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  • American Institute of Physics (AIP)  (10)
  • 2020-2023
  • 1990-1994  (10)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 3201-3203 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Detailed transmission and scanning electron microscopic images of electromigration-induced open circuit failures are presented for fine line aluminum alloy thin film interconnects. A characteristic slit open circuit, similar to stress migration open circuits in narrow interconnects, is shown for various film compositions, processing, and deposition conditions. It is suggested that slit failure morphology is more generally observed for low (≈1) ratios of conductor line width to film grain size. The slit failures observed often occur near copper rich precipitates. The morphology of several slit voids suggests that they are transgranular across the linewidth, consistent with other recent reports of electromigration induced damage in single crystal interconnects.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 4885-4893 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This work is principally concerned with the microstructure of electromigration failure in narrow Al-2Cu-1Si conducting lines on Si. Samples were patterned from 0.5-μm-thick vapor-deposited films with mean grain size of 2.4 μm, and had linewidths of 1.3 μm (W/G≈0.5), 2 μm (W/G≈0.8), and 6 μm (W/G≈2.5). The lines were tested to failure at T=226 °C and j=2.5×106 A/cm2. Other samples were tested over a range of substrate temperatures and current densities to test the effect of these variables, and 1.3 μm lines were tested after preaging at 226 °C for various times to change the Cu-precipitate distribution prior to testing. Three failure modes were observed: The 6 μm specimens failed by separation along grain boundaries with an apparent activation energy of 0.65 eV; the 1.3 μm specimens that were preaged for 24 h failed after very long times by gradual thinning to rupture; all other narrow lines failed by the transgranular-slit mechanism with an activation energy near 0.93 eV. Microstructural studies suggest that the transgranular-slit failure mechanism is due to the accumulation of a supersaturation of vacancies in the bamboo grains that terminate polygranular segments in the line. Failure occurs after Cu has been swept from the grain that fails. Failure happens first at the end of the longest polygranular segment of the line, at a time that decreases exponentially with the polygranular segment length. Preaging the line to create a more stable distribution of Cu lengthens the time required to sweep Cu from the longest polygranular segment, and significantly increases the time to failure. In the optimal case the transgranular-slit failure mechanism is suppressed, and the bamboo grain fails by diffuse thinning to rupture. Preaging is particularly effective in increasing the lifetimes of lines that contain very long polygranular segments, and has the consequence that the time to first failure in an array of lines is much longer than predicted by a log-normal fit to the distribution of failure times.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 1837-1845 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This paper reports a study of the effect of Cu precipitation on electromigration failure in Al-2Cu-1Si thin-film conducting lines. The films were 0.5 μm in thickness, and patterned to widths of 1.3 and 4 μm, providing width-to-grain-size ratios (W/G) of approximately 0.5 and 2. The lines were aged for various times at 226 °C, and were then tested to failure at a current density of 2.5×106 A/cm2. Scanning and transmission electron microscopy were used to study the Cu precipitate distribution, its evolution during aging and electromigration, and the microstructural failure mechanism. Aging produces a dense distribution of intragranular θ' (Al2Cu; coherent), with stable θ (Al2Cu; incoherent) in the grain boundaries. The θ' is replaced by θ as aging proceeds. In the wide lines (W/G≈2), the mean time to failure (MTF) increases slowly and monotonically with prior aging time. The failure happens through the growth and coalescence of intergranular voids. In the narrow lines (W/G≈0.5), both the MTF and the time to first failure increase by more than an order of magnitude when the line is aged for 24 h prior to testing, then decrease on further aging. The dominant failure mode is the "slit'' failure mode previously observed in pure Al. However, the 24 h specimens fail by gradual, uniform thinning. Failure occurs in regions that have been swept free of intragranular precipitates. The failure time appears to be proportional to the intragranular density of θ precipitates, and related to the time required to sweep these from a critical length of line.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 9476-9479 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A hyperthermal beam of state-selected NO+ X Σ+(v=0–6) ions is scattered on a clean, well-characterized GaAs(110) surface. The threshold for the appearance of scattered O− ions occurs at a collision energy of 25 eV. Vibrational energy proves to be an order of magnitude more effective than translational energy in enhancing the yield in this channel.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 1991-1998 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We describe an external control circuit for a commercial, real-time, self-scanning photodiode array system. It had a phase-locked loop that synchronized the scan of the photodiode array to an external reference frequency. The signal from the photodiode array had, in principle, an infinite signal-to-noise ratio at the reference frequency. The circuit allowed independent adjustment of the integration time of the array and was simple and inexpensive to build. It was useful in measuring periodic or pulsed spectra such as occurs in laser or communications experiments.