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  • 1
    Publication Date: 2021-07-05
    Description: We have determined the content of free l-amino acids and d-aspartate in the nervous tissue of three representative cephalopods: Sepia officinalis, Octopus vulgaris, and Loligo vulgaris, and the optic lobes of adult and embryo Sepia officinalis. Taurine is the most abundant amino acid in the cephalopod nervous tissue. Its content amounts to more than 50% of the total free amino acids. The other most concentrated amino acids are Glu, Ala, Asp, and GABA. High concentrations of d-aspartate were found in the nervous tissue of all cephalopods examined (7–12 μmol/g wet tissue) which represents 50–80% of the total aspartate (d + l), depending on the animal. Among the various regions of the brain of Octopus vulgaris, d-aspartate was found to be evenly distributed in the various regions of the brain. In nerve tissue of Sepia officinalis, there is no significant difference in the pattern of free l-amino acids, in particular of the d-aspartate concentration, between adults and embryos, except for GABA, Gly, His and Thr. This suggests that d-aspartate in nerve tissue of the Cephalopoda is of endogenous origin and not a product of accumulation from exogenous sources. From a comparative study of the content of d-aspartate in the nervous tissue of different animals, we found that protostomia contain a significantly higher amount than deuterostomia. Thus, d-aspartate could be a criterion to distinguish the protostomia phyla from the deuterostomia phyla.
    Type: Article , PeerReviewed
    Format: text
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  • 2
    Publication Date: 2022-04-22
    Description: New geochemical and isotopic data on volcanic rocks spanning the period ~75–50 ka BP on Ischia volcano, Italy, shed light on the evolution of the magmatic system before and after the catastrophic, caldera-forming Monte Epomeo Green Tuff (MEGT) eruption. Volcanic ac tivity during this period was influenced by a large, composite and differentiating magmatic system, replenished several times with isotopically distinct magmas of deepprovenance. Chemical and isotopic variations highlight that the pre-MEGT eruptions were fed by trachytic/phonolitic magmas from an isotopically zoned reservoir that were poorly enriched in radiogenic Sr and became progressively less radiogenic with time. Just prior to the MEGT eruption, the magmatic system was recharged by an isotopically distinct magma, relatively more enriched in radiogenic Sr with respect to the previously erupted magmas. This second magma initially fed several SubPlinian explosive eruptions and later supplied the climactic, phonolitic-to-trachytic MEGT eruption(s). Isotopic data, together with erupted volume estimations obtained for MEGT eruption(s), indicate that 〉5–10 km3of this relatively enriched magma had accumulated in the Ischia plumbing system. Geochemical modelling indicates that it accumulated at shallow depths (4–6 km), over a period of ca. 20 ka. After the MEGT eruption, volcanic activity was fed by a new batch of less differentiated (trachyte-latite) magma that was slightly less enriched in radiogenic Sr. The geochemical and Sr–Nd-isotopic variations through time reflect the upward flux of isotopically distinct magma batches, variably contaminated byHercynian crust at 8–12 km depth. The deep-sourced latitic to trachytic magmas stalled at shallow depths (4–6 km depth), differentiated to phonolite through crystal fractionation and assimilation of a feldspar-rich mush, or ascended directly to the surface and erupted.
    Description: Published
    Description: 1035
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Ischia volcano ; Magmatic plumbing system ; Radiogenic isotopes ; Geothermometry ; Feldspar assimilation ; Caldera collapse
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-12-03
    Description: We report on the results of an extensive geochemical survey of fluids released in the Vardar zone (central-western Serbia), a mega-suture zone at the boundary between Eurasia and Africa plates. Thirty-one bubbling gas samples are investigated for their chemical and isotopic compositions (He, C, Ar) and cluster into three distinct groups (CO2-dominated, N2-dominated, and CH4-dominated) based on the dominant gas species. The measured He isotope ratios range from 0.08 to 1.19 Ra (where Ra is the atmospheric ratio), and reveal for the first time the presence of a minor (〈20%) but detectable regional mantle-derived component in Serbia. δ13C values range from −20.2‰ to −0.1‰ (versus PDB), with the more negative compositions observed in N2-dominated samples. The carbon-helium relationship indicates that these negative δ13C compositions could be due to isotopic fractionation processes during CO2 dissolution into groundwater. In contrast, CO2-rich samples reflect mixing between crustal and mantle-derived CO2. Our estimated mantle-derived He flux (9.0 × 109 atoms m−2 s−1) is up to 2 orders of magnitude higher than the typical fluxes in stable continental areas, suggesting a structural/tectonic setting favoring the migration of deep-mantle fluids through the crust.
