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  • 1
    Publication Date: 2022-04-22
    Description: New geochemical and isotopic data on volcanic rocks spanning the period ~75–50 ka BP on Ischia volcano, Italy, shed light on the evolution of the magmatic system before and after the catastrophic, caldera-forming Monte Epomeo Green Tuff (MEGT) eruption. Volcanic ac tivity during this period was influenced by a large, composite and differentiating magmatic system, replenished several times with isotopically distinct magmas of deepprovenance. Chemical and isotopic variations highlight that the pre-MEGT eruptions were fed by trachytic/phonolitic magmas from an isotopically zoned reservoir that were poorly enriched in radiogenic Sr and became progressively less radiogenic with time. Just prior to the MEGT eruption, the magmatic system was recharged by an isotopically distinct magma, relatively more enriched in radiogenic Sr with respect to the previously erupted magmas. This second magma initially fed several SubPlinian explosive eruptions and later supplied the climactic, phonolitic-to-trachytic MEGT eruption(s). Isotopic data, together with erupted volume estimations obtained for MEGT eruption(s), indicate that 〉5–10 km3of this relatively enriched magma had accumulated in the Ischia plumbing system. Geochemical modelling indicates that it accumulated at shallow depths (4–6 km), over a period of ca. 20 ka. After the MEGT eruption, volcanic activity was fed by a new batch of less differentiated (trachyte-latite) magma that was slightly less enriched in radiogenic Sr. The geochemical and Sr–Nd-isotopic variations through time reflect the upward flux of isotopically distinct magma batches, variably contaminated byHercynian crust at 8–12 km depth. The deep-sourced latitic to trachytic magmas stalled at shallow depths (4–6 km depth), differentiated to phonolite through crystal fractionation and assimilation of a feldspar-rich mush, or ascended directly to the surface and erupted.
    Description: Published
    Description: 1035
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Ischia volcano ; Magmatic plumbing system ; Radiogenic isotopes ; Geothermometry ; Feldspar assimilation ; Caldera collapse
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-12-10
    Description: Groundwater close to three municipal solid waste landfll sites in Sicily (southern Italy) was sampled to determine the presence of contaminants and the risk associated with its possible use as drinking and sanitary water. Polycyclic aromatic hydrocarbons, polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and metals were investigated. These target compounds are the most common pollutants present in leachates. Risk Assessment Guidance for Superfund (RAGS, US EPA) was used to assess human health risk. Ingestion, dermal, and total exposure to these xenobiotic contaminants in groundwater were evaluated, and the cancer and non-cancer risk indexes were calculated. The results revealed that, while the groundwater complied with Italian Drinking Water Directive 30/2001, it did not comply with the "good environmental state" criteria of Directive 30/2009 at two of the three sites investigated. Worrying results were revealed by the risk assessment at the investigated sites. Cancer and non-cancer risk indexes indicated a probable risk, mainly due to dermal exposure to groundwater. These results underline the importance of assessing the risk for all possible routes, evaluating not only ingestion but also dermal exposure, especially when organic pollutants are present. The results of this study show that human health risk has probably been underestimated in the past, as dermal exposure to organic pollutants has only rarely been evaluated in the literature.
    Description: Published
    Description: 535–550
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Human health risk ; Polycyclic aromatic hydrocarbons ; Polychlorinated biphenyls ; Dioxin PCDD/Fs ; Toxic elements ; Environmental quality standard
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Wallace, E. J., Donnelly, J. P., van Hengstum, P. J., Winkler, T. S., McKeon, K., MacDonald, D., d'Entremont, N. E., Sullivan, R. M., Woodruff, J. D., Hawkes, A. D., & Maio, C. 1,050 years of hurricane strikes on long island in the Bahamas. Paleoceanography and Paleoclimatology, 36(3), (2021): e2020PA004156, https://doi.org/10.1029/2020PA004156.