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 2481-2488 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The electrical and chemical properties of the interfaces formed at room temprature, between the surface of epitaxial n-type InyAl1−yAs(100) and a selection of metals have been studied. Highly ideal Au, Ag, Cu, and In diodes exhibiting the highest reported barriers (0.78–0.91 eV), measured by the current-voltage (I-V) technique, have been obtained by forming intimate contacts on atomically clean, lattice matched, molecular beam epitaxy grown InyAl1−yAs/InP(100). The formation of Au- and In-InyAl1−yAs interfaces has been investigated using x-ray photoemission spectroscopy, showing that in both cases the Fermi level is pinned at the surface prior to metal deposition. The deposition of both In and Au overlayers initiated the selective removal of As from the interface to segregate on the metal surface; however the presence of these metals on the semiconductor surface produced no further Fermi shift. These observations, in conjunction with the barrier heights measured by the I-V technique, are discussed in the context of currently supported models of Schottky barrier formation.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 879-884 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The rate of resistivity decay in Al-2Cu-1Si thin-film conductors was studied as a function of temperature and grain size distribution. The decay kinetics were assumed to be governed by the rate of precipitate reconfiguration to grain boundaries. This assumption was confirmed by transmission electron microscopy (TEM) observations of the microstructure during resistance decay, and by studies of lines of two different widths. The results can be explained qualitatively from the microstructure of the lines. In particular, increasing the mean grain size slows the rate of resistivity decay, and establishing a bimodal distribution with a significant population of relatively large grains has the same effect. A simple model was developed to treat these effects quantitatively. The model assumes a cylindrical grain geometry and a uniform initial distribution of Cu and ignores the effect of intragranular precipitation. The model yields reasonable values for the activation energy for Cu diffusion in thin films, and predicts the correct dependence of the decay rate on grain size and grain distribution; however, it appears to overestimate the value of the preexponential factor D0.
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 6791-6812 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The scattering of state-selected NO+(X 1Σ+, v=0–6) on GaAs(110) was explored across the hyperthermal energy region. Relative yields and velocity distributions for scattered anionic products NO−(X 3Σ−, v=0) and O−(2P) were measured as a function of the number of vibrational quanta and collision energy for NO+(X 1Σ+, v=0–6) incident on the surface. Facile neutralization along the inbound trajectory forms vibrationally excited NO(2Π) immediately prior to surface impact. Electron attachment to form NO−(X 3Σ−, v=0) occurs near the distance of closest approach between the molecule and surface. With regard to O−(2P) emergence, a collision-induced dissociation mechanism is consistent with the observed 25 eV threshold. Incident vibrational energy is as much as ten times more effective than translational energy in forming O−(2P). This paper represents the first experimental investigation into the effect of vibrational energy on electron transfer and dissociation of ions at surfaces and highlights the unique interplay between translational and vibrational motions in an ion/surface encounter.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 1079-1087 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The enhancement of long wavelength (〉600 nm) light absorption by light scattering can result in a significant increase in the short circuit current density of a-Si:H-based solar cells. A model of absorption enhancement is presented and used to predict both light absorption in the active i layer and the total reflectance of single-junction a-Si:H p-i-n solar cells. These results are compared with the corresponding measurements performed on actual solar cells. It is found that the texture imparted to the metallic interface may result in a significant decrease in the reflectance of the rear contact, and in certain of the rear contacts considered, the reflectance is also reduced by interface formation phenomena. These mechanisms reduce the reflectance of the aluminum rear contact to less than 50% in the solar cells studied. In these cells and others where large light absorption occurs in the rear contact, incomplete light randomization is not found to be an important enhancement limiting effect. A thin layer of indium-tin-oxide inserted between the a-Si:H n layer and the contact metal results in critical trapping of scattered light and so reduces light absorption in the rear contact.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY : American Institute of Physics (AIP)
    Physics of Fluids 5 (1993), S. 2317-2325 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The pressure moment of a rigid particle is defined to be the trace of the first moment of the surface stress acting on the particle. A Faxén law for the pressure moment of one spherical particle in a general low-Reynolds-number flow is found in terms of the ambient pressure, and the pressure moments of two rigid spheres immersed in a linear ambient flow are calculated using multipole expansions and lubrication theory. The results are expressed in terms of resistance functions, following the practice established in other interaction studies. The osmotic pressure in a dilute colloidal suspension at small Péclet number is then calculated, to second order in particle volume fraction, using these resistance functions. In a second application of the pressure moment, the suspension or particle-phase pressure, used in two-phase flow modeling, is calculated using Stokesian dynamics and results for the suspension pressure for a sheared cubic lattice are reported.
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