    Description: Published
    Description: e2021GC010017
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-12-01
    Description: In this study, we assess the spectral characteristics of seismic noise at the sites of the Italian Seismic Network and its spatio-temporal variability. The evaluation of noise is crucial for the assessment of the detection capability of a seismic network. We selected a set of 233 stations, those equipped with broadband velocimeters (with corner period urn:x-wiley:23335084:media:ess2910:ess2910-math-0001 40 s) and operating continuously for at least four consecutive years. The analysis was carried out in the frequency band from 0.025 to 30 Hz, in accordance with the seismic sensors bandwidth. We estimated the Power Spectral Density (PSD) of the seismic noise for fixed temporal windows and then we calculated the Probability Density Functions (PDF) at each station. Exploiting the large data set available, we have been able to: (a) describe the characteristics of the noise power at each site; (b) investigate both temporal and spatial variations of the background noise, revealing correlations of the noise levels with natural and anthropogenic noise sources; (c) propose an empirical relationship linking the “microseismic” noise (i.e., 0.12–1.2 Hz) with the geographical features of the site hosting the seismic station; (d) establish the baselines of a new seismic noise model that could be considered as a new reference for the Italian territory.
    Description: Published
    Description: e2020EA001579
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2021-12-14
    Description: questionnaire to survey the common petrological monitoring procedures adopted by volcano monitoring insti- tutions has been developed, aimed at identifying prevailing techniques and rating their suitability in terms of costs versus benefits. The collected information resulted from a sample of eighteen participating institutions, which include countries with some of the most important active volcanic provinces worldwide. The participating institutions also offer insights into volcanoes with a variety of volcanic activity, providing a comprehensive pic- ture of the state of art of petrological monitoring. The final purposes are (i) to promote the advancement that pet- rologic monitoring brings in the comprehension of the eruptive processes, providing the only “signals” (i.e., rock samples) concerning the physico-chemical properties of the magma feeding the eruption; (ii) to design best practices, and (iii) to define the minimum requirements needed to perform an efficient petrological monitoring during ongoing eruptions. The survey also highlighted the main problems to overcome to have a profitable pet- rological monitoring infrastructure, including (i) the time required to accomplish both field survey and labora- tory works (sampling, sample preparation, and analyses), (ii) the lack of onsite analytical facilities, (iii) the shortage of qualified staff. Starting from the state of the art of petrological monitoring, how it is performed by the different institutions worldwide, and what participants considered as the major problems, we identified the Best Practices in Petrolog- ical Monitoring as the best compromise between fast and easy analyses and the relevance of the acquired results.
    Description: Eurovolc
    Description: Published
    Description: 107365
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Petrology ; Best Practices ; Petrological Monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-12-10
    Description: Groundwater close to three municipal solid waste landfll sites in Sicily (southern Italy) was sampled to determine the presence of contaminants and the risk associated with its possible use as drinking and sanitary water. Polycyclic aromatic hydrocarbons, polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and metals were investigated. These target compounds are the most common pollutants present in leachates. Risk Assessment Guidance for Superfund (RAGS, US EPA) was used to assess human health risk. Ingestion, dermal, and total exposure to these xenobiotic contaminants in groundwater were evaluated, and the cancer and non-cancer risk indexes were calculated. The results revealed that, while the groundwater complied with Italian Drinking Water Directive 30/2001, it did not comply with the "good environmental state" criteria of Directive 30/2009 at two of the three sites investigated. Worrying results were revealed by the risk assessment at the investigated sites. Cancer and non-cancer risk indexes indicated a probable risk, mainly due to dermal exposure to groundwater. These results underline the importance of assessing the risk for all possible routes, evaluating not only ingestion but also dermal exposure, especially when organic pollutants are present. The results of this study show that human health risk has probably been underestimated in the past, as dermal exposure to organic pollutants has only rarely been evaluated in the literature.