    Description: Sedimentary records of past hurricane activity indicate centennial-scale periods over the past millennium with elevated hurricane activity. The search for the underlying mechanism behind these active hurricane periods is confounded by regional variations in their timing. Here, we present a new high resolution paleohurricane record from The Bahamas with a synthesis of published North Atlantic records over the past millennium. We reconstruct hurricane strikes over the past 1,050 years in sediment cores from a blue hole on Long Island in The Bahamas. Coarse-grained deposits in these cores date to the close passage of seven hurricanes over the historical interval. We find that the intensity and angle of approach of these historical storms plays an important role in inducing storm surge near the site. Our new record indicates four active hurricane periods on Long Island that conflict with published records on neighboring islands (Andros and Abaco Island). We demonstrate these three islands do not sample the same storms despite their proximity, and we compile these reconstructions together to create the first regional compilation of annually resolved paleohurricane records in The Bahamas. Integrating our Bahamian compilation with compiled records from the U.S. coastline indicates basin-wide increased storminess during the Medieval Warm Period. Afterward, the hurricane patterns in our Bahamian compilation match those reconstructed along the U.S. East Coast but not in the northeastern Gulf of Mexico. This disconnect may result from shifts in local environmental conditions in the North Atlantic or shifts in hurricane populations from straight-moving to recurving storms over the past millennium.
    Description: This work was funded by the National Science Foundation Graduate Research Fellowship (to E. J. W.), the Dalio Explore Foundation, and National Science Foundation grant OCE-1356708 (to J. P. D. and P. J. vH.).
    Keywords: Bahamas ; Blue holes ; Carbonates ; Paleohurricanes ; Sediment cores
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Publication Date: 2022-06-22
    Description: Geothermal areas of Greece are located in regions affected by recent volcanism and in continental basins characterised by elevated heat flow. Many of them are found along the coast and thus, water is often saline due to marine intrusion. In the current study, we present about 300 unpublished and literature data from thermal and cold mineral waters collected along Greece. Samples were analysed for major ions, Li, SiO2 and isotopes in water. Measured temperatures range from 6.5 to 98°C, pH from 1.96 to 11.98, whilst Total Dissolved Solutes (TDS) from 0.22 to 51 g/L. Waters were subdivided into four main groups: i) thermal; ii) cold; iii) acidic (pH 〈5) and iv) hyperalkaline (pH 〉11). On statistical basis, the thermal waters were subdivided into subgroups according to both their temperature [warm (〈29 °C), hypothermal (29-48 °C), thermal (48-75 °C) and hyperthermal (〉75 °C)] and TDS [low salinity (〈4 g/L), brackish (4-30 g/L) and saline (〉30 g/L)]. Cold waters were subdivided basing on their pCO2 [low (〈0.05 atm), medium (0.05-0.85 atm) and high (〉0.85 atm)]. δ18O-H2O ranges from -12.7 to +2.7 ‰ vs. SMOW, while δ2H-H2O from -91 to +12 ‰ vs. SMOW being generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Positive δ18O shifts with respect to the former are mostly related to mixing with seawater, while only for a few samples they point to high-temperature water-rock interaction processes. Only a few thermal waters gave reliable geothermometric estimates, suggesting reservoir temperatures between 80 and 260 °C.
    Description: Published
    Description: 2111–2133
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Hydrogeochemistry ; Stable isotopes ; Carbon dioxide ; Geothermometry ; 03. Hydrosphere ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2022-10-19
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography and Paleoclimatology 36(7), (2021): e2020PA004088, https://doi.org/10.1029/2020PA004088.
