storage Area Network system. We outline concepts of the software architectures which allow easy data access following predefined user policies. We envisage the integration of seismic data and those originating from other scientific fields (such as volcano imagery, geochemistry, deformation, gravity, magneto-telluric), in order to facilitate cross-checking of the findings encountered from the single data streams, in particular allowing their immediate verification with respect to ground truth.

Description: Published

Description: 53-92

Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive

Description: partially_open

Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after carbon dioxide. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (IPCC, 2007). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Active or recent volcanic/geothermal areas represent one of these sources of geological methane. But due to the fact that methane flux measurements are laboratory intensive, very few data have been collected until now and the contribution of this source has been generally indirectly estimated (Etiope et al., 2007). The Greek territory is geodynamically very active and has many volcanic and geothermal areas. Here we report on methane flux measurements made at two volcanic/geothermal systems along the South Aegean volcanic arc: Sousaki and Nisyros. The former is an extinct volcanic area of Plio-Pleistocene age hosting nowadays a low enthalpy geothermal field. The latter is a currently quiescent active volcanic system with strong fumarolic activity due to the presence of a high enthalpy geothermal system. Both systems have gas manifestations that emit significant amounts of hydrothermal methane and display important diffuse carbon dioxide emissions from the soils. New data on methane isotopic composition and higher hydrocarbon contents point to an abiogenic origin of the hydrothermal methane in the studied systems. Measured methane flux values range from –48 to 29,000 (38 sites) and from –20 to 1100 mg/mˆ2/d (35 sites) at Sousaki and Nisyros respectively. At Sousaki measurement sites covered almost all the degassing area and the diffuse methane output can be estimated in about 20 t/a from a surface of about 10,000 mˆ2. At Nisyros measurements covered the Stephanos and Kaminakia areas, which represent only a part of the entire degassing area. The two areas show very different methane degassing pattern with latter showing much higher flux values. Methane output can be estimated in about 0.25 t/a from an area of about 30,000 mˆ2 at Stephanos and about 1 t/a from an area of about 20,000 mˆ2 at Kaminakia. The total output from the entire geothermal system of Nisyros probably should not exceed 2 t/a.

Description: Published

Description: Vienna, Austria

Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi

Description: open

Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.

Description: Published

Description: Vienna, Austria

Description: 4.4. Scenari e mitigazione del rischio ambientale

Description: open