    Description: Published
    Description: 535–550
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Human health risk ; Polycyclic aromatic hydrocarbons ; Polychlorinated biphenyls ; Dioxin PCDD/Fs ; Toxic elements ; Environmental quality standard
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2021-11-29
    Description: In this work, we propose a wavelet-based filtering for soil CO2 flux time series. The filter relies on the detection of the periodic components achieved by means of the long-term time-frequency characterization of the time series. For this purpose, we exploited the vast data set coming from the monitoring network installed at Mt. Etna volcano (Italy). The network provides hourly measure of CO2 flux together with the measure of the climatic variables. These data allow to investigate the relationships between CO2 time series and the potentially influencing meteorological factors. This has been assessed calculating the wavelet coherence between CO2 time series against air temperatures, atmospheric pressure, and relative humidity in all the sites where these information were available. Results highlight the occurrence of marked cycles at about ∼1 year for the most of the sites while shorter cycles occur only at some sites. From these cycles a periodic signal can be calculated, and therefore opportunely removed from the time CO2 series to enhance the volcano-related anomalies. We found also common cycles among CO2 and the climatic variables, which synchronicity is constant over time but it is site-specific. Starting from this consideration, we calculated a reference signal for CO2 combining analytically the temperature, the pressure, and the humidity cycles: this model of the climatic effect has been used to predict the seasonal trend of the CO2 output.
    Description: Published
    Description: 107421
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Description: JCR Journal
    Keywords: Soil CO2 ; Continuous wavelet transform ; Spectral analysis ; Etna
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2022-06-22
    Description: Geothermal areas of Greece are located in regions affected by recent volcanism and in continental basins characterised by elevated heat flow. Many of them are found along the coast and thus, water is often saline due to marine intrusion. In the current study, we present about 300 unpublished and literature data from thermal and cold mineral waters collected along Greece. Samples were analysed for major ions, Li, SiO2 and isotopes in water. Measured temperatures range from 6.5 to 98°C, pH from 1.96 to 11.98, whilst Total Dissolved Solutes (TDS) from 0.22 to 51 g/L. Waters were subdivided into four main groups: i) thermal; ii) cold; iii) acidic (pH 〈5) and iv) hyperalkaline (pH 〉11). On statistical basis, the thermal waters were subdivided into subgroups according to both their temperature [warm (〈29 °C), hypothermal (29-48 °C), thermal (48-75 °C) and hyperthermal (〉75 °C)] and TDS [low salinity (〈4 g/L), brackish (4-30 g/L) and saline (〉30 g/L)]. Cold waters were subdivided basing on their pCO2 [low (〈0.05 atm), medium (0.05-0.85 atm) and high (〉0.85 atm)]. δ18O-H2O ranges from -12.7 to +2.7 ‰ vs. SMOW, while δ2H-H2O from -91 to +12 ‰ vs. SMOW being generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Positive δ18O shifts with respect to the former are mostly related to mixing with seawater, while only for a few samples they point to high-temperature water-rock interaction processes. Only a few thermal waters gave reliable geothermometric estimates, suggesting reservoir temperatures between 80 and 260 °C.
    Description: Published
    Description: 2111–2133
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Hydrogeochemistry ; Stable isotopes ; Carbon dioxide ; Geothermometry ; 03. Hydrosphere ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2022-10-19
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography and Paleoclimatology 36(7), (2021): e2020PA004088, https://doi.org/10.1029/2020PA004088.
    Description: We reconstruct deep water-mass salinities and spatial distributions in the western North Atlantic during the Last Glacial Maximum (LGM, 19–26 ka), a period when atmospheric CO2 was significantly lower than it is today. A reversal in the LGM Atlantic meridional bottom water salinity gradient has been hypothesized for several LGM water-mass reconstructions. Such a reversal has the potential to influence climate, ocean circulation, and atmospheric CO2 by increasing the thermal energy and carbon storage capacity of the deep ocean. To test this hypothesis, we reconstructed LGM bottom water salinity based on sedimentary porewater chloride profiles in a north-south transect of piston cores collected from the deep western North Atlantic. LGM bottom water salinity in the deep western North Atlantic determined by the density-based method is 3.41–3.99 ± 0.15% higher than modern values at these sites. This increase is consistent with: (a) the 3.6% global average salinity change expected from eustatic sea level rise, (b) a northward expansion of southern sourced deep water, (c) shoaling of northern sourced deep water, and (d) a reversal of the Atlantic's north-south deep water salinity gradient during the LGM.
    Description: This work was supported by the US National Science Foundation (grant numbers 1433150 and 1537485).
    Description: 2021-10-24
    Keywords: Carbon cycle ; Climate change ; Deep water ; Glaciation ; Meridional overturning circulation ; Paleosalinity ; Porewater
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 10
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in E. J., Donnelly, J. P., van Hengstum, P. J., Wiman, C., Sullivan, R. M., Winkler, T. S., d'Entremont, N. E., Toomey, M., & Albury, N. Intense hurricane activity over the past 1500 years at South Andros Island, the Bahamas. Paleoceanography and Paleoclimatology, 34(11), (2019): 1761-1783, doi:10.1029/2019PA003665.
    Description: Hurricanes cause substantial loss of life and resources in coastal areas. Unfortunately, historical hurricane records are too short and incomplete to capture hurricane‐climate interactions on multi‐decadal and longer timescales. Coarse‐grained, hurricane‐induced deposits preserved in blue holes in the Caribbean can provide records of past hurricane activity extending back thousands of years. Here we present a high resolution record of intense hurricane events over the past 1500 years from a blue hole on South Andros Island on the Great Bahama Bank. This record is corroborated by shorter reconstructions from cores collected at two nearby blue holes. The record contains coarse‐grained event deposits attributable to known historical hurricane strikes within age uncertainties. Over the past 1500 years, South Andros shows evidence of four active periods of hurricane activity. None of these active intervals occurred in the past 163 years. We suggest that Intertropical Convergence Zone position modulates hurricane activity on the island based on a correlation with Cariaco Basin titanium concentrations. An anomalous gap in activity on South Andros Island in the early 13th century corresponds to a period of increased volcanism. The patterns of hurricane activity reconstructed from South Andros Island closely match those from the northeastern Gulf of Mexico but are anti‐phased with records from New England. We suggest that either changes in local environmental conditions (e.g., SSTs) or a northeastward shift in storm tracks can account for the increased activity in the western North Atlantic when the Gulf of Mexico and southeastern Caribbean are less active.
    Description: This work was funded by the National Science Foundation Graduate Research Fellowship (to E.J.W.), National Science Foundation grant OCE‐1356708 (to J.P.D. and P.J.vH.), the Dalio Explore Foundation and the USGS Land Change Science Program (M.R.T.). We are grateful to members of WHOI Coastal Systems Group, in particular Stephanie Madsen, for their help in the processing core samples. We thank two anonymous reviewers, Matthew Lachniet, Marci Robinson (USGS) and Miriam Jones (USGS) for their helpful feedback on earlier versions of this manuscript. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. The data are available on the National Climatic Data Center (http://www.ncdc.noaa.gov/dataaccess/paleoclimatology‐data) and WHOI Coastal Systems Group (https://web.whoi.edu/coastal‐group/) websites.
    Keywords: Paleohurricanes ; Carbonate tidal flats ; Blue holes ; Andros ; Bahamas
    Repository Name: Woods Hole Open Access Server
    Type: Article
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