    Description: We reconstruct deep water-mass salinities and spatial distributions in the western North Atlantic during the Last Glacial Maximum (LGM, 19–26 ka), a period when atmospheric CO2 was significantly lower than it is today. A reversal in the LGM Atlantic meridional bottom water salinity gradient has been hypothesized for several LGM water-mass reconstructions. Such a reversal has the potential to influence climate, ocean circulation, and atmospheric CO2 by increasing the thermal energy and carbon storage capacity of the deep ocean. To test this hypothesis, we reconstructed LGM bottom water salinity based on sedimentary porewater chloride profiles in a north-south transect of piston cores collected from the deep western North Atlantic. LGM bottom water salinity in the deep western North Atlantic determined by the density-based method is 3.41–3.99 ± 0.15% higher than modern values at these sites. This increase is consistent with: (a) the 3.6% global average salinity change expected from eustatic sea level rise, (b) a northward expansion of southern sourced deep water, (c) shoaling of northern sourced deep water, and (d) a reversal of the Atlantic's north-south deep water salinity gradient during the LGM.
    Description: This work was supported by the US National Science Foundation (grant numbers 1433150 and 1537485).
    Description: 2021-10-24
    Keywords: Carbon cycle ; Climate change ; Deep water ; Glaciation ; Meridional overturning circulation ; Paleosalinity ; Porewater
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 6
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in E. J., Donnelly, J. P., van Hengstum, P. J., Wiman, C., Sullivan, R. M., Winkler, T. S., d'Entremont, N. E., Toomey, M., & Albury, N. Intense hurricane activity over the past 1500 years at South Andros Island, the Bahamas. Paleoceanography and Paleoclimatology, 34(11), (2019): 1761-1783, doi:10.1029/2019PA003665.
    Description: Hurricanes cause substantial loss of life and resources in coastal areas. Unfortunately, historical hurricane records are too short and incomplete to capture hurricane‐climate interactions on multi‐decadal and longer timescales. Coarse‐grained, hurricane‐induced deposits preserved in blue holes in the Caribbean can provide records of past hurricane activity extending back thousands of years. Here we present a high resolution record of intense hurricane events over the past 1500 years from a blue hole on South Andros Island on the Great Bahama Bank. This record is corroborated by shorter reconstructions from cores collected at two nearby blue holes. The record contains coarse‐grained event deposits attributable to known historical hurricane strikes within age uncertainties. Over the past 1500 years, South Andros shows evidence of four active periods of hurricane activity. None of these active intervals occurred in the past 163 years. We suggest that Intertropical Convergence Zone position modulates hurricane activity on the island based on a correlation with Cariaco Basin titanium concentrations. An anomalous gap in activity on South Andros Island in the early 13th century corresponds to a period of increased volcanism. The patterns of hurricane activity reconstructed from South Andros Island closely match those from the northeastern Gulf of Mexico but are anti‐phased with records from New England. We suggest that either changes in local environmental conditions (e.g., SSTs) or a northeastward shift in storm tracks can account for the increased activity in the western North Atlantic when the Gulf of Mexico and southeastern Caribbean are less active.
    Description: This work was funded by the National Science Foundation Graduate Research Fellowship (to E.J.W.), National Science Foundation grant OCE‐1356708 (to J.P.D. and P.J.vH.), the Dalio Explore Foundation and the USGS Land Change Science Program (M.R.T.). We are grateful to members of WHOI Coastal Systems Group, in particular Stephanie Madsen, for their help in the processing core samples. We thank two anonymous reviewers, Matthew Lachniet, Marci Robinson (USGS) and Miriam Jones (USGS) for their helpful feedback on earlier versions of this manuscript. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. The data are available on the National Climatic Data Center (http://www.ncdc.noaa.gov/dataaccess/paleoclimatology‐data) and WHOI Coastal Systems Group (https://web.whoi.edu/coastal‐group/) websites.
    Keywords: Paleohurricanes ; Carbonate tidal flats ; Blue holes ; Andros ; Bahamas
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 7
    Publication Date: 2022-05-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 126(4), (2021): e2020JC016614, https://doi.org/10.1029/2020JC016614.
    Description: Horizontal and vertical motions associated with mesoscale (10–100 km) and submesoscale (1–10 km) features, such as fronts, meanders, eddies, and filaments, play a critical role in redistributing physical and biogeochemical properties in the ocean. This study makes use of a multiplatform data set of 82 drifters, a Lagrangian float, and profile timeseries of temperature and salinity, obtained in a ∼1-m/s semipermanent frontal jet in the Alboran Sea as part of CALYPSO (Coherent Lagrangian Pathways from the Surface Ocean to Interior). Drifters drogued at ∼1-m and 15-m depth capture the mesoscale and submesoscale circulation aligning along the perimeter of fronts due to horizontal shear. Clusters of drifters are used to estimate the kinematic properties, such as vorticity and divergence, of the flow by fitting a bivariate plane to the horizontal drifter velocities. Clusters with submesoscale length scales indicate normalized vorticity ζ/f 〉 1 with Coriolis frequency f and normalized divergence of (1) occurring in patches along the front, with error variance around 10%. By computing divergence from drifter clusters at two different depths, we estimate minimum vertical velocity of (−100 m day−1) in the upper 10 m of the water column. These results are at least twice as large as previous estimates of vertical velocity in the region. Location, magnitude, and timing of the convergence are consistent with behavior of a Lagrangian float subducting in the center of a drifter cluster. These results improve our understanding of frontal subduction and quantify convergence and vertical velocity using Lagrangian tools.
    Description: This research was supported by the Office of Naval Research (ONR) Departmental Research Initiative CALYPSO under program officers Terri Paluszkiewicz and Scott Harper. The authors' ONR grant numbers are as follows: D. R. Tarry, A. Pascual, S. Ruiz and A. Mahadevan N000141613130, S. Essink N000146101612470, P.-M. Poulain N000141812418, T. OÖzgökmen N000141812138, L. R. Centurioni N000141712517 and N00014191269, T. Farrar N000141812431, A. Shcherbina N000141812139 and N000141812420, and E. A. D'Asaro N000141812139.
    Keywords: Alboran Sea ; drifters ; kinematic properties ; Lagrangian float ; submesoscale ; vertical velocity
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 8
    Publication Date: 2022-05-24
    Description: The relation between macroseismic intensity and ground shaking makes it possible to transform instrumental Ground Motion Parameters (GMPs) in macroseismic intensity and vice versa, and is therefore useful for making comparisons between estimates of seismic hazard determined in terms of GMPs and macroseismic intensity, and for other engineering and seismological applications. Empirical relationships between macroseismic intensity and different recorded GMPs for the Italian territory are presented in this paper. The coefficients are calibrated using a dataset of horizontal geometrical mean GMPs, i.e. peak ground acceleration (PGA), peak ground velocity (PGV), spectral acceleration (SA) at 0.2, 0.3, 1.0 and 2.0 s from the ITalian ACcelerometric Archive (ITACA; Luzi et al. 2019), and macroseismic intensity at Mercalli-Cancani-Sieberg (MCS) scale from the database DBMI15 (Locati et al. 2019). A dataset was obtained that corresponds to 240 pairs of macroseismic intensity-GMPs from 67 Italian earthquakes in the time window 1972-2016 with moment magnitude ranging from 4.2 to 6.8 and macroseismic intensity in the range [2, 10-11]. The final dataset is developed correlating strong motion stations and macroseismic intensity observations generally within 2 km from each other, but the associations is manually validated through the expert opinion. The adopted functional form is non-linear predicting macroseismic intensity as a function of LogGMPs and vice versa by performing separate regressions. The set of empirical conversion relationships GMP-I MCS -GMP and the associated standard deviations are compared with previous models. The results of an illustrative PSHA, obtained using a new seismogenic zonation (Santulin et al. 2017), proposed as one of the inputs of the new Italian seismic hazard model (Meletti et al. 2017), are used to analyse and compare seismic hazard assessment in terms of PGA and the related seismic hazard map in terms of macroseismic intensity (MCS) obtained using the empirical relationships here proposed for the PGA.
    Description: Published
    Description: 5143–5164
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Keywords: macroseismic ; intensity ; groundmotionparameters